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2. 发明申请

WO1990005159A1 CONDENSATION PRODUCTS BASED ON COLOPHONIUM MALEIC IMIDES 审中-公开
标题翻译：基于Colophonium马来酰亚胺的冷凝产品
公开(公告)号：WO1990005159A1
公开(公告)日：1990-05-17
申请号：PCT/EP1989001297
申请日：1989-10-31
申请人： BASF LACKE + FARBEN AG , PRANTL, Bernhard , FRANK, Erich , KOCH, Walter , LÖBBERT, Gerd
发明人： BASF LACKE + FARBEN AG
IPC分类号： C08G73/16
CPC分类号： C09D11/102 , C08G73/16 , C09F1/04
摘要： Condensation products based on colophonium maleic imides are obtained by A) reaction of 100 parts by weight of colophonium with 1 to 20 parts by weight of maleic anhydride at a temperature between 150 and 250°C; B) reaction of the adduct (A) formed in step A with an amino alcohol containing a primary amine group at temperatrues of 130 to 250 °C, in a molar ratio of anhydride groups to amino groups of 0.8 to 1.2:1; C) if necessary, further condensation of the condensation product (B) at a temperature between 180 and 300°C and/or D) if necessary, further reaction of the condensation product (B) or (C) formed in step B or C with a dimeric and/or trimeric fatty acid at temperatures between 150 and 300°C, in a molar ratio of hydroxyl groups of the condensation product (B) or (C) to carboxylic groups of the fatty acid from 0.1 to 1.2:1 and E) reaction of the condensation product (B), (C) or (D) formed in step B, C or D with a polyalcohol of functionality 3 to 6 at temperatures between 230 and 300°C, in a molar ratio of carboxylic groups to hydroxyl groups of 0.7 to 1.5:1.
摘要翻译：所述产品通过以下步骤获得：（A）将100重量份的松香与1至20重量份的马来酸酐在150至250℃的温度下转化; （B）在130-250℃的温度下用伯氨基醇将相（A）中得到的加合物再转化，酸酐基和氨基之间的摩尔比在0 ，8和1.2为1; （C）适当时，在180-300℃的温度下缩合缩合产物（B）; 和/或（D）如果合适的话，用二聚体和/或三聚体脂肪酸在阶段（B）或（C）期间获得的缩合产物（B）或 150℃和300℃，缩合产物（B）或（C）的羟基与脂肪酸的羧基之间的摩尔比为1至0.1至1.2; 和（E）将在阶段（B），（C）或（D）期间获得的缩合产物（B），（C）或（D）再转变成官能度为3-6 在230和300℃之间的温度下，羧基和羟基之间的摩尔比在1和0.7之间为1.5。

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