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    • 1. 发明申请
    • ESTER POLYMER, PRODUCTION THEREOF, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR MADE THEREFROM
    • ESTER聚合物,其生产和电子照相机
    • WO1993022361A1
    • 1993-11-11
    • PCT/JP1993000576
    • 1993-04-30
    • IDEMITSU KOSAN CO., LTD.NAGAO, TomohiroSAKAMOTO, ShujiMORISHITA, HironobuMIYAMOTO, Hideyuki
    • IDEMITSU KOSAN CO., LTD.
    • C08G63/00
    • C08G64/12C08G63/64C08G63/6856G03G5/0564G03G5/075G03G5/076
    • An ester polymer composed of solely the following repeating units (I): -(-W-X-O-CO-)- or both of the repeating units (I) and (II) and having a reduced viscosity [ eta sp/C] of 0.2-10.0 dl/g as measured with a solution thereof in methylene chloride at a concentration of 0.5 g/dl at 20 DEG C; a process for producing the ester polymer by the reaction of a dihydric phenol (III): HO-X-OH or a mixture of dihydric phenols (III) and (IV) with a carbonate-forming compound or a dibasic acid; and an electrophotographic photoreceptor comprising a photosensitive layer provided on a conductive support, wherein the ester polymer is used as a charge transport substance or a binder resin in the photosensitive layer. In said formulae, W represents -O- or a single bond; X represents a divalent group derived from a dihydric phenol containing a hydrazine structure; R and R represent each halogen, alkyl, cycloalkyl or aryl; m and n represents each an integer of 0 to 4; and Y represents a single bond, -O-, -S-, -SO-, -SO2-, -CR R -, 1,1-cycloalkylene or a alpha , omega -alkylene.
    • 仅由以下重复单元(I)组成的酯聚合物: - ( - WXO-CO - ) - 或重复单元(I)和(II)两者,并且具有0.2- 在20℃下用其在二氯甲烷中的溶液以0.5g / dl的浓度测量为10.0dl / g; 通过二元酚(III):HO-X-OH或二元酚(III)和(IV)的混合物与形成碳酸酯的化合物或二元酸反应制备酯聚合物的方法; 以及包含设置在导电性支持体上的感光层的电子照相感光体,其中,所述酯聚合物用作感光层中的电荷输送物质或粘合剂树脂。 在所述式中,W表示-O-或单键; X表示由含有肼结构的二元酚衍生的二价基团; R 25和R 26分别代表卤素,烷基,环烷基或芳基; m和n表示0〜4的整数。 并且Y表示单键,-O - , - S - , - SO - , - SO 2 - ,-CR 27 R 28 - ,1,1-亚环烷基或α,ω-亚烷基。