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1. 发明申请

WO2009034017A1 KOAGULATION VON KAUTSCHUKDISPERSIONEN DURCH ELEKTROPORATION/DURCH ELEKTRISCHE HOCHSPANNUNGSIMPULSE 审中-公开
标题翻译：橡胶分散体通过电/ BY高压电IMPULSE混凝
公开(公告)号：WO2009034017A1
公开(公告)日：2009-03-19
申请号：PCT/EP2008/061724
申请日：2008-09-05
申请人： BASF SE , GUENTHERBERG, Norbert , MUEHLBACH, Klaus , HEINEN, Hartmut
发明人： GUENTHERBERG, Norbert , MUEHLBACH, Klaus , HEINEN, Hartmut
IPC分类号： C08F6/22 , C08C1/14 , C08F279/02
CPC分类号： C08F6/22 , C08C1/14 , C08C1/15
摘要： Die vorliegende Erfindung betrifft ein Verfahren zur Koagulation von Kunststoffteilchen in Kunststoffdispersionen, wobei elektrische Hochspannungsimpulse auf die Kunststoffdispersion einwirken, sowie die Verwendung von elektrischen Hochspannungsimpulsen zur Koagulation von Kunststoffteilchen in Kunststoffdispersionen und Kunststoffteilchen, koaguliert durch dieses Verfahren.
摘要翻译：本发明涉及一种用于塑料粒子在聚合物分散体的凝结方法，所述高电压电脉冲作用于塑性分散，以及使用高电压的电脉冲的用于塑料在塑料分散体和塑料颗粒的凝结，通过该方法凝结。

2. 发明申请

WO9933914A3 STYRENE COPOLYMER COMPOSITIONS HAVING REDUCED SURFACE GLOSS AND COMPOSITE ARTICLES INCORPORATING SAME 审中-公开
标题翻译：具有缩小的表面光泽的苯乙烯共聚物组合物以及并入相同组合物的组合物
公开(公告)号：WO9933914A3
公开(公告)日：1999-09-10
申请号：PCT/EP9808361
申请日：1998-12-18
申请人： BASF CORP , BENNETT JAMES H , MUEHLBACH KLAUS , KOGOWSKI GARY , GOERRISSEN HEINER , MC KEE GRAHAM EDMUND
发明人： BENNETT JAMES H , MUEHLBACH KLAUS , KOGOWSKI GARY , GOERRISSEN HEINER , MC KEE GRAHAM EDMUND
IPC分类号： C08F257/02 , C08L51/04 , C08L25/04 , B32B27/28 , C08L51/00 , C08L55/02
CPC分类号： C08F257/02 , C08L51/04 , C08F212/08 , C08L2666/04
摘要： The invention provides a weatherable low gloss styrene copolymer composition which requires the addition of from 0.1 to 20 % by weight of the total composition, of a partially crystalline polymer such as a polyalkylterephthalate, especially polybutyleneterephthalate or polyethyleneterephthalate, or polyethylenenaphthalate to a styrene copolymer (A). The low gloss styrene copolymer composition of the invention has a graft copolymer resin which results from polymerizing one or more monomers (A1) selected from the group consisting of (i) aromatic vinyl compounds, (ii) ethylenically unsaturated compounds, and (iii) mixtures thereof, in the presence of an elastomeric rubber (A2) in particulate form. The elastomeric rubber (A2) in particulate form results from polymerizing one or more monomers selected from the group consisting of (i) alkyl acrylates having from 1 to 8 carbon atoms, (ii) butadiene, (iii) olefin compounds, (iv) ethylenically unsaturated compounds, (v) aromatic vinyl compounds, (vi) polyfunctional monomers having a crosslinking effect, and (vii) mixtures thereof. The invention further provides a method of reducing the surface gloss of a styrene copolymer resin by adding to a styrene copolymer resin (A), from 0.1 to 20 % by weight of a partially crystalline polymer such as a polyalkylterephthalate (B), based on the total weight of the composition. The invention also provides a composite suitable for use as exterior siding for a structure, the composite comprising at least one interior layer (I) comprising a thermoplastic resin, and at least one exterior layer (II) having a low gloss styrene copolymer comprising the low gloss styrene copolymer composition of the invention, wherein exterior layer (II) is continuous and coextensive with interior layer (I).
摘要翻译：本发明提供耐候性低光泽度苯乙烯共聚物组合物，其需要将总组合物的0.1至20重量％的部分结晶聚合物，例如聚对苯二甲酸烷基酯，特别是聚对苯二甲酸丁二醇酯或聚对苯二甲酸乙二醇酯或聚萘二甲酸乙二醇酯添加至苯乙烯共聚物（A ）。本发明的低光泽苯乙烯共聚物组合物具有接枝共聚物树脂，其由选自（i）芳族乙烯基化合物，（ii）烯属不饱和化合物和（iii）混合物中的一种或多种单体（A1）在粒状形式的弹性体橡胶（A2）存在下进行。颗粒形式的弹性体橡胶（A2）由选自以下的一种或多种单体聚合得到：（i）具有1至8个碳原子的丙烯酸烷基酯，（ii）丁二烯，（iii）烯烃化合物，（iv）烯属（v）芳族乙烯基化合物，（vi）具有交联作用的多官能单体，和（vii）它们的混合物。本发明进一步提供了通过向苯乙烯共聚物树脂（A）中加入0.1-20重量％的部分结晶聚合物如聚对苯二甲酸烷基酯（B）来降低苯乙烯共聚物树脂的表面光泽度的方法，基于组合物的总重量。本发明还提供适合用作结构的外侧壁的复合材料，所述复合材料包含至少一个包含热塑性树脂的内层（I）和至少一个具有低光泽度苯乙烯共聚物的外层（II），所述低光泽度苯乙烯共聚物包含低本发明的光泽苯乙烯共聚物组合物，其中外层（II）与内层（I）连续并共同延伸。

