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    • 4. 发明申请
    • POSITIVE-WORKING, THERMALLY SENSITIVE IMAGEABLE ELEMENT
    • 积极的工作,敏感的图像元素
    • WO2005100419A1
    • 2005-10-27
    • PCT/US2005/010139
    • 2005-03-25
    • KODAK POLYCHROME GRAPHICS LLCRAY, KevinKITSON, Anthony, PaulKALAMEN, John
    • RAY, KevinKITSON, Anthony, PaulKALAMEN, John
    • C08F212/32
    • C08F220/44B41C1/1008B41C1/1016B41C2210/02B41C2210/06B41C2210/14B41C2210/20B41C2210/22B41C2210/24B41C2210/262B41M5/368C08F220/56Y10S430/145
    • Alkali solute copolymers, imageable elements useful as lithographic printing plate precursors that contain the alkali solute copolymers, and methods for forming images using the imageable elements are disclosed. The alkali soluble copolymers comprise, in polymerized form: (a) N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, or a mixture thereof; (b) acrylamide, methacrylamide, or a mixture thereof; (c) acrylonitrile, methacrylonitrile, or a mixture thereof; and (d) one or more monomers selected from the group consisting of monomers of the structure: CH 2 =C(R)-Z-X-NHC(O)NH-Y-R', in which: X is -[C (CH 3 ) 2 ]- or -[(CH 2 ) n ]-, in which n is 0 to 12; Y is o-, m-, or p- -[C 6 H 4 ]-; Z is -[C(O)O]-, -[C(O)NH]-, or o-, m-, or p-[-C 6 H 4 )-; R is hydrogen or C 1 to C 4 alkyl; R' is -OC(O)-OR", -OC(O)-Ar, or -OSO 2 -Ar; R" is C 1 to C 12 alkyl, C 1 to C 12 arylalkyl, C 1 to C 12 aryl, C 1 to C 12 alkenyl, or trimethylsilyl; Ar is C 6 H 5-n’ T n’ , in which Ar has a total of six to ten carbon atoms, each T is independently selected from the group consisting of C 1 to C 4 alkyl, fluoro, chloro, bromo, iodo, trifluoromethyl, methoxy, and cyano; and n' is an integer from 0 to 5; and in which the copolymer is soluble in alkaline solutions having a pH greater than at least about 11.
    • 公开了碱性溶质共聚物,可用作含有碱性溶质共聚物的平版印刷版前体的可成像元素,以及使用可成像元件形成图像的方法。 碱溶性共聚物以聚合形式包含:(a)N-苯基马来酰亚胺,N-环己基马来酰亚胺,N-苄基马来酰亚胺或其混合物; (b)丙烯酰胺,甲基丙烯酰胺或其混合物; (c)丙烯腈,甲基丙烯腈或其混合物; 和(d)一种或多种选自以下结构单体的单体:CH 2 = C(R)-ZX-NHC(O)NH-Y-R',其中:X是 - [C(CH 3) 2] - 或 - [(CH 2)n] - ,其中n为0至12; Y是O-,m-或对 - [C 6 H 4] - ; Z是 - [C(O)O] - , - [C(O)NH] - 或o-,m-或对 - [-C 6 H 4) - ; R是氢或C 1至C 4烷基; R'是-OC(O)-OR“,-OC(O)-Ar或-OSO 2 -Ar; R”是C 1至C 12烷基,C 1至C 12芳烷基,C 1至C 12芳基,C 1至C 12链烯基或 三甲基; Ar为C6H5-n'Tn',其中Ar具有总共6至10个碳原子,每个T独立地选自C1至C4烷基,氟,氯,溴,碘,三氟甲基,甲氧基和 氰基; 并且n'是0至5的整数; 并且其中共聚物可溶于pH大于至少约11的碱性溶液中。