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1. 发明申请

WO2012169390A1 TUNGSTEN OXIDE PHOTOCATALYST AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：氧化钨光催化剂及其制备方法
公开(公告)号：WO2012169390A1
公开(公告)日：2012-12-13
申请号：PCT/JP2012/063827
申请日：2012-05-23
申请人： SHOWA DENKO K.K. , HOSOGI Yasuhiro , KURODA Yasushi
发明人： HOSOGI Yasuhiro , KURODA Yasushi
IPC分类号： B01J35/00 , B01J37/00 , B01J21/06 , B01J23/888 , B01J37/03
CPC分类号： B01J23/888 , B01J21/063 , B01J35/0013 , B01J35/002 , B01J35/004 , B01J37/00 , B01J37/033 , B82Y40/00 , Y10S977/779 , Y10S977/811 , Y10S977/892
摘要： The present invention relates to a method for producing a tungsten oxide photocatalyst having titanium oxide and copper ion supported thereon, comprising dissolving urea in a solution in which copper-ion supporting tungsten oxide particles are uniformly dispersed in a titanium oxide sol, thermally decomposing the urea to thereby allow the titanium oxide to precipitate on the surface of copper ion-supporting tungsten oxide and to be supported thereon; and a tungsten oxide photocatalyst modified by both titanium oxide and copper ion obtained by the method, wherein the rate of change of diffuse reflectivity (at wavelength of 700 nm) is less than 3% before and after the irradiation of ultraviolet and the titanium oxide is supported on the tungsten oxide in an island shape of 1 to 100 nm in size. The tungsten oxide photocatalyst having titanium oxide and copper ion supported thereon of the present invention exhibits high catalyst activity under visible light irradiation.
摘要翻译：本发明涉及一种其上负载有氧化钛和铜离子的氧化钨光催化剂的制造方法，其特征在于，将尿素溶解在氧化钛溶胶中均匀分散有铜离子的氧化钨粒子的溶液中，从而允许氧化钛在负载有铜离子的氧化钨的表面上沉淀并负载在其上; 以及通过该方法获得的氧化钛和铜离子改性的氧化钨光催化剂，其中在紫外线照射前后的漫反射率（波长700nm）的变化率小于3％，氧化钛为负载在尺寸为1〜100nm的岛状的氧化钨上。本发明的负载有氧化钛和铜离子的氧化钨光催化剂在可见光照射下显示出高的催化剂活性。

2. 发明申请

WO0216031A3 CATALYST FOR AMMOXIDATION AND METHOD FOR PRODUCING NITRILE COMPOUND USING THE CATALYST 审中-公开
标题翻译：用于氨氧化的催化剂和用催化剂生产腈类化合物的方法
公开(公告)号：WO0216031A3
公开(公告)日：2002-07-04
申请号：PCT/JP0107155
申请日：2001-08-21
申请人： SHOWA DENKO KK , KURODA YASUSHI , OHMORI YOKO , TSUJI KATSUYUKI , NOZAWA TSUTOMU , NAKAJO TETSUO , TAKEHIRA KATSUOMI
发明人： KURODA YASUSHI , OHMORI YOKO , TSUJI KATSUYUKI , NOZAWA TSUTOMU , NAKAJO TETSUO , TAKEHIRA KATSUOMI
IPC分类号： B01J23/22 , B01J23/26 , B01J37/02 , C07C253/28 , C07C255/51 , C07C253/26
CPC分类号： C07C253/28 , B01J23/22 , B01J23/26 , B01J37/0236 , B01J2523/00 , C07C255/51 , B01J2523/23 , B01J2523/55 , B01J2523/67 , B01J2523/69 , B01J2523/31 , B01J2523/41
摘要： An ammoxidation catalyst is provided, characterized in that a crystalline composite oxide containing vanadium and chromium and having a specific powder X-ray diffraction peak pattern is used as the catalyst component in practicing gas phase ammoxidation of an organic compound having an alkyl group. Also provided are a method for producing a nitrile compound using the catalyst and a method for evaluating the performance of a gas phase ammoxidation catalyst using powder X-ray diffraction.
摘要翻译：提供了一种氨氧化催化剂，其特征在于，在实施具有烷基的有机化合物的气相氨氧化反应中，使用含有钒和铬且具有特定粉末X射线衍射峰图案的结晶复合氧化物作为催化剂组分。还提供了使用该催化剂制备腈化合物的方法和使用粉末X射线衍射评估气相氨氧化催化剂性能的方法。

