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    • 10. 发明申请
    • METHOD FOR PREPARATION OF HIGH POLARITY CROSSLINKABLE POLYMER
    • 高极性可交联聚合物的制备方法
    • WO2012060688A1
    • 2012-05-10
    • PCT/MY2011/000138
    • 2011-06-23
    • MIMOS BERHADMOHD RAIS, AhmadROSIYAH, YahyaAHMAD DANIAL, Azzahari
    • MOHD RAIS, AhmadROSIYAH, YahyaAHMAD DANIAL, Azzahari
    • C08F220/26C08F220/18C08F224/00C08F2/06C08F220/32G01N27/40
    • C08F2/06C08F220/18C08F220/26C08F220/32C08F224/00
    • The present invention relates to a method of preparing high polarity crosslinkable co-polymer comprises the steps of: a) purifying the methyl methacrylate, glycidyl methacrylate and tetrahydrofurfuryl acrylate monomers by washing with saturated sodium bicarbonate solution, drying with sodium sulfate, magnesium sulfate and stirring over BaO or P 2 O 5 or CaH 2 followed by distillation at atmopheric pressure or under reduced pressure; b) mixing appropriate ratios of methyl methacrylate, glycidyl methacrylate and tetrahydrofurfuryl acrylate monomers; c) adding 1 to 5 parts of benzene or toluene solvent to the total volume of the methyl methacrylate, glycidyl methacrylate and tetrahydrofurfuryl acrylate monomers; d) adding 3mg to 0.3g of benzoyl peroxide catalyst to the reaction mixture; e) refluxing the reaction mixture at 80 to 100°C for 2 to 20 hours under blanket of argon or purified nitrogen gas; and f) decanting the remaining benzene or toluene solvent, washing the crosslink-able MGT co-polymer with petroleum ether.
    • 本发明涉及制备高极性可交联共聚物的方法,包括以下步骤:a)通过用饱和碳酸氢钠溶液洗涤,用硫酸钠,硫酸镁干燥并搅拌,纯化甲基丙烯酸甲酯,甲基丙烯酸缩水甘油酯和丙烯酸四氢糠酯单体 超过BaO或P2O5或CaH2,然后在大气压或减压下蒸馏; b)混合甲基丙烯酸甲酯,甲基丙烯酸缩水甘油酯和丙烯酸四氢糠酯单体的适当比例; c)向甲基丙烯酸甲酯,甲基丙烯酸缩水甘油酯和丙烯酸四氢糠酯单体的总体积中加入1至5份苯或甲苯溶剂; d)向反应混合物中加入3mg至0.3g过氧化苯甲酰催化剂; e)将反应混合物在80至100℃下在氩气或纯化氮气保护下回流2至20小时; 和f)倾析剩余的苯或甲苯溶剂,用石油醚洗涤可交联的MGT共聚物。