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1. 发明申请

WO2011087231A3 PREPARATION METHOD OF SOLID CATALYST FOR PROPYLENE POLYMERIZATION, AND CATALYST PREPARED THEREBY 审中-公开
标题翻译：丙烯聚合用固体催化剂的制备方法及其制备的催化剂
公开(公告)号：WO2011087231A3
公开(公告)日：2011-11-10
申请号：PCT/KR2010009557
申请日：2010-12-30
申请人： SAMSUNG TOTAL PETROCHEMICALS , KIM SANG YULL , LEE JIN WOO , KIM EUN IL , PARK JOON RYEO
发明人： KIM SANG YULL , LEE JIN WOO , KIM EUN IL , PARK JOON RYEO
IPC分类号： C08F4/654 , C08F4/656 , C08F10/06
CPC分类号： C08F110/06 , C08F10/06 , Y02P20/52 , C08F4/651 , C08F4/6565
摘要： The present invention relates to a preparation method of a solid catalyst for propylene polymerization, and a catalyst prepared thereby, and more specifically, to a preparation method of a solid catalyst for propylene polymerization which can polymerize polypropylene having excellent stereoregularity with a high yield by using a silane-based compound, and an acycloalkane dicarboxylate-based or acycloalkene dicarboxylate-based internal electron donor, and a catalyst prepared thereby.
摘要翻译：本发明涉及用于丙烯聚合的固体催化剂的制备方法，以及由此制备的催化剂，更具体地说，涉及一种用于丙烯聚合的固体催化剂的制备方法，该方法可以通过使用可以高收率地立体规整性优异的聚丙烯基于硅烷的化合物和基于二羧酸环烷二羧酸酯或基于环烯烃二羧酸酯的内部电子供体，以及由此制备的催化剂。

2. 发明申请

WO2009084799A1 METHOD OF PREPARATION OF SPHERICAL SUPPORT FOR OLEFIN POLYMERIZATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂球形支撑剂的制备方法
公开(公告)号：WO2009084799A1
公开(公告)日：2009-07-09
申请号：PCT/KR2008/005375
申请日：2008-09-11
申请人： SAMSUNG TOTAL PETROCHEMICALS CO., LTD. , KIM, Eun-Il , LEE, Young-Joo , JUNG, Hoe-Chul , PARK, Joon-Ryeo
发明人： KIM, Eun-Il , LEE, Young-Joo , JUNG, Hoe-Chul , PARK, Joon-Ryeo
IPC分类号： C08F4/02
CPC分类号： C08F4/022 , C08F10/00
摘要： Provided is a method of preparation of dialkoxy magnesium that is used as a support for an olefin polymerization catalyst for polyolefin preparation. Specifically, provided is a method of preparation of a support for an olefin polymerization catalyst, which comprises preparation of dialkoxy magnesium by reacting magnesium metal with alcohol in the presence of a reaction initiator, wherein bromine is used as the reaction initiator so as to obtain spherical dialkoxy magnesium.
摘要翻译：提供了用作聚烯烃制备用烯烃聚合催化剂的载体的二烷氧基镁的制备方法。具体地，提供了一种制备烯烃聚合催化剂载体的方法，其包括在反应引发剂存在下，使镁金属与醇反应制备二烷氧基镁，其中使用溴作为反应引发剂，以获得球形二烷氧基镁。

3. 发明申请

WO2006004296A1 METHOD OF POLYMERIZATION OF OLEFIN AND OLEFIN/ ALPHA-OLEFIN USING ARYLOXY-BASED OLEFIN- (CO)POLYMERIZATION CATALYST 审中-公开
标题翻译：烯丙基 - （CO）聚合催化剂聚合烯烃和烯烃/烯丙醇的方法
公开(公告)号：WO2006004296A1
公开(公告)日：2006-01-12
申请号：PCT/KR2005/000941
申请日：2005-03-31
申请人： SAMSUNG TOTAL PETROCHEMICALS CO., LTD. , KIM, Eun-Il , CHANG, Ho-Sik
发明人： KIM, Eun-Il , CHANG, Ho-Sik
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/651 , C08F4/6548 , C08F2500/12 , C08F210/14
摘要： The present invention provides a method of polymerization of olefin or copolymerization of olefin/alpha-olefin using transition metal compound with an oxidation number of 3 as a catalyst and organo-aluminum compound as a cocatalyst, wherein the transition metal compound with an oxidation number of 3 is produced by reacting organo-magnesium compound with a compound which is formed by reacting transition metal compound having aryloxy group with an oxidation number of 4 or more with external electron donor. According to the present invention, an olefin (co)polymer with a narrow molecular weight distribution is obtained.
摘要翻译：本发明提供使用氧化数为3的过渡金属化合物作为催化剂和有机铝化合物作为助催化剂的烯烃聚合方法或烯烃/α-烯烃的共聚合，其中氧化数为 3是通过使有机镁化合物与通过与外部电子给体氧化数为4以上的具有芳氧基的过渡金属化合物反应形成的化合物而制备的。根据本发明，得到分子量分布窄的烯烃（共）聚合物。

