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    • 1. 发明申请
    • METHOD OF DEASHING FROM POLYMER SOLUTIONS
    • 从聚合物溶液中分离的方法
    • WO2007117098A1
    • 2007-10-18
    • PCT/KR2007/001693
    • 2007-04-06
    • LG CHEM, LTD.JUNG, Hye-YoungCHUN, Sung-HoHONG, Sung-DonLEE, Jung-MinKIM, HeonKRAVCHUK, Dmitry
    • JUNG, Hye-YoungCHUN, Sung-HoHONG, Sung-DonLEE, Jung-MinKIM, HeonKRAVCHUK, Dmitry
    • C08F6/08C08F6/06C08J3/00
    • C08F6/02
    • Disclosed is a method of removing a residual catalyst metal compound from a polymer solution. The method comprises the steps of: a) mixing a solution in which at least one organic nitrogen compound is dissolved in a polar solvent and the polymer solution to precipitate a chelate compound of the organic nitrogen compounds and the residual catalyst metal compound, b) adding the polar solvent to the solution mixture to dissolve a chelate compound and to precipitate a polymer, and c) filtering the precipitated polymer. After the polymer polymerization is completed, an organic nitrogen compound solution is added to perform a chelate reaction with the residual catalyst metal compound in a solution phase, and the polar solvent is added to precipitate the polymer so that only polymer precipitates are filtered while an additional filtration process in respect to the chelate compound is not performed to easily remove the residual catalyst metal compound. Thereby, it is possible to produce products that are of good quality.
    • 公开了从聚合物溶液中除去残留的催化剂金属化合物的方法。 该方法包括以下步骤:a)将其中至少一种有机氮化合物溶解在极性溶剂中的溶液与聚合物溶液混合以沉淀有机氮化合物和残余催化剂金属化合物的螯合化合物,b)将 向溶液混合物中加入极性溶剂以溶解螯合物并沉淀聚合物,和c)过滤沉淀的聚合物。 聚合物聚合完成后,加入有机氮化合物溶液以在溶液相中与残留的催化剂金属化合物进行螯合反应,并加入极性溶剂以沉淀聚合物,使得只有聚合物沉淀物过滤,同时另外 相对于螯合化合物的过滤方法不进行以容易除去残留的催化剂金属化合物。 因此,可以生产质量好的产品。
    • 4. 发明申请
    • APPARATUS AND METHOD FOR RECOVERING POLYMER
    • 用于回收聚合物的装置和方法
    • WO2008069569A1
    • 2008-06-12
    • PCT/KR2007/006279
    • 2007-12-05
    • LG CHEM, LTD.HONG, Sung-DonLEