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1. 发明申请

WO1997027227A1 PROCESS FOR PREPARING POLYMERS OF C2-C10 ALKENES IN THE PRESENCE OF METALLOCENE COMPLEXES WITH CATIONICALLY FUNCTIONALIZED CYCLOPENTADIENYL LIGANDS 审中-公开
标题翻译： PROCESS FOR在金属茂的存在下与阳离子官能化的环戊二烯基PRODUCING的C2至C10烯烃的聚合物
公开(公告)号：WO1997027227A1
公开(公告)日：1997-07-31
申请号：PCT/EP1997000277
申请日：1997-01-22
申请人： BASF AKTIENGESELLSCHAFT , KRISTEN, Marc, Oliver , JUTZI, Peter , REDEKER, Thomas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , Y10S526/943 , C08F4/6392
摘要： The invention concerns a process for preparing polymers of C2-C10 alkenes in the presence of catalyst systems, those which contain: (A) a metallocene complex of general formula (I), at least one of the R groups corresponding to formula (a), in which R is C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl, R and R are hydrogen, C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl, R and R are C1-C10 alkyl, C6-C15 aryl or C3-C10 cycloalkyl, and n is an integer ranging from 0 to 10; and (B) a metallocenium ion-forming compound, as active components being used as catalyst systems.
摘要翻译：一种用于C 2至在催化剂体系的存在下C10烯烃的聚合物的制备过程中被用作含催化剂体系，作为活性成分的（A）通式（I）的茂金属配合物的基团为式R的其中至少一个：（a ）对应，其中R <22>，C1至C10烷基，C6至C15芳基或C3至C10环烷基，R <23>和R <24>为氢，C1至C10烷基，C6 至C15芳基或C3至C10环烷基，R <25>和R <26> C1-C10烷基，C6至C15芳基或C3至C10环烷基，N <2>是一个整数范围从0到10和（B）形成茂金属离子的化合物。

2. 发明申请

WO1993020113A1 CATALYST SYSTEMS FOR POLYMERISING C2 TO C10 ALK-1-ENES 审中-公开
标题翻译：用于聚合C2至C10 ALK-1-ENES的催化剂体系
公开(公告)号：WO1993020113A1
公开(公告)日：1993-10-14
申请号：PCT/EP1993000694
申请日：1993-03-23
申请人： BASF AKTIENGESELLSCHAFT , EVERTZ, Kaspar , SCHLUND, Rueger , SCHWEIER, Guenther , BRINTZINGER, Hans , ROELL, Werner , JUTZI, Peter , MIELING, Ingrid , MENGELE, Winfried
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F04/602
CPC分类号： C07F17/00 , C08F4/61912 , C08F4/61927 , C08F10/00
摘要： Catalyst systems for polymerising C2 to C10 alk-1-enes containing as active components: a) a metallic complex of general formula (I) in which M is a metal of the III, IV or V sub-group of the periodic system or a metal from the lanthanide group; X is fluorine, chlorine, bromine, iodine, hydrogen, C1 to C10 alkyl, C6 to C15 aryl or -OR7, where R7 is C1 to C10 alkyl, C6 to C15 aryl, alkylaryl, arylalkyl, fluoralkyl or fluoraryl with 1 to 10 C atoms in the alkyl radical and 6 to 20 C atoms in the aryl radical; n is the valency of M minus 2; R1 to R6 are hydrogen, C¿1? to C10 alkyl, 5 to 7 membered cycloalkyl which in turn may have a C1 to C10 alkyl as a substituent, C6 to C15 aryl or arylalkyl in which two adjacent radicals may together stand for cyclic groups having 4 to 15 C atoms, or Si(R?8)¿3 where R8 is C1 to C10 alkyl, C6 to C15 aryl or C3 to C10 cycloalkyl; E1, E2 are, independently, Si(R9)2, Ge(R9)2, Sn(R9)2 or C(R9)2-C(R9)2 where R9 is C1 to C10 alkyl, C3 to C10 cycloalkyl or C6 to C15 aryl; and b) is an open-chained or cyclic alumoxane compound of general formula (II) or (III) in which R10 is a C¿1? to C4 alkyl group and m is an integer from 5 to 30.
摘要翻译：用于烯烃-1的C2至C10，含有作为活性成分的聚合催化剂体系：A）通式（I）的金属茂配合物，其中取代基和指数具有以下含义：M是金属亚组III，IV或周期表或镧系元素族的金属的V，X表示氟，氯，溴，碘，氢，C1至C10，芳基C 6 -C 15或-OR 7， R7是烷基C1-C10，芳基C 6 -C 15，烷基芳基，芳基烷基，氟烷基或氟芳基各自为1〜10个碳原子在烷基中和6至20个碳原子的芳基， n为M的以两个，R1至R6表示氢，C1至C10，5至7元环烷基，扣除其可以具有的化合价，反过来，C1至C10作为取代基，一个芳基或C6至C15芳基烷基，其中可能还有两个相邻斯托克斯可一起表示具有4至15个碳原子的环状基团，或Si（R8）3，R8表示C1至C10烷基，C6至C15芳基或C3至C10环烷基，E1，E2 （R 9）2，Ge（R 9）2，Sn（R 9）2或C（R 9）2 -C（R 9）2，其中R 9是C 1 -C 10烷基，一个C3-C10烷基或C6-C15，和b）铝氧烷化合物，以打开或环状链的通式，（II）或（III），其中R 10表示C1中的烷基以C 4和米是5到30之间的整数。