3. 发明申请

WO2011013850A1 PHOTOCATALYTIC MATERIALS AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：光化学材料及其制造方法
公开(公告)号：WO2011013850A1
公开(公告)日：2011-02-03
申请号：PCT/JP2010/063231
申请日：2010-07-29
申请人： THE UNIVERSITY OF TOKYO , SHOWA DENKO K.K. , HASHIMOTO, Kazuhito , IRIE, Hiroshi , YU, Huogen , KURODA, Yasushi , HOSOGI, Yasuhiro
发明人： HASHIMOTO, Kazuhito , IRIE, Hiroshi , YU, Huogen , KURODA, Yasushi , HOSOGI, Yasuhiro
IPC分类号： C01G23/053 , C01G23/07 , B01J23/06 , B01J23/30 , B01J23/888
CPC分类号： C01G23/053 , B01J21/063 , B01J23/002 , B01J23/30 , B01J23/72 , B01J23/888 , B01J35/002 , B01J35/004 , B01J37/031 , B01J2523/00 , C01G23/07 , C01P2002/52 , B01J2523/32 , B01J2523/47 , B01J2523/69
摘要： The present invention relates to a photocatalytic material having a visible light activity which includes a tungsten-doped titanium oxide or a tungsten/gallium-codoped titanium oxide, and a divalent copper salt and/or a trivalent iron salt supported on a surface of the doped or codoped titanium oxide, and a process for producing the photocatalytic material.
摘要翻译：本发明涉及具有可见光活性的光催化材料，其包括掺杂钨的氧化钛或钨/镓共掺杂的氧化钛，以及二价铜盐和/或三价铁盐，其负载在掺杂的或共掺二氧化钛，以及制备光催化材料的方法。

4. 发明申请

WO1997050135A1 HYDROGEN STORING ALLOY ELECTRODE AND PROCESS FOR PRODUCING HYDROGEN STORAGE ALLOY ELECTRODE 审中-公开
标题翻译：氢存储合金电极及其生产氢存储合金电极的工艺
公开(公告)号：WO1997050135A1
公开(公告)日：1997-12-31
申请号：PCT/JP1997002146
申请日：1997-06-20
申请人： SANYO ELECTRIC CO., LTD. , ISE, Tadashi , FUKUDA, Hiroshi , IMOTO, Teruhiko , KATO, Kikuko , KURODA, Yasushi , HIGASHIYAMA, Nobuyuki , MATSUURA, Yoshinori , KIMOTO, Mamoru , NOGAMI, Mitsuzou , FUJITANI, Shin , YONEZU, Ikuo , NISHIO, Koji
发明人： SANYO ELECTRIC CO., LTD.
IPC分类号： H01M04/26
CPC分类号： H01M4/366 , H01M4/383 , Y10T29/49115
摘要： A highly efficient and effective activating method by which the electrochemical activity of a hydrogen storage alloy is improved and a hydrogen storage alloy electrode having an excellent initial internal pressure characteristic, low-temperature discharge characteristic, high-rate discharge characteristic, and cycle characteristic and manufactured by using the activating method. A process for producing a hydrogen storage alloy electrode includes an alloy activating step in which a hydrogen storage alloy is dipped in strong acidic solution containing metallic ions and the pH value rise of the solution is accelerated by adding an alkali to the solution.
摘要翻译：提高储氢合金的电化学活性的高效有效的活化方法和具有优异的初始内压特性，低温放电特性，高倍率放电特性和循环特性的储氢合金电极，并制成通过使用激活方法。制备储氢合金电极的方法包括合金活化步骤，其中将储氢合金浸入含有金属离子的强酸性溶液中，并通过向溶液中加入碱来加速溶液的pH值升高。

5. 发明申请

WO2011111848A3 METHOD AND APPARATUS FOR PRODUCING METAL OXIDE PARTICLES 审中-公开
公开(公告)号：WO2011111848A3
公开(公告)日：2011-09-15
申请号：PCT/JP2011/055864
申请日：2011-03-07
申请人： NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY , SHOWA DENKO K.K. , OHTANI Bunsho , SUGISHITA Noriyuki , KURODA Yasushi
发明人： OHTANI Bunsho , SUGISHITA Noriyuki , KURODA Yasushi
IPC分类号： C01B13/22 , C01G23/07 , C01G1/02
摘要： There is provided a method and an apparatus for producing metal oxide particles, which produce metal oxide particles having a high photocatalytic activity with high yield. The method for producing metal oxide particles of the invention is characterized by including combining, in a reaction tube, a preheated metal chloride-containing gas with a preheated first gas which does not contain the metal chloride at a first junction to obtain a first combined gas, and combining the first combined gas with a preheated second gas which does not contain the metal chloride, at a second junction which is further downstream of the first junction, to obtain a second combined gas, wherein at least one of the metal chloride-containing gas and the first gas contains oxygen, and wherein the preheated metal chloride-containing gas is further heated in a region between the first junction and the second junction (referred to as first reaction zone), by combining the first gas with the metal chloride-containing gas at the first junction while setting the preheat temperature of the first gas at a temperature equal to or higher than the preheat temperature of the metal chloride-containing gas, and the first combined gas is further heated in a region downstream of the second junction by combining the second gas with the first combined gas at the second junction while setting the preheat temperature of the second gas at a temperature equal to or higher than the temperature of the first combined gas.

