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1. 发明申请

WO1997028571A1 PROCESS FOR THE PRODUCTION OF AN ELECTRODE FOR A FUSED CARBONATE FUEL CELL, ELECTRODE PRODUCED ACCORDING TO THIS PROCESS AND FUSED CARBONATE FUEL CELL PROVIDED WITH AN ELECTRODE PRODUCED ACCORDING TO THIS PROCESS 审中-公开
标题翻译： METHOD FOR制造电极用于熔融碳酸盐燃料电池，根据所述方法和电极的熔融碳酸盐燃料电池具有直TO所制造电极
公开(公告)号：WO1997028571A1
公开(公告)日：1997-08-07
申请号：PCT/EP1997000422
申请日：1997-01-31
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , BISCHOFF, Manfred , ROHLAND, Bernd , JANTSCH, Uwe
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M04/88
CPC分类号： H01M4/8857 , H01M4/8875 , H01M4/8885 , H01M4/9016 , H01M8/142 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , Y02E60/526 , Y02P70/56
摘要： The invention concerns a process for the production of a porous lithium cobaltite electrode plate with a large inner surface and low polarization resistance. Lithium carbonate powder and cobalt metal powder are uniformly mixed together and then films are produced from the mixture and plates from the films, which plates are sintered and then placed in an air stream for several hours at a temperature between 400 DEG C and 488 DEG C until the conversion of said plates to lithium cobaltite electrode plates with an extremely large inner surface has taken place.
摘要翻译：本发明涉及一种用于生产具有大的内表面积和低的极化电阻的多孔钴酸锂的电极板的方法。为了这个目的Lithiumkarbonat-和钴金属粉末混合在一起均匀，然后从共混膜并从其中被烧结至它随后在400℃和488摄氏度的温度下流动的空气暂停直到转换数小时膜板中制备所述板中的具有非常大的内表面积的钴酸锂的电极板已经发生。

2. 发明申请

WO1996020337A1 PROCESS FOR REGULATING DESIGN LOAD AND ACCELERATION BEHAVIOUR OF SUPERCHARGED INTERNAL COMBUSTION ENGINES 审中-公开
标题翻译：用于控制增压发动机的加速负载验收和行为
公开(公告)号：WO1996020337A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995005081
申请日：1995-12-21
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , ÖSTREICHER, Wolfgang , ZELLBECK, Hans
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： F02D29/06
CPC分类号： F02D35/023 , F02B3/06 , F02D23/02 , F02D31/007 , F02D41/0007 , F02D41/10 , F02D41/401 , F02D2200/0406 , Y02T10/144 , Y02T10/44
摘要： A process is disclosed for improving the design load behaviour of an internal combustion engine operating in a substantially stationary mode and supercharged by an exhaust gas turbocharger. By temporarily regulating the starting point of engine feeding in a dynamic variable manner, adapted to the load and mode of operation of the engine, the whole potential of the engine may be used during system-inherent downfalls of the speed of rotation caused when the load is increased. The disclosed regulation of the starting point of engine feeding increases the indexed mean pressure and allows to reach all given mechanical load limits. It acts upon the combustion process and increases power output of diesel engines supercharged by exhaust gas turbocharger whose boost pressure build-up is otherwise limited and unfavourably delayed by the turbocharger limited capacity of acceleration.
摘要翻译：提出一种方法，用于提高基本静止驱动涡轮增压器增压的内燃发动机的设计载荷行为，其中，在负载应用系统相关的速度下降由动态负载和发动机操作匹配的可变进料启动控制的临时切换时，发动机的总功率电势可以被利用。由传送指示平均有效压力的起动控制本发明的装置是通过涡轮增压器的极限加速度能力增加通过利用给定的机械负载限制由否则强制在废气涡轮增压器增压的柴油发动机引起的，不利的延迟的增压压力可利用由燃烧过程的输送控制影响因素的开始增强性能。

