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    • 5. 发明申请
    • METHOD OF PRODUCING FATTY ALCOHOLS FROM VEGETABLE OILS BY FRACTIONAL DISTILLATION
    • 用于生产脂肪醇蔬菜基地通过分级
    • WO1995011210A1
    • 1995-04-27
    • PCT/EP1994003348
    • 1994-10-12
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIENKÖHLER, MichaelSCHMID, Karl-HeinzDEMMERING, GüntherKOMP, Horst-DieterKUBERSKY, Hans-Peter
    • HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
    • C07C29/80
    • C11D3/2031A61K8/342A61K8/97A61Q5/00A61Q19/00C07C29/149C07C31/125C07C33/025C11D3/2013C11D3/202C07C33/02
    • The invention concerns a method of producing fatty alcohols with an iodine number between 20 and 110 from vegetable oils, the alcohols consisting essentially of unsaturated fatty alcohols or mixtures of saturated and unsaturated fatty alcohols of the general formula (I): R OH, in which R is a saturated or unsaturated straight-chain or branched-chain alkyl group with 8 to 22 carbon atoms. Using prior art methods, the triglycerides contained in the vegetable-oil raw materials are (a) decomposed under pressure into the constituent fatty acids and optionally esterified with methanol or (b) transesterified to give the fatty-acid methyl esters and (c) the fatty acids or fatty-acid methyl esters are hydrogenated to give fatty alcohols. The method is characterized in that the fatty acids, the fatty-acid methyl esters and/or their hydrogenation products are fractionally distilled and the first runnings taken from the distillation, the end product having an iodine number from 20 to 110. The invention also concerns fatty alcohols produced from vegetable oils having an iodine number from 20 to 95 and the use of fatty alcohols produced from vegetable oils in the manufacture of washing, rinsing and cleaning agents as well as hair-care and body-care agents.
    • 基于具有20和110之间的碘值,其基本上包括不饱和脂肪醇,饱和和不饱和脂肪醇与通式(I)R <1> OH的混合物,其中R <1>表示饱和或植物用于生产脂肪醇的方法 不饱和的,直链或碳原子数为8〜22的支链烷基,包括,其中以已知的方式被切割,所述甘油三酯包含a)该植物脂肪由高压分解原料中的脂肪酸和任选地与甲醇酯化的或b)在脂肪酸甲酯 摩尔)加成的酯交换和c是脂肪酸或脂肪酸甲基酯与脂肪醇,其特征在于,所述脂肪酸,所述脂肪酸甲基酯和/或产物可以从氢化被分馏,由流动的量除去,使得最终产物具有的碘值 从20至110,并且包括基于植物的脂肪醇 具有20和95之间的碘值和用于生产洗衣洗涤剂,餐具洗涤剂和清洁剂的头发和身体护理使用脂肪醇。