4. 发明申请

WO2010005164A2 METHOD FOR CONTROLLING SIZE OF SPHERICAL CARRIER FOR OLEFIN POLYMERIZATION CATALYST 审中-公开
标题翻译：控制烯烃聚合催化剂球形载体尺寸的方法
公开(公告)号：WO2010005164A2
公开(公告)日：2010-01-14
申请号：PCT/KR2009001958
申请日：2009-04-16
申请人： SAMSUNG TOTAL PETROCHEMICALS , KIM EUN-IL , KIM JONG-SIK , KANG SOL , PARK JOON-RYEO
发明人： KIM EUN-IL , KIM JONG-SIK , KANG SOL , PARK JOON-RYEO
IPC分类号： B01J35/08
CPC分类号： C08F10/00 , C08F110/06 , C08F4/02 , C08F4/6548 , C08F2500/15 , C08F2500/18
摘要： The present invention relates to a method for controlling the size of a dialkoxy magnesium carrier used in the manufacture of an olefin polymerization catalyst. More specifically, the present invention relates to a method for controlling the size of a dialkoxy magnesium carrier for an olefin polymerization catalyst by injecting metallic magnesium and alcohol in 1-3 times and reacting them, when the dialkoxy magnesium carrier is prepared by reacting the metallic magnesium with alcohol in the presence of a magnesium halide or nitrogen-halogen compound as a reaction initiator.
摘要翻译：本发明涉及一种控制用于制造烯烃聚合催化剂的二烷氧基镁载体的尺寸的方法。更具体地说，本发明涉及一种通过在金属镁和醇中注入1-3次并控制烯烃聚合催化剂的二烷氧基镁载体的尺寸并使它们反应的方法，当二烷氧基镁载体通过使金属镁与醇在卤化镁或氮 - 卤素化合物存在下作为反应引发剂。

5. 发明申请

WO2006033513A1 CATALYST FOR OLEFIN POLYMERIZATION INCLUDING PHENOXY LIGAND AND METHOD OF (CO) POLYMERIZATION OF OLEFIN USING THE SAME 审中-公开
标题翻译：用于烯烃聚合的催化剂，包括苯氧基配体和使用其的烯烃（CO）聚合方法
公开(公告)号：WO2006033513A1
公开(公告)日：2006-03-30
申请号：PCT/KR2005/000943
申请日：2005-03-31
申请人： SAMSUNG TOTAL PETROCHEMICALS CO., LTD. , KIM, Eun-Il , CHANG, Ho-Sik
发明人： KIM, Eun-Il , CHANG, Ho-Sik
IPC分类号： C08F4/64
CPC分类号： B01J31/0214 , B01J2231/122 , C08F10/00 , C08F110/02 , C08F4/6546 , C08F4/6548 , C08F2500/12 , C08F2500/19
摘要： The present invention provides a Ziegler-Natta catalyst for olefin polymerization comprising transition metal compound containing aryloxy ligand and transition metal with the oxidation number of 3 from Group IV, V or VI of the Periodic Table of Elements which is prepared by the reduction of transition metal compound containing at least two aryloxy ligands and transition metal with the oxidation number of 4 or more from Group IV, V or VI of the Periodic Table, and an olefin (co)polymerization method using the same as a main catalyst. According to the present invention, it is possible to provide a Ziegler-Natta catalyst for olefin polymerization having high polymerization activity, as compared with conventional catalysts of transition metal compounds comprising transition metal compound containing transition metal with the oxidation number of 3, and a method for preparing olefin (co)polymer having broad molecular weight distribution by using the same with high activity.
摘要翻译：本发明提供用于烯烃聚合的齐格勒 - 纳塔催化剂，其包含含有芳氧基配体的过渡金属化合物和通过还原过渡金属制备的元素周期表IV，V或VI族的氧化数为3的过渡金属含有至少两个芳氧基配位体的化合物和周期表第Ⅳ，Ⅴ或Ⅵ族氧化数为4以上的过渡金属的化合物和使用该芳氧基的主要催化剂的烯烃（共）聚合方法。根据本发明，与含氧化数为3的含有过渡金属的过渡金属化合物的过渡金属化合物的常规催化剂相比，可以提供具有高聚合活性的烯烃聚合的齐格勒 - 纳塔催化剂，用于制备具有高活性的具有宽分子量分布的烯烃（共）聚合物。

