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    • 6. 发明申请
    • IRIDIUM COMPLEX COMPOUNDS, ORGANIC ELECTROLUMINESCENT DEVICES AND USES THEREOF
    • 有机复合化合物,有机电致发光器件及其用途
    • WO2009011447A2
    • 2009-01-22
    • PCT/JP2008063219
    • 2008-07-16
    • SHOWA DENKO KKIGARASHI TAKESHITAGUCHI ISAMU
    • IGARASHI TAKESHITAGUCHI ISAMU
    • C07F15/00C09K11/06H01L51/50H05B33/14
    • C07F15/0033
    • Blue-emitting phosphorescent compounds show high solubility in solvents for coating solutions in the production of organic EL devices and have excellent thermal stability. Organic EL devices having the blue-emitting phosphorescent compounds have high luminous efficiency and long life. A blue-emitting phosphorescent compound is an iridium complex compound represented by Formula (1) below: wherein R1 is a C2-30 organic group; R2 to R4 are each independently a hydrogen atom or a C1-10 alkyl group; R5 to R8 are each independently an electron-withdrawing group selected from the group consisting of halogen atoms, C1-10 fluorine-substituted alkyl groups, C1-10 fluorine-substituted alkoxy groups, cyano group, aldehyde group, C2-10 acyl groups, C2-10 alkoxycarbonyl groups, C1-10 aminocarbonyl groups, thiocyanate group and C1-10 sulfonyl groups, a C1-10 organic group optionally having a heteroatom (except the electron-withdrawing groups) or a hydrogen atom; and at least one of R5 to R8 is the electron-withdrawing group.
    • 蓝色发光磷光体化合物在有机EL器件制造中在涂布溶液的溶剂中显示出高的溶解性,并且具有优异的热稳定性。 具有蓝色发光性磷光化合物的有机EL元件的发光效率高,寿命长。 蓝色发光磷光体化合物是由下式(1)表示的铱络合物:其中R1是C2-30有机基团; R2至R4各自独立地为氢原子或C1-10烷基; R5至R8各自独立地为选自卤素原子,C 1-10氟取代烷基,C 1-10氟取代烷氧基,氰基,醛基,C 2-10酰基的吸电子基团, C2-10烷氧基羰基,C1-10氨基羰基,硫氰酸酯基和C1-10磺酰基,任选具有杂原子(除吸电子基除外)或氢原子的C 1-10有机基团; 并且R5至R8中的至少一个为吸电子​​基团。