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    • 8. 发明申请
    • USE OF COPOLYMERS BASED ON ETHYLENICALLY UNSATURATED DICARBOXYLIC ACIDS OR DICARBOXYLIC ACID ANHYDRIDES, LOWER OLEFINS AND HYDROPHOBIC COMONOMERS FOR AFTER-TANNING, STUFFING OR WATERPROOFING LEATHER AND FURS
    • 共聚物的使用基于烯属不饱和二羧酸或二羧酸酐,低级烯烃和疏水共聚单体为复鞣,脂肪或防水皮革和毛皮
    • WO1997037046A1
    • 1997-10-09
    • PCT/EP1997001593
    • 1997-03-27
    • BASF AKTIENGESELLSCHAFTKNEIP, MichaelKISTENMACHER, AxelDANISCH, PeterWOLF, Gerhard
    • BASF AKTIENGESELLSCHAFT
    • C14C09/00
    • C09D123/08C14C9/00
    • The invention concerns the use of aqueous solutions or dispersions of copolymers which are obtained by the radical copolymerization of: (a) between 20 and 90 wt % of at least one monoethylenically unsaturated C4-C6 dicarboxylic acid or its anhydride as component A; (b) between 5 and 50 wt % of at least one C2-C6 olefin as component B; (c) between 5 and 50 wt % of at least one hydrophobic comonomer selected from the group comprising the long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, amides of long-chain amides with acrylic acid or methacrylic acid and the long-chain alkylvinyl ethers as component C; and (d) between 0 and 40 wt % of further comonomers which can be copolymerized with the above monomers as component D; the total of the amounts of components A, B, C and optionally D being 100 wt %. This copolymerization process is followed by at least partial esterification or hydrolysis and neutralizing and/or reaction with bases of the carboxyl groups which occur during hydrolysis. These solutions or dispersions are used for treating leather and/or furs.
    • 水溶液或由(a)的20〜90重量%的至少一种单烯不饱和C 4 -C 6二羧酸或其酸酐,作为组分A的%自由基共聚获得的共聚物的分散体; (B)5至50重量%的至少一种具有2至6个碳原子,作为组分Bα-烯烃; (C)5至50重量选自长链烯烃,长链醇与丙烯酸或甲基丙烯酸,长链酰胺与丙烯酸或甲基丙烯酸和长链烷基乙烯基醚作为组分C的酰胺的酯中的至少一种疏水性共聚单体的%; (D)其他单体0〜40重量%共聚的上述单体的共聚单体作为组分D,其中组分A的量的总和,B,C以及任选地D是100重量%,和随后至少部分酯化或水解和 中和和/或用碱在水解过程中形成的羧基的反应,可用于处理皮革和/或毛皮。
    • 10. 发明申请
    • AQUEOUS SOLUTIONS OR DISPERSIONS OF COPOLYMERS
    • 水溶液或COPOLYMERIZATES的分散体
    • WO1995020056A1
    • 1995-07-27
    • PCT/EP1995000144
    • 1995-01-16
    • BASF AKTIENGESELLSCHAFTBIRKHOFER, HermannKNEIP, MichaelDANISCH, PeterDENZINGER, WalterKISTENMACHER, AxelHARTMANN, Heinrich
    • BASF AKTIENGESELLSCHAFT
    • C14C09/00
    • C08J3/03C08F220/18C08F222/06C14C9/02
    • Aqueous solutions or dispersions of copolymers obtainable by the radical copolymerisation of A ) 50 to 60 mol% C6 to C40 mono-olefines or C6 to C40 alkyl vinyl ethers or mixtures of C6 to C40 alkyl vinyl ethers and up to 50 mol%, in relation to the entire quantity of the component A , C6 to C40 mono-olefines with B ) 60 to 40 mol% of monoethylenically unsaturated C4-C8 dicarboxylic acid anhydrides, or by the radical copolymerisation of A ) 50 to 90 wt % C6 to C40 alkyl acrylates or methyl acrylates or vinyl esters of C6 to C40 carboxylic acids or mixtures thereof with B ) 10 to 50 wt % of monoethylenically unsaturated C3 to C12 carboxylic acids, monoethylenically unsaturated C4 to C12 dicarboxylic acid anhydrides, semi-ester or semi-amides of monoethylenically unsaturated C4 to C12 dicarboxylic acids, amides of monoethylenically unsaturated C3 to C12 carboxylic acids or mixtures thereof, to form copolymers with molar masses of 500 to 30,000 whereby the carboxyl groups present in an aqueous medium are at least partly neutralised and part of the carboxyl groups may be amidated, and which are characterised by an emulsifier content of 0.5 to 40 wt % in relation to the quantity of copolymer. These aqueous solutions or dispersions are suitable for stuffing and fulling leathers and fur pelts.
    • 水溶液或由A <1>)40至60摩尔%的C6至C40单烯烃或C6至C40烷基乙烯基醚或C6的混合物至C40烷基乙烯基醚的自由基共聚获得的共聚物的水分散体和至多50 摩尔%,基于组分的总量A <1>,C6具有乙<1>)为60〜40摩尔%的单烯属不饱和C4至C8二羧酸酐C40单烯烃或者被A的自由基共聚<2> )从50至90重量%的C6至C40烷基的丙烯酸酯或甲基丙烯酸酯或C6乙烯酯至C40羧酸或它们的混合物与乙它们的<2>)10至50重量单烯不饱和C3的%至C12羧酸 单烯类不饱和C4至C12二羧酸酐,单酯或单烯类不饱和C4的单酰胺至C 12二羧酸,单烯不饱和C3的酰胺至C 12 - 羧酸或它们的混合物与500和3之间的分子量的共聚物 可用的是0.000,其中,所述羧基基团存在于至少部分地中和的水性介质中,并且可以是羧酸基团的一部分酰胺化,并且其特征在于的含量为0.5〜40重量%,基于共聚物的量的乳化剂, 是。 这些水性溶液或分散液适合于加脂和填充皮革和毛皮。