3. 发明申请

WO1998044582A1 FUEL CELL ASSEMBLY WITH INTERNAL AND EXTERNAL GAS DISTRIBUTION DEVICES 审中-公开
标题翻译：与内部和外部气体分配装置的燃料电池装置
公开(公告)号：WO1998044582A1
公开(公告)日：1998-10-08
申请号：PCT/EP1998001727
申请日：1998-03-24
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , KRAUS, Peter , ROLF, Stefan
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/24
CPC分类号： H01M8/2483 , H01M8/04014 , H01M8/04022 , H01M8/241 , H01M8/244 , H01M8/247 , H01M8/2484 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： The invention relates to a fuel cell assembly with a number of fuel cells arranged in a stack (1), each fuel cell containing an anode (2), an electrolyte matrix (3) and a cathode (4). Each fuel cell also has an anode input (11), an anode output (12), a cathode input (13) and a cathode output (14) by which means fuel gas and cathode gas can enter or leave. According to the invention, the fuel gas is conveyed to the anode input (11) of the fuel cells via an internal gas distribution device (51) which distributes the gas current inside the fuel cells. The cathode gas, on the other hand, is led to or away from the cathode input (13) and/or cathode output (14) by means of the external gas distribution devices (43, 44) which distribute the gas current to the fuel cells outside. According to various embodiments of the invention, the currents of fuel gas and cathode gas run through the fuel cells in a cross current, a counter-current or direct current. Additional measures are taken for the integrated catalytic oxidation of fuel gas residues.
摘要翻译：它包含在每种情况下一个阳极具有多个燃料电池组件（2），电解质基质（3）和阴极（4），在燃料电池堆（1）中描述的布置的燃料电池。每个燃料电池具有阳极输入端（11），阳极输出（12），阴极入口（13）和用于燃料气体和阴极气体的供应和排出的阴极输出（14）。根据本发明的燃料气体向燃料电池的阳极入口（11）经由气体流动的燃料电池内部的气体分配装置（51）内循环的阴极输入端（13）和外/或在阴极输出（14）通过气体流的装置提供，而阴极气体分配（43,44）被提供或由其排出的燃料电池的外部气体分配装置。根据通过燃料气体和阴极气体的流的本发明的实施例中，燃料电池中的横流，逆流或直流电，其中，另外采取措施用于燃料气体的残基的集成催化氧化。

4. 发明申请

WO1998004012A1 CURRENT-CARRYING COMPONENT FOR A FUSED CARBONATE FUEL CELL WITH ANTICORROSIVE COATING 审中-公开
标题翻译：用于附腐蚀涂层的熔融载流部件
公开(公告)号：WO1998004012A1
公开(公告)日：1998-01-29
申请号：PCT/EP1997003777
申请日：1997-07-15
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , HIERMAIER, Manfred , KLOSE, Reinhard , WIND, Jörg
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/02
CPC分类号： H01M8/0206 , H01M8/021 , H01M8/0228 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： The invention concerns a current-carrying component for a fused carbonate fuel cell, in particular an anode current collector or bipolar plate, with a special steel substrate (1) and an anticorrosive coating provided thereon. According to the invention, at least one first layer (2) and one second layer (3) are formed on the substrate (1). The first layer (2), which consists of a material which is inert with respect to the anode gas atmosphere and is not wetted by the molten electrolyte, is applied to the component surface, and the second layer (3), which consists of a material which essentially does not mix with the material of the first layer (2), is formed between the first layer (2) and the substrate (1).
摘要翻译：这是一个载流部件用于熔融，特别是负极集电体或双极板，描述了具有衬底（1）制成的基板上的不锈钢和一（1）提供了用于防腐蚀涂层，其中，所述衬底（1）的至少一个第一层（2）由上形成的材料制成的部件和第二层（3）的表面，其基本上不与所述第一层的材料混合上的材料，该材料是惰性的阳极气体的气氛中并且不被熔融电解液润湿，（2）中，第一层（2）和所述基板（1）之间形成。

5. 发明申请

WO1994018713A1 PROCESS FOR PRODUCING THE CATHODE LAYER OF MOLTEN CARBONATE FUEL CELLS 审中-公开
标题翻译： PROCESS FOR熔融碳酸盐燃料电池阴极涂料制备中
公开(公告)号：WO1994018713A1
公开(公告)日：1994-08-18
申请号：PCT/EP1994000253
申请日：1994-01-29
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , JANTSCH, Uwe , KOCH, Hermann , ROHLAND, Bernd , WEILBERG, Frank , WENDT, Hartmut
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/14
CPC分类号： H01M8/142 , H01M4/8657 , H01M4/8846 , H01M4/8857 , H01M4/8882 , H01M4/8885 , H01M4/9016 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , Y02E60/526 , Y10T29/49108 , Y10T29/49115
摘要： In order to produce the cathode layer of a molten carbonate fuel cell in which the cathode layer is part of a sandwich structure also comprising a matrix layer and an anode layer, a porous cobalt or iron layer is filled with lithium carbonate, the cobalt or iron layer is oxidized at a temperature below the melting point of the lithium carbonate in an oxidizing atmosphere, so that a cobalt or iron oxide layer is produced, and after the temperature is increased above the lithium carbonate melting point, the cobalt or iron oxide reacts with the molten lithium carbonate, producing lithium cobaltide or lithium ferrite. The thus produced cathode layer allows high current densities with insignificant voltage losses and has an extremely low solubility in molten electrolytes.

