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    • 2. 发明申请
    • RECYCLED METHOD FOR A WASTED POLYMER WHICH IS MIXED POLYESTER POLYAMIDE AND RECLAIMED MATERIALS THEREOF
    • 混合聚酰亚胺及其回收材料的复合聚合物的回收方法
    • WO2005092963A1
    • 2005-10-06
    • PCT/KR2005/000851
    • 2005-03-24
    • KIM, do gyunKIM, hyosung
    • KIM, do gyunKIM, hyosung
    • C08J11/24
    • C08J11/24C08J2367/00C08J2377/00Y02W30/706
    • The present invention relates to a recycling method of a mixed waste of polyester and polyamide (hereinafter, referred to as "mixed waste") in which polyesters including polyethylene terephthalate and polyamides are inseparable from one another. In accordance with the recycling method of the present invention, it is possible to prepare a solid block polymer having an acid value of 1 to 150 mgKOH/g, a weight average molecular weight of 3,000 to 50,000 and a softening point of 10 to 150°C, or a liquid polyester-amide block polymer composition having good compatibility, solubility and dispersibility. In addition, the polymer having an acid value of more than 20 mgKOH/g is reacted with a basic compound to form a neutralized salt which is then used to prepare a water-soluble polyester-amide block polymer composition. The prepared water-soluble polyester-amide block polymer composition can be utilized as industrially useful material such as synthetic resin fine particles, microcapsules, adsorbents, polymerization toner binders for electron photography, fiber processing agents, sizing agents for use in paper-making and paper strength agents, wastewater treatment agents, dispersants, cement admixtures, inkjet ink binders, epoxy resin curing agents and modifiers, water-dispersible epoxy resin curing agents and modifiers. The solid or liquid polyester-amide block polymer composition having an acid value of less than 10 mgKOH/g can be employed as industrially useful material such as printer ink, coating materials, powder paints, adhesives, hot melt adhesives, binders for toner manufactured by grinding methods, waterproofing agents, unsaturated polyester-amide resins, and polyurethane resins.
    • 本发明涉及聚酯和聚酰胺(以下称为“混合废料”)的混合废弃物的再循环方法,其中包括聚对苯二甲酸乙二醇酯和聚酰胺在内的聚酯彼此不可分离。 根据本发明的回收方法,可以制备酸值为1〜150mgKOH / g,重均分子量为3,000〜50,000,软化点为10〜150℃的固体嵌段聚合物 C或具有良好相容性,溶解性和分散性的液体聚酯 - 酰胺嵌段聚合物组合物。 此外,酸值大于20mgKOH / g的聚合物与碱性化合物反应形成中和盐,然后将其用于制备水溶性聚酯 - 酰胺嵌段聚合物组合物。 制备的水溶性聚酯 - 酰胺嵌段聚合物组合物可用作工业上有用的材料,例如合成树脂细颗粒,微胶囊,吸附剂,用于电子照相的聚合调色剂粘合剂,纤维加工剂,用于造纸和纸的上浆剂 强化剂,废水处理剂,分散剂,水泥混合物,喷墨油墨粘合剂,环氧树脂固化剂和改性剂,水分散性环氧树脂固化剂和改性剂。 具有酸值小于10mgKOH / g的固体或液体聚酯 - 酰胺嵌段聚合物组合物可用作工业上有用的材料,例如印刷油墨,涂料,粉末涂料,粘合剂,热熔粘合剂,由 研磨方法,防水剂,不饱和聚酯酰胺树脂和聚氨酯树脂。
    • 3. 发明申请
    • POLYOL INCLUDED PHOSPHORUS AND NITROGEN
    • 多元醇包含磷和氮
    • WO2009002100A3
    • 2008-12-31
    • PCT/KR2008/003661
    • 2008-06-25
    • KIM, Do-GyunKIM, Hyosung
    • KIM, Do-GyunKIM, Hyosung
    • C08G18/28
    • Provided are a phosphorus- and nitrogen-containing polyol composition, a method of preparing the same, and flame-retardant polyol for polyurethane, using the phosphorus- and nitrogen-containing polyol composition. In particular, provided are a phosphorus- and nitrogen-containing polyol which has a structure in which, in the molecule of polyol, phosphorus is co-bound to a hydroxyl group of polyol and an amino group of a nitrogen compound by a chemical reaction, and is prepared to comprise 1-20% of phosphorus and 1-17% of nitrogen, thereby obtaining excellent stability, compatibility with other polyols, reactivity, and flame-retardant characteristics, and a method of preparing the same.
