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    • 1. 发明申请
    • ALKYLTHIO-, ALKYLSULPHINYL- AND ALKYLSULPHONYLCARBAMATES AS HERBICIDES
    • 阿尔茨海默病,阿尔茨海默病和阿尔茨海默氏病作为除草剂
    • WO1998008810A1
    • 1998-03-05
    • PCT/EP1997004626
    • 1997-08-25
    • NOVARTIS AGREMPFLER, HermannMÜHLEBACH, MichelCEDERBAUM, Fredrik
    • NOVARTIS AG
    • C07C323/43
    • C07D333/48A01N47/12C07C309/66C07C317/28C07C323/43C07C323/60C07C2601/02C07C2601/08C07C2601/14C07C2601/16C07D309/04C07D333/20
    • Compounds of formula (I) in which R is halogen, C1-C3haloalkyl, cyano, nitro or C1-C3haloalkoxy; Z is hydrogen, halogen or together with R, -O-CF2-O-; R1 is C1-C5alkyl or C3-C6cycloalkyl; R2 and R3 independently of one another are hydrogen, C1-C4alkyl or C3-C6cycloalkyl; R4 is C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C3-C6cycloalkyl or C5- or C6-cycloalkenyl, or is C1-C4alkyl, C2-C6alkenyl, C2-C6alkynyl or C3-C6cycloalkyl, each of which is substituted by halogen, cyano, C1-C4alkyl-CO, phenyl-CO, COOR5, C1-C4alkoxy, C1-C4haloalkoxy, oxiranyl, dioxolanyl, tetrahydrofuranyl, tetrahydropyranyl, C3-C6cycloalkyl, halo-C3-C6-cycloalkyl, phenyl or phenoxy, it being possible for the phenyl group, in turn, to be substituted by halogen, C1-C3alkyl, C1-C4alkoxy, cyano or C1-C3haloalkyl, or is phenyl or phenyl which is substituted by halogen, C1-C3alkyl, C1-C4alkoxy, cyano or C1-C3haloalkyl; or R4 together with one of the R2 groups forms a C2-C6alkylene bridge; R5 is C1-C5alkyl or C3-C6cycloalkyl; n is the number 1, 2, or 3 and m is thenumber 0, 1 or 2; and the diastereomers and enantiomers of these compounds are suitable as herbicides.
    • 其中R是卤素,C 1 -C 3卤代烷基,氰基,硝基或C 1 -C 3卤代烷氧基的式(I)化合物; Z是氢,卤素或与R,-O-CF2-O-一起; R1是C1-C5烷基或C3-C6环烷基; R2和R3彼此独立地是氢,C1-C4烷基或C3-C6环烷基; R4是C1-C6烷基,C2-C6链烯基,C2-C6炔基,C3-C6环烷基或C5-或C6-环烯基,或是C1-C4烷基,C2-C6链烯基,C2-C6炔基或C3-C6环烷基,其各自被卤素 ,氰基,C 1 -C 4烷基-CO,苯基-CO,COOR 5,C 1 -C 4烷氧基,C 1 -C 4卤代烷氧基,环氧乙烷基,二氧戊环基,四氢呋喃基,四氢吡喃基,C 3 -C 6环烷基,卤代C 3 -C 6环烷基,苯基或苯氧基 苯基被卤素,C 1 -C 3烷基,C 1 -C 4烷氧基,氰基或C 1 -C 3卤代烷基取代,或被苯基或被卤素,C 1 -C 3烷基,C 1 -C 4烷氧基,氰基或C 1 -C 4烷氧基取代的苯基 -C3haloalkyl; 或R4与一个R2基团形成C2-C6亚烷基桥; R5是C1-C5烷基或C3-C6环烷基; n为1,2或3,m为0,1或2, 并且这些化合物的非对映异构体和对映异构体适用作除草剂。