3. 发明申请

WO2012072643A2 PRODUCTION OF ISOBUTYLENE HOMOPOLYMER OR COPOLYMER DERIVATIVES 审中-公开
标题翻译： MANUFACTURING异丁烯或共聚物衍生物
公开(公告)号：WO2012072643A2
公开(公告)日：2012-06-07
申请号：PCT/EP2011071306
申请日：2011-11-29
申请人： BASF SE , KOENIG HANNAH MARIA , MUEHLBACH KLAUS , MACH HELMUT , EICHENAUER ULRICH
发明人： KOENIG HANNAH MARIA , MUEHLBACH KLAUS , MACH HELMUT , EICHENAUER ULRICH
IPC分类号： C08F8/00 , C08F4/06 , C08F4/14 , C08F4/26 , C08F10/10 , C08F110/10
CPC分类号： C08F8/00 , C08F2810/40 , C08F10/10 , C08F4/26 , C08F4/70
摘要： Disclosed is the production of isobutylene homopolymer or copolymer derivatives comprising a hydrophobic polyisobutylene polymer residue that has a number average molecular weight of 110 to 250,000 and low-molecular polar groups containing amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups. According to the invention, isobutylene or a monomer mixture containing isobutylene is polymerized in the presence of an iron halide donor complex acting as a polymerization catalyst, an aluminum trihalide donor complex or an aluminum alkyl halide donor complex containing an organic compound having an ether function or a carboxylic acid ester function as a donor, or a Lewis acid complex containing organic sulfonic acids and optional donors, the resulting highly reactive isobutylene polymer is reacted with a compound introducing the low-molecular polar group or a substructure thereof, and in case the reaction is performed using a substructure, the formation of the low-molecular polar group is completed by performing successive reactions.
摘要翻译：具有残余HY-降的解除，其数均分子量为110的聚异丁烯聚合物250,000，低分子量xylgruppen每个氨基官能团的极性基团，硝基，水力，硫醇基团，羧酸或-Car-onäurederivatfunktionen异丁烯或共聚物衍生物的生产，包括磺酸或Sulfonsäurederivatfunktionen，醛和/或甲硅烷基，所述异丁烯或以有效的存在作为聚合卤化铁供体络合物，Aluminiumtrihalo-卤化物供体络合物或Aluminumalkylhalogenid供体复合物，其作为含异丁烯的单体混合物供体包含具有醚官能团或羧酸功能，或含路易斯酸 - 柑-PLEX具有或不具有聚合供体的有机磺酸的有机化合物，所得到的与NIED高反应性异丁烯 ermolekulare极性基团或它们的部分结构，导入化合物和低分子量的极性基团的形成反应在与由随后的反应的部分结构反应的情况下完成。