6. 发明申请

WO2005049659A1 ZIEGLER-NATTA CATALYST FOR OLEFIN POLYMERIZATION INCLUDING ARYLOXY GROUP AND METHOD FOR POLYMERIZATION OF OLEFIN USING THE SAME 审中-公开
标题翻译：用于烯烃聚合的ZIEGLER-NATTA催化剂，包括芳族聚酰胺基团和使用该烯烃聚合的烯烃的方法
公开(公告)号：WO2005049659A1
公开(公告)日：2005-06-02
申请号：PCT/KR2004/002127
申请日：2004-08-24
申请人： SAMSUNG ATOFINA CO. LTD. , KIM, Eun-Il , CHANG, Ho-Sik
发明人： KIM, Eun-Il , CHANG, Ho-Sik
IPC分类号： C08F4/643
CPC分类号： C08F10/00 , C08F110/02 , C08F4/6546 , C08F4/6548 , C08F2500/12 , C08F2500/18
摘要： The present invention relates to a Ziegler-Natta catalyst for olefin polymerization and a method for polymerization of olefin using the same. Specifically, the invention relates to a Ziegler-Natta catalyst for olefin polymerization, which is produced by a method comprising a step of reacting a transition metal compound in which the transition metal having an oxidation number of 4 or more is selected from Groups IV, V or VI of the Periodic table and two or more aryloxy ligands are bound to the transition metal, with an organomagnesium compound, to reduce said transition metal compound to a reduced form in which the transition metal has an oxidation number of 3, and a method for polymerization of olefin using said catalyst.
摘要翻译：本发明涉及用于烯烃聚合的齐格勒 - 纳塔催化剂和使用其的烯烃聚合方法。具体地说，本发明涉及一种用于烯烃聚合的齐格勒 - 纳塔催化剂，该催化剂是通过一种方法制备的，该方法包括使氧化数为4以上的过渡金属选自IV，V族的过渡金属化合物或VI，并且两个或更多个芳氧基配体与有机镁化合物结合到过渡金属上，以将所述过渡金属化合物还原为其中过渡金属的氧化数为3的还原形式，以及用于使用所述催化剂聚合烯烃。

7. 发明申请

WO2012070753A3 SOLID CATALYST FOR THE POLYMERIZATION OF PROPYLENE, AND METHOD FOR PREPARING SAME 审中-公开
标题翻译：用于丙烯聚合的固体催化剂及其制备方法
公开(公告)号：WO2012070753A3
公开(公告)日：2012-07-19
申请号：PCT/KR2011006528
申请日：2011-09-02
申请人： SAMSUNG TOTAL PETROCHEMICALS , KIM SANG YULL , LEE JIN WOO , KIM EUN IL , PARK JOON RYEO
发明人： KIM SANG YULL , LEE JIN WOO , KIM EUN IL , PARK JOON RYEO
IPC分类号： C08F4/654 , C08F10/06
CPC分类号： C08F10/00 , C08F110/06 , Y02P20/52 , C08F4/651 , C08F2500/15
摘要： The present invention relates to a solid catalyst for the polymerization of propylene and to a method for preparing same, and more particularly, to a solid catalyst for the polymerization of propylene, which can polymerize polypropylene which does not contain substances that are harmful to the environment, and which has excellent stereoregularity with a high yield by using a bicycloalkene dicarboxylate-based internal electron donor, and to a method for preparing the solid catalyst.
摘要翻译：本发明涉及一种用于丙烯聚合的固体催化剂及其制备方法，更具体地说，涉及用于聚合聚丙烯的固体催化剂，其可聚合不含有对环境有害的物质的聚丙烯并且通过使用基于二碳烯二羧酸酯的内电子给体具有优异的立构规整性和高产率，以及制备固体催化剂的方法。