6. 发明申请

WO1998027249A1 ELECTROLYZER, ISOLATED BY ENCAPSULATION WITH RESPECT TO PRESSURIZED WATER 审中-公开
标题翻译： DRUCKWASSERGEKAPSELTER电解槽
公开(公告)号：WO1998027249A1
公开(公告)日：1998-06-25
申请号：PCT/EP1997007080
申请日：1997-12-17
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , HOFMANN, Hans , MÜLLER-FROELICH, Lutz
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： C25B09/00
CPC分类号： C25B1/12 , C25B9/00 , C25B9/04 , Y02E60/366
摘要： The invention relates to an electrolyzer for the electrolysis of water in hydrogen and oxygen with a number of electrolytic cells, each containing an anode and a cathode, connected in series in a cell block (1) surrounded by a pressure vessel (2). At one end of the cell block (1) is a first electrode (anode 3), and at the opposite end of the cell block is a second electrode (cathode 4). Both are connected with leading-in cables (5, 6), which run through the pressure vessel (2) and conduct the electric current to the cell block (1), the interior of the pressure vessel (2) being filled with pressurized water (7) surrounding the cell block (1). In accordance with the invention, it is envisaged that the first electrode (3) is placed inside the cell block (1) so as to be electrically isolated, by encapsulation, with respect to the pressurized water (7), and that there is a channel (8), sealed against the pressurized water (7), that leads from the cell block through the pressurized vessel (2) to the outside. Through this channel, the leading-in cable (5), which is connected with the first electrode (3), is led to said first electrode (3).
摘要翻译：它串联连接在用于水的电解成氢和氧与多个封闭在压力容器中的一个电解槽（2）细胞块（1）在每种情况下所描述的阳极和包含电解电池的阴极，其中，在所述单元块的一端（1）一个第一电极（阳极3）位于与在所述单元块的相对端的第二电极（阴极4），它们分别通过压力容器龙头（2）中，电流供给导线（5,6），用于将电流供给到电池块（1）被连接时，与所述压力容器（2）填充在单元块的内部（1）周围的加压水（7）。根据本发明，提供的是，第一电极（3）中的单元块的内部（1）相对于所述加压水（7）被布置成包封的电绝缘，并且所述单元块（1）至所述压力容器（2）向外部并且通向加压水（7）的密封通道（8）由连接到设置在所述第一电极（3）的电源（5）被引导到所述第一电极（3）。

7. 发明申请

WO1997033332A1 METHOD OF PRODUCING A CATHODE BY OXIDATION IN A MOLTEN CARBONATE FUEL CELL 审中-公开
标题翻译：制造方法阴极BY氧化反应在一个熔融碳酸盐燃料电池
公开(公告)号：WO1997033332A1
公开(公告)日：1997-09-12
申请号：PCT/EP1997001094
申请日：1997-03-05
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , WENDT, Hartmut , SALGE, Hans-Jürgen , BISCHOFF, Manfred
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/14
CPC分类号： H01M8/142 , H01M4/8621 , H01M4/8878 , H01M4/8892 , H01M4/9016 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , Y02E60/526 , Y02P70/56 , Y10T29/49108 , Y10T29/53204
摘要： The invention concerns a method of producing a cathode for a molten carbonate fuel cell by oxidizing a porous precursor electrode and bringing it into contact with the molten carbonate. After a lyered arrangement containing the precursor electrode, a matrix layer with the molten carbonate, and a porous anode has been assembled, the precursor electrode is anodically oxidized with a predetermined current density development and doped by contact with the molten carbonate.
摘要翻译：本发明涉及一种通过用熔融的前体多孔电极和接触氧化制造用于熔融碳酸盐燃料电池的阴极的方法。该前体电极前体电极的组装后阳极氧化，具有多孔的阳极和包含与所述电流密度的可预先确定的轮廓层布置熔融和基质层通过与熔融接触掺杂。