4. 发明申请

WO2008020012A3 THERMOPLASTISCHE FORMMASSEN AUF BASIS VON ACRYLNITRIL, STYROL UND BUTADIEN 审中-公开
公开(公告)号：WO2008020012A3
公开(公告)日：2008-02-21
申请号：PCT/EP2007/058388
申请日：2007-08-14
申请人： BASF SE , PEPERS, Michel , MUEHLBACH, Klaus , HAEHNLEIN, Marc , SAUER, Michael , MITULLA, Konrad , OEPEN, Sabine , SUWIER, Davy Roger , NIESSNER, Norbert
发明人： PEPERS, Michel , MUEHLBACH, Klaus , HAEHNLEIN, Marc , SAUER, Michael , MITULLA, Konrad , OEPEN, Sabine , SUWIER, Davy Roger , NIESSNER, Norbert
IPC分类号： C08L25/12 , C08L55/02 , C08F220/12 , C08F265/06 , C08F6/22 , C08C1/07 , C08L33/08
摘要： Ein Verfahren zur Herstellung einer thermoplastischen ABS-Formmasse beruht darauf, dass man durch Massepolymerisation oder Lösungsmittelpolymerisation das thermoplastische Copolymer A aus Acrylnitril und Styrol herstellt, durch Emulsionspolymerisation unter Verwendung eines Redox-Initiatorsystems das Pfropfcopolymer B, aufgebaut aus Pfropfgrundlage (B1) und Pfropfhülle (B2), herstellt, und anschließend das thermoplastische Copolymer A und das Pfropfcopolymer B sowie gegebenenfalls die weiteren Komponenten K und/oder die weiteren thermoplastischen Polymere (TP) mischt.