8. 发明申请

WO2011071237A2 MANUFACTURING METHOD OF SOLID CATALYST FOR PROPYLENE POLYMERIZATION 审中-公开
标题翻译：丙烯聚合用固体催化剂的制造方法
公开(公告)号：WO2011071237A2
公开(公告)日：2011-06-16
申请号：PCT/KR2010006720
申请日：2010-10-01
申请人： SAMSUNG TOTAL PETROCHEMICALS , KIM SANG YULL , PARK JOON RYEO , KIM EUN IL , LEE JIN WOO
发明人： KIM SANG YULL , PARK JOON RYEO , KIM EUN IL , LEE JIN WOO
IPC分类号： C08F4/654 , B01J21/06 , C08F4/32 , C08F10/06
CPC分类号： C08F110/06 , Y02P20/52 , C08F2500/12 , C08F2500/03 , C08F4/6548 , C08F4/651
摘要： The present invention relates to a manufacturing method of a solid catalyst for propylene polymerization, and more specifically to a manufacturing method of the solid catalyst for propylene polymerization, which has a high melt flow index and broad molecular weight distribution, and can polymerize polypropylene having superior tacticity in high yield.
摘要翻译：丙烯聚合用固体催化剂的制造方法技术领域本发明涉及丙烯聚合用固体催化剂的制造方法，特别涉及熔体流动指数高，分子量分布宽的聚丙烯聚合用固体催化剂的制造方法，高产量的立体性。

9. 发明申请

WO2009075461A1 METHOD OF PREPARATION OF SPHERICAL SUPPORT FOR OLEFIN POLYMERIZATION CATALYST 审中-公开
标题翻译：烯烃聚合催化剂球形支撑剂的制备方法
公开(公告)号：WO2009075461A1
公开(公告)日：2009-06-18
申请号：PCT/KR2008/005374
申请日：2008-09-11
申请人： SAMSUNG TOTAL PETROCHEMICALS CO., LTD. , KIM, Eun-Il , LEE, Young-Joo , JUNG, Hoe-Chul , PARK, Joon-Ryeo
发明人： KIM, Eun-Il , LEE, Young-Joo , JUNG, Hoe-Chul , PARK, Joon-Ryeo
IPC分类号： C08F4/02
CPC分类号： C08F10/00 , C08F4/022
摘要： Provided is a method of preparation of a spherical support for an olefin polymerization catalyst. Specifically, provided is a method of preparation of a support which can be used in preparation of an olefin polymerization catalyst, wherein, MgX(I)(X=halogen atom) is prepared by reacting a reaction initiator, nitrogen halide, and magnesium metal, and then magnesium metal and alcohol are reacted in the presence of the MgX, thereby resulting a smooth-surfaced spherical dialkoxy magnesium support having a uniform particle size distribution.
摘要翻译：提供了一种制备用于烯烃聚合催化剂的球形载体的方法。具体地说，提供了可用于制备烯烃聚合催化剂的载体的制备方法，其中通过使反应引发剂，氮
卤化物和镁金属反应制备MgX（I）（X =卤素原子）然后在MgX存在下镁金属和醇反应，从而得到具有均匀粒度分布的光滑表面的球形二烷氧基镁载体。

10. 发明申请

WO2008133382A1 CATALYST FOR POLYMERIZATION OF PROPYLENE AND METHOD FOR POLYMERIZATION OF PROPYLENE USING THE SAME 审中-公开
标题翻译：用于丙烯聚合的催化剂和使用该丙烯聚合丙烯的方法
公开(公告)号：WO2008133382A1
公开(公告)日：2008-11-06
申请号：PCT/KR2007/005463
申请日：2007-10-31
申请人： SAMSUNG TOTAL PETROCHEMICALS CO., LTD. , KIM, Eun-Il , LEE, Young-Ju , JUNG, Hoe-Chul , PARK, Joon-Ryeo
发明人： KIM, Eun-Il , LEE, Young-Ju , JUNG, Hoe-Chul , PARK, Joon-Ryeo
IPC分类号： C08F4/64 , C08F4/654
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F4/651 , C08F4/6548 , C08F2500/15 , C08F2500/12 , C08F2500/18 , C08F4/02
摘要： Provided are a catalyst for polymerization of propylene and a method for polymerization of propylene using the same. Specifically, provided are a catalyst for propylene polymerization which comprises titanium tetrachloride, an internal electron donor, and dialkoxy magnesium particles, as a carrier, obtained from the reaction of a halogen compound or nitrogen-halogen compound as a reaction initiator, metal magnesium and an alcohol, and a method for propylene polymerization using the same.
摘要翻译：提供了丙烯的聚合催化剂和使用其的丙烯聚合方法。具体地说，提供了一种用于丙烯聚合的催化剂，其包括由作为反应引发剂的卤素化合物或氮 - 卤素化合物的反应获得的作为载体的四氯化钛，内部电子给体和二烷氧基镁颗粒，金属镁和醇和使用其的丙烯聚合方法。

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