6. 发明申请

WO2011043496A2 COPPER ION-MODIFIED TITANIUM OXIDE AND PROCESS FOR PRODUCING THE SAME, AND PHOTOCATALYST 审中-公开
标题翻译：铜改性氧化钛及其制造方法和光催化剂
公开(公告)号：WO2011043496A2
公开(公告)日：2011-04-14
申请号：PCT/JP2010/068223
申请日：2010-10-08
申请人： THE UNIVERSITY OF TOKYO , SHOWA DENKO K. K. , HASHIMOTO, Kazuhito , IRIE, Hiroshi , HOSOGI, Yasuhiro , KURODA, Yasushi
发明人： HASHIMOTO, Kazuhito , IRIE, Hiroshi , HOSOGI, Yasuhiro , KURODA, Yasushi
CPC分类号： B01J21/063 , B01J23/72 , B01J35/002 , B01J35/004 , B01J35/006 , B01J37/033 , B82Y30/00 , C01G23/00 , C01G23/047 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2004/64
摘要： The present invention relates to a copper ion-modified titanium oxide including titanium oxide whose surface is modified with a copper ion, and containing a brookite-type crystal; a process for producing a copper ion-modified titanium oxide, including a hydrolysis step of subjecting a titanium compound capable of producing titanium oxide to hydrolysis in a reaction solution, and a surface modification step of mixing a solution obtained after the hydrolysis with an aqueous solution containing a copper ion to modify a surface of the titanium oxide therewith; and a photocatalyst containing the copper ion-modified titanium oxide in an amount of 70% by mass or more.
摘要翻译：本发明涉及一种包含氧化钛的铜离子改性氧化钛，其表面用铜离子改性，并含有板钛矿型结晶; 一种生产铜离子改性氧化钛的方法，包括使能够生产氧化钛的钛化合物在反应溶液中水解的水解步骤，以及将水解后获得的溶液与水溶液混合的表面改性步骤含有铜离子以改性氧化钛的表面; 以及含有70质量％以上的铜离子改性氧化钛的光催化剂。

7. 发明申请

WO2011043496A3 COPPER ION-MODIFIED TITANIUM OXIDE AND PROCESS FOR PRODUCING THE SAME, AND PHOTOCATALYST 审中-公开
标题翻译：铜改性氧化钛及其制造方法和光催化剂
公开(公告)号：WO2011043496A3
公开(公告)日：2012-01-05
申请号：PCT/JP2010068223
申请日：2010-10-08
申请人： UNIV TOKYO , SHOWA DENKO KK , HASHIMOTO KAZUHITO , IRIE HIROSHI , HOSOGI YASUHIRO , KURODA YASUSHI
发明人： HASHIMOTO KAZUHITO , IRIE HIROSHI , HOSOGI YASUHIRO , KURODA YASUSHI
IPC分类号： B01J23/72
CPC分类号： B01J21/063 , B01J23/72 , B01J35/002 , B01J35/004 , B01J35/006 , B01J37/033 , B82Y30/00 , C01G23/00 , C01G23/047 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2004/64
摘要： The present invention relates to a copper ion-modified titanium oxide including titanium oxide whose surface is modified with a copper ion, and containing a brookite-type crystal; a process for producing a copper ion-modified titanium oxide, including a hydrolysis step of subjecting a titanium compound capable of producing titanium oxide to hydrolysis in a reaction solution, and a surface modification step of mixing a solution obtained after the hydrolysis with an aqueous solution containing a copper ion to modify a surface of the titanium oxide therewith; and a photocatalyst containing the copper ion-modified titanium oxide in an amount of 70% by mass or more.
摘要翻译：本发明涉及一种包含氧化钛的铜离子改性氧化钛，其表面用铜离子改性，并含有板钛矿型结晶; 一种生产铜离子改性氧化钛的方法，包括使能够生产氧化钛的钛化合物在反应溶液中水解的水解步骤，以及将水解后获得的溶液与水溶液混合的表面改性步骤含有铜离子以改性氧化钛的表面; 以及含有70质量％以上的铜离子改性氧化钛的光催化剂。