    • 本发明提供使用含磷和氮的多元醇组合物的含磷和含氮多元醇组合物,其制备方法和用于聚氨酯的阻燃多元醇。 特别是提供一种含磷和氮的多元醇,其具有在多元醇分子中通过化学反应将磷与多元醇的羟基和氮化合物的氨基共结合的结构, 并且被制备成包含1-20%的磷和1-17%的氮,由此获得优异的稳定性,与其它多元醇的相容性,反应性和阻燃特性,以及制备该方法的方法。
    • 4. 发明申请
    • POLYOLS AND POLYURETHANES, POLYURETHANEFORMS USING THE SAME
    • 聚氨酯和聚氨酯,使用它的聚氨酯
    • WO2006080743A1
    • 2006-08-03
    • PCT/KR2005/003366
    • 2005-10-10
    • KIM, Do GyunKIM, Hyosung
    • KIM, Do GyunKIM, Hyosung
    • C08J11/18
    • C08J11/22C08G18/4018C08G18/4288C08G18/4833C08G18/606C08G18/6492C08G2101/0025C08J2367/02C08J2375/04C08J2377/00Y02W30/706
    • The present invention relates to a preparing method of polyols and polyurthane, polyurethaneforms using the same by depolymerizing the polyester, polyamide and polyurethane with the polymeric fatty acid monopoly hydroxyl alcoholide, and additionally react with the polybasic acid, polyol and amine to prepare acid value of 0.5~lDKOH/g, hydroxyl value of 10~500DKOH/g, and amine value of l~50DKOH/g in polyol, and polyurethane and polyurethaneforms using the same. This is to transform the double bond of the unsaturated fatty acid from the component of the oils and fats in conjugate double bond to induce the Diesl-Alder reaction, and with the improvement of the reactivity to form stability combination in chemical structure to prevent the separate leaching appearance of fatty and fatty oil from the final product, and having the fine compatibility with the polyether-polyol as well as transparent and storage stability. Furthermore, it has 100% of solid with very low viscosity at the room temperature for easy handling while having a great reactivity with the isocyanate that this preparing polyol having excellent chemical and mechanical properties. And, in particular, by recycling the waste edible oil and waste synthetic resin that can be employed as industrially useful material for environment-friendly and economical advantage.
    • 本发明涉及多元醇和聚氨酯的制备方法,通过使聚酯,聚酰胺和聚氨酯与聚合的脂肪酸聚合的羟基醇聚合物解聚而使用聚酯,聚酰胺和聚氨酯,并且还与多元酸,多元醇和胺进行反应以制备其酸值 0.5〜lKOH / g,羟基值为10〜500DKOH / g,多元醇中胺值为1〜50DKOH / g,聚氨酯和聚氨酯成型体使用。 这是将不饱和脂肪酸的双键从共轭双键中的油和脂肪的成分转化为诱导Diesl-Alder反应,并且随着反应性的提高,形成化学结构中的稳定性组合以防止分离 从最终产品中浸出脂肪和脂肪油,并且与聚醚多元醇具有良好的相容性以及透明和储存稳定性。 此外,它具有100%的固体,在室温下具有非常低的粘度,易于处理,同时与异氰酸酯具有很大的反应性,该制备的多元醇具有优异的化学和机械性能。 特别是通过循环使用可以作为工业上有用的材料的废食用油和废合成树脂,具有环保和经济的优点。