5. 发明申请

WO2012072536A2 PRODUCTION OF ISOBUTYLENE COPOLYMER DERIVATIVES 审中-公开
标题翻译：生产ISOBUTENCOPOLYMERISATEN导数的
公开(公告)号：WO2012072536A2
公开(公告)日：2012-06-07
申请号：PCT/EP2011071112
申请日：2011-11-28
申请人： BASF SE , KOENIG HANNAH MARIA , MUEHLBACH KLAUS , MACH HELMUT , EICHENAUER ULRICH
发明人： KOENIG HANNAH MARIA , MUEHLBACH KLAUS , MACH HELMUT , EICHENAUER ULRICH
IPC分类号： C08F8/32
CPC分类号： C08F8/32 , C08F8/14 , C08F8/44 , C08F10/10 , C08F255/10 , C08F290/042 , C08F2810/40 , C08F4/70 , C08F4/26
摘要： Disclosed is the production of isobutylene copolymer derivatives by radically copolymerizing (a) 10 to 90 mol-% of a monoethylenically unsaturated C4 to C12 dicarboxylic acid or the anhydride, half-ester or full ester thereof, (b) 10 to 90 mol-% of a highly reactive isobutylene polymer having a number average molecular weight of 110 to 250,000, and (c) 0 to 50 mol-% of monoethylenically unsaturated compounds that can be copolymerized with monomer components (a) and (b), and then reacting the carboxylic acid or carboxylic acid derivative functions in the obtained isobutylene copolymer with ammonia, an amine and/or an alcohol so as to form groupings having hydroxy, carboxylic acid ester, amino, quaternized amino, amido and/or imido groups. In order to produce monomer component (b), isobutylene or a monomer mixture containing isobutylene is polymerized in the presence of an iron halide donor complex acting as a polymerization catalyst, an aluminum trihalide donor complex or an aluminum alkyl halide donor complex containing an organic compound having an ether function or a carboxylic acid ester function as a donor, or a Lewis acid complex containing at least one organic sulfonic acid and optional donors.
摘要翻译： Isobutencopolymerisaten的衍生物的制备由（a）的10〜90％（摩尔）单烯类不饱和C 4至C 12二羧酸，bonsäure或其酸酐，半桥或全酯，自由基共聚（B）10〜90摩尔％反应性高的异丁烯具有110的数均分子量为250,000，和（c）0〜50摩尔％的单烯属不饱和化合物的与所述单体组分（a）和（b）共聚，然后将羧酸或羧酸衍生物功能性在所得Isobutencopolymerisat与反应含有氨，胺和/或醇，以形成具有羟基，羧酸酯，氨基，季铵化的氨基，酰氨基和/或酰亚胺基团，部分，其中一个（b）异丁烯以产生单体成分或异丁烯在有效的情况下，作为聚合卤化铁供体络合物，Aluminiumtr单体混合物含有ihalogenid供体配合物或Aluminumalkylhalogenid供体络合物作为供体，具有醚功能或羧酸酯官能团，或至少一种有机含磺酸 - 路易斯酸络合物，具有或不具有聚合供体的有机化合物。

6. 发明申请

WO2008020012A2 THERMOPLASTIC MOLDING COMPOUNDS BASED ON ACRYLONITRILE, STYRENE, AND BUTADIENE 审中-公开
标题翻译：热塑性模塑化合物基于丙烯腈，苯乙烯和丁二烯
公开(公告)号：WO2008020012A2
公开(公告)日：2008-02-21
申请号：PCT/EP2007058388
申请日：2007-08-14
申请人： BASF AG , PEPERS MICHEL , MUEHLBACH KLAUS , HAEHNLEIN MARC , SAUER MICHAEL , MITULLA KONRAD , OEPEN SABINE , SUWIER DAVY ROGER , NIESSNER NORBERT
发明人： PEPERS MICHEL , MUEHLBACH KLAUS , HAEHNLEIN MARC , SAUER MICHAEL , MITULLA KONRAD , OEPEN SABINE , SUWIER DAVY ROGER , NIESSNER NORBERT
IPC分类号： C08L25/12 , C08C1/07 , C08F6/22 , C08F220/12 , C08L55/02
CPC分类号： C08L55/02 , C08C1/07 , C08F6/22 , C08F279/04 , C08L33/08 , C08L2666/04 , C08L25/12 , C08L53/02
摘要： Disclosed is a method for producing a thermoplastic ABS molding compound. According to said method, the thermoplastic copolymer A is produced from acrylonitrile and styrene by means of bulk polymerization or solution polymerization, while graft copolymer B, which is composed of a graft base (B1) and a graft shell (B2), is produced by means of emulsion polymerization using a redox initiator system, whereupon the thermoplastic copolymer A, graft copolymer B, and additional optional components K and/or additional thermoplastic polymers (TP) are mixed.
摘要翻译：基于由本体聚合或溶液聚合的丙烯腈和苯乙烯，使用氧化还原引发剂体系通过乳液聚合构成的接枝基体，接枝共聚物B的热塑性共聚物A制备的事实生产热塑性ABS模制组合物（B1）的方法，和接枝外壳（B2 ），制造，然后将热塑性共聚物A和接枝共聚物B和，如果合适的话，另外的部件K和/或其它热塑性聚合物（TP）被混合。

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