8. 发明申请

WO2011111848A2 METHOD AND APPARATUS FOR PRODUCING METAL OXIDE PARTICLES 审中-公开
标题翻译：用于生产金属氧化物颗粒的方法和装置
公开(公告)号：WO2011111848A2
公开(公告)日：2011-09-15
申请号：PCT/JP2011055864
申请日：2011-03-07
申请人： UNIV HOKKAIDO NAT UNIV CORP , SHOWA DENKO KK , OHTANI BUNSHO , SUGISHITA NORIYUKI , KURODA YASUSHI
发明人： OHTANI BUNSHO , SUGISHITA NORIYUKI , KURODA YASUSHI
IPC分类号： C01B13/22
CPC分类号： C01B13/22 , C01G1/02 , C01G23/07 , C01P2002/30 , C01P2004/03 , C01P2006/12 , C01P2006/90
摘要： There is provided a method and an apparatus for producing metal oxide particles, which produce metal oxide particles having a high photocatalytic activity with high yield. The method for producing metal oxide particles of the invention is characterized by including combining, in a reaction tube, a preheated metal chloride-containing gas with a preheated first gas which does not contain the metal chloride at a first junction to obtain a first combined gas, and combining the first combined gas with a preheated second gas which does not contain the metal chloride, at a second junction which is further downstream of the first junction, to obtain a second combined gas, wherein at least one of the metal chloride-containing gas and the first gas contains oxygen, and wherein the preheated metal chloride-containing gas is further heated in a region between the first junction and the second junction (referred to as first reaction zone), by combining the first gas with the metal chloride-containing gas at the first junction while setting the preheat temperature of the first gas at a temperature equal to or higher than the preheat temperature of the metal chloride-containing gas, and the first combined gas is further heated in a region downstream of the second junction by combining the second gas with the first combined gas at the second junction while setting the preheat temperature of the second gas at a temperature equal to or higher than the temperature of the first combined gas.
摘要翻译：提供了一种生产金属氧化物颗粒的方法和设备，其以高产率生产具有高光催化活性的金属氧化物颗粒。本发明的金属氧化物粒子的制造方法的特征在于，在反应管中，将预热的含金属氯化物的气体与在第一接合处不含有金属氯化物的预热的第一气体组合，得到第一组合气体并且在第二结合处将第一组合气体与不含金属氯化物的预热的第二气体组合，以获得第二组合气体，其中至少一种含金属氯化物的气体，第一气体含有氧，并且其中预热的含金属氯化物的气体在第一接合点和第二接合点（称为第一反应区域）之间的区域中进一步加热，通过将第一气体与金属氯化物 - 在将第一气体的预热温度设定为等于或高于金属氯化物c的预热温度的温度的同时，通过在第二连接处组合第二气体与第一组合气体，将第一组合气体在第二接合点的下游区域进一步加热，同时将第二气体的预热温度设定在等于或高于第一组合气体的温度。

9. 发明申请

WO2005003035A3 SOL CONTAINING TITANIUM DIOXIDE, THIN FILM FORMED THEREFROM AND PRODUCTION PROCESS OF THE SOL 审中-公开
标题翻译：包含二氧化钛的SOL，其形成的薄膜和SOL的生产工艺
公开(公告)号：WO2005003035A3
公开(公告)日：2005-03-31
申请号：PCT/JP2004009888
申请日：2004-07-05
申请人： SHOWA DENKO KK , WAKIZAKA YASUAKI , KURODA YASUSHI
发明人： WAKIZAKA YASUAKI , KURODA YASUSHI
IPC分类号： B01J21/06 , B01J23/42 , B01J23/52 , B01J23/745 , B01J35/00 , B01J35/10 , B01J37/02 , B01J37/03 , C01G20060101 , C01G23/00 , C01G23/053 , C09C1/36
CPC分类号： B01J35/004 , B01J21/063 , B01J21/066 , B01J23/42 , B01J23/52 , B01J23/745 , B01J35/1014 , B01J35/1019 , B01J37/0219 , B01J37/033 , B82Y30/00 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2004/64 , C01P2006/12 , C01P2006/60 , C09C1/3607 , C09C1/3661
摘要： A sol comprising a precipitated component in an amount of less than 10 mass% based on the total solid content of the sol and comprising titanium oxide comprising a transition metal compound. When the sol is mixed with a binder which can be hardened at ambient temperature, the mixture readily forms a thin film having high photocatalytic performance on a substrate of poor heat resistance such as plastics or paper. The titanium oxide sol can readily forms titanium oxide thin film on surfaces of a variety of substrate materials such as ceramics, glass, metal, plastics, wood, or paper. Articles to which photocatalytic performance or hydrophilicity is imparted include building materials, fluorescent lamps, glass panes, machinery, vehicles, glass products, household electrical appliances, water purifying apparatuses, agricultural materials, electronic apparatus, tools, tableware, bath products, toiletry products, furniture, clothing, cloth products, fibers, leather products, paper products, sporting goods, beauty-related instruments, health improvement instruments, medical goods, futon, containers, eyeglasses, signboards, piping, wiring, brackets, sanitary materials, and automobile parts as well as environmental purification apparatuses/units.
摘要翻译：一种溶胶，其包含基于所述溶胶的总固体含量小于10质量％的沉淀组分，并包含包含过渡金属化合物的氧化钛。当溶胶与可在环境温度下硬化的粘合剂混合时，混合物容易在耐热性差的基材上形成具有高光催化性能的薄膜，例如塑料或纸。氧化钛溶胶可以容易地在各种基材如陶瓷，玻璃，金属，塑料，木材或纸张的表面上形成氧化钛薄膜。赋予光催化性能或亲水性的制品包括建筑材料，荧光灯，玻璃板，机械，车辆，玻璃制品，家用电器，净水装置，农用材料，电子仪器，工具，餐具，沐浴用品，化妆品，家具，服装，布制品，纤维，皮革制品，纸制品，运动用品，美容仪器，健康改善仪器，医疗用品，日式，集装箱，眼镜，招牌，管道，布线，支架，卫生材料和汽车部件以及环境净化设备/单位。