3. 发明申请

WO1993024536A1 CATALYST SYSTEMS FOR POLYMERISING C2- TO C10ALK-1-ENES 审中-公开
标题翻译： C2的催化剂体系聚合，C10-ALK-1恩恩
公开(公告)号：WO1993024536A1
公开(公告)日：1993-12-09
申请号：PCT/EP1993001329
申请日：1993-05-27
申请人： BASF AKTIENGESELLSCHAFT , EVERTZ, Kaspar , SCHLUND, Rueger , JUTZI, Peter , MIELING, Ingrid
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F04/60
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925
摘要： Catalyst systems for polymerising C2 to C10-alk-1-enes contain as active components (a) a metallocene complex having the general formula (I), in which the substituents and indexes have the following meaning: M stands for a metal of the secondary group III, IV or V of the periodic table or for a metal from the group of the lanthanides; X stand for halogen, hydrogen, C1- to C10-alkyl, C3- to C10-cycloalkyl, C6- to C15-aryl, alkylaryl with 7 to 15 C atoms or -OR15, in which R15 stands for C¿1? to C1 to C10-alkyl, C6- to C15-aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroalkyl or fluoroaryl having each 1 to 10 C atoms in the alkyl residue and 6 to 20 C atoms in the aryl residue; n stands for the valency of M, less the number two; R?1 to R14¿ stand for hydrogen, C¿1? to C10-alkyl, C3- to C10-cycloalkyl, which in turn can carry a C1- to C10-alkyl as substituent, C6- to C15-aryl or arylalkyl, whereas if required two adjacent residues may also stand together for cyclic groups having 4 to 15 C atoms, or Si(R?16)¿3, in which R16 stands for C¿1?- to C10-alkyl, C6- to C15-aryl or C3- to C10-cycloalkyl; y?1, y2¿ stand for CH¿2?, C(R?17)¿2, Si(R17)2, Ge(R17)2 or Sn(R17)2, in which R17 stands for C¿1?- to C10-alkyl, C6- to C15-aryl, C3- to C10-cycloalkyl, alkylaryl or Si(R?18)¿3, in which R18 stands for C¿1?- to C10-alkyl, C6- to C15-aryl, C3- to C10-cycloalkyl or alkylaryl; as well as (b) an open-chain or cyclic alumoxane compound having the general formula (II) or (III), in which R?19¿ stands for a C¿1?- to C4-alkyl group and m is an integer between 5 and 30.

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