8. 发明申请

WO1996020507A1 CURRENT COLLECTOR FOR A FUEL CELL AND A METHOD OF MANUFACTURING THE SAME 审中-公开
标题翻译：集电器用于生产燃料电池和过程
公开(公告)号：WO1996020507A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995005111
申请日：1995-12-22
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , KRAUS, Peter , NITSCHKE, Felix , WIND, Jörg
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/02
CPC分类号： H01M4/669 , H01M4/664 , H01M8/0204 , H01M8/0206 , Y02P70/56
摘要： The invention relates to a fuel cell current collector made of a special steel alloy, the latter forming a corrosion-resistant oxide coating on the current collector surface. The current collector (5) contains a doping agent at its surface, the valency of the doping agent being different from that of the cations contained in the oxide layer. The doping agent can either be deposited on the surface of the current collector or can be a component of the steel alloy used for the current collector. The doping agent used can be a chromium-containing special steel alloy which forms a lithium ferrite layer on its surface, e.g. cobalt or one or more of the elements cobalt, manganese, copper, magnesium. The invention results in a current collector which, while having good corrosion resistance, also has high conductivity and is suitable in particular for use with high-temperature fuel cells based on lithium-potassium, lithium-sodium or lithium-sodium-potassium-carbonate electrolytes. It can be used to particular advantage as the cathode-side current collector in a high-temperature fuel cell of this type.
摘要翻译：它是用于其由不锈钢合金制成的燃料电池的电流收集器，其形成在集电体的腐蚀氧化膜，所描述的抗性，其中所述集电体（5）包含在其表面上的掺杂材料的表面上，其比其它化合价包含在氧化物层中的阳离子。掺杂剂材料可以任选地施加到集电体的表面，或者是用于生产的集电体的钢合金的成分。作为掺杂剂材料可以包含在其表面上形成锂层的铁素体铬不锈钢合金，例如的情况下钴或一种或可以提供更多的元素钴，锰，铜，镁。本发明提供一种集流器被提供，其具有高导电性和特别是用于在高温燃料电池使用了锂钾，锂，钠或锂 - 钠 - 钾良好的耐腐蚀性Karbonatelektrolyten是合适的。特别有利的是作为阴极侧集电体在这样的高温型燃料电池使用。

9. 发明申请

WO1997044844A1 PROCESS FOR OPERATING A FUEL CELL ARRANGEMENT 审中-公开
标题翻译：一种用于运行的燃料电池装置
公开(公告)号：WO1997044844A1
公开(公告)日：1997-11-27
申请号：PCT/EP1997002474
申请日：1997-05-15
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , HOFFMANN, Joachim
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/04
CPC分类号： H01M8/247 , H01M8/04014 , H01M8/04022 , H01M8/04097
摘要： The description relates to a process for operating a fuel cell arrangement (1) consisting of a number of fuel cells, in which fuel gas is supplied to the anodes of the fuel cells at an anode inlet (5), anode exhaust gas is removed from the anodes at an anode outlet (6), cathode gas is supplied to the cathodes of the fuel cells at a cathode inlet (7) and the cathode exhaust gas is removed from the cathodes at a cathode outlet (8). According to the invention, the oxygen concentration is measured at least at one point in the flow path of the cathode gas and/or the anode gas by means of a lambda sensor and the flows of anode and/or cathode gas are adjusted depending on the result of the oxygen concentration measurement. The process is especially advantageous in controlling the gas composition in the operation of a fuel cell arrangement in which part of the cathode exhaust gas is returned from the cathode outlet (8) to the cathode inlet (7) and at least a part of the anode exhaust gas from the anode outlet (6) is mixed with the returned cathode gas.
摘要翻译：有一种操作数上的阳极入口供应到燃料电池的阳极（5）的燃料气体中，说明燃料电池（1）的构成的燃料电池组件，到阳极输出（6）阳极废气从阳极中排出的方法中，在阴极输入（7）供给到燃料电池的阴极，并在阴极出口（8）从所述阴极排出的阴极废气的阴极气体。根据本发明，通过λ探针的装置中的氧浓度至少测定在阴极气体和/或阳极气体和阳极气体和/或阴极气体的响应于对氧浓度的测量值的流的流动路径的一个点进行调整。特别有利的是控制在其返回的阴极废气的一部分从阴极出口（8）阴极入口（7）和至少一个阳极排气气体从所述阳极出口部分的燃料电池装置的操作中的气体组合物的方法，（6）与再循环的阴极气体混合。

10. 发明申请

WO1997006572A1 MOLTEN CARBONATE FUEL CELL 审中-公开
标题翻译：熔融碳酸盐燃料电池
公开(公告)号：WO1997006572A1
公开(公告)日：1997-02-20
申请号：PCT/EP1996003471
申请日：1996-08-06
申请人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH , NITSCHKE, Felix , SÖLLNER, Oliver , ROSSA, Helmut , PETERHANS, Stefan
发明人： MTU MOTOREN- UND TURBINEN-UNION FRIEDRICHSHAFEN GMBH
IPC分类号： H01M08/14
CPC分类号： H01M8/142 , H01M4/8626 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： The invention concerns a fuel cell having a porous matrix layer impregnated with a molten alkali-metal carbonate, the matrix layer being bordered on one side by a porous anode layer and on the other side by a porous cathode layer. The area of the cathode/matrix interface (5) is greater than the area of the projection of this interface on a surface (2) with the same lateral limits as the cathode/matrix interface.
摘要翻译：本发明是具有多孔的燃料电池，由邻近的多孔阳极层的一侧上的Alkalicarbonatschmelze基质层和在另一侧上润湿多孔阴极层。阴极界面/基体的区域（5）比其上的面（2）与形成的界面阴极/矩阵的横向边界投影大。

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