10. 发明申请

WO2005003035A2 SOL CONTAINING TITANIUM DIOXIDE, THIN FILM FORMED THEREFROM AND PRODUCTION PROCESS OF THE SOL 审中-公开
标题翻译：含有二氧化钛的溶胶，由其形成的薄膜及其制造方法
公开(公告)号：WO2005003035A2
公开(公告)日：2005-01-13
申请号：PCT/JP2004/009888
申请日：2004-07-05
申请人： SHOWA DENKO K.K. , WAKIZAKA, Yasuaki , KURODA, Yasushi
发明人： WAKIZAKA, Yasuaki , KURODA, Yasushi
IPC分类号： C01G
CPC分类号： B01J35/004 , B01J21/063 , B01J21/066 , B01J23/42 , B01J23/52 , B01J23/745 , B01J35/1014 , B01J35/1019 , B01J37/0219 , B01J37/033 , B82Y30/00 , C01G23/047 , C01G23/0536 , C01P2002/72 , C01P2004/64 , C01P2006/12 , C01P2006/60 , C09C1/3607 , C09C1/3661
摘要： A sol comprising a precipitated component in an amount of less than 10 mass% based on the total solid content of the sol and comprising titanium oxide comprising a transition metal compound. When the sol is mixed with a binder which can be hardened at ambient temperature, the mixture readily forms a thin film having high photocatalytic performance on a substrate of poor heat resistance such as plastics or paper. The titanium oxide sol can readily forms titanium oxide thin film on surfaces of a variety of substrate materials such as ceramics, glass, metal, plastics, wood, or paper. Articles to which photocatalytic performance or hydrophilicity is imparted include building materials, fluorescent lamps, glass panes, machinery, vehicles, glass products, household electrical appliances, water purifying apparatuses, agricultural materials, electronic apparatus, tools, tableware, bath products, toiletry products, furniture, clothing, cloth products, fibers, leather products, paper products, sporting goods, beauty-related instruments, health improvement instruments, medical goods, futon, containers, eyeglasses, signboards, piping, wiring, brackets, sanitary materials, and automobile parts as well as environmental purification apparatuses/units.
摘要翻译：包含基于溶胶的总固体含量小于10质量％的量的沉淀组分并且包含含有过渡金属化合物的氧化钛的溶胶。当溶胶与可在环境温度下硬化的粘合剂混合时，该混合物容易在耐热性差的基材如塑料或纸上形成具有高光催化性能的薄膜。氧化钛溶胶可容易地在陶瓷，玻璃，金属，塑料，木材或纸等各种基板材料的表面上形成氧化钛薄膜。具有光催化性能或亲水性的物品包括建筑材料，荧光灯，玻璃窗，机械，车辆，玻璃制品，家用电器，净水器，农业材料，电子设备，工具，餐具，沐浴产品，化妆品，家具，服装，布料制品，纤维，皮革制品，纸制品，体育用品，美容相关器具，健康改善工具，医疗用品，被褥，容器，眼镜，招牌，管道，接线，支架，卫生材料和汽车部件以及环境净化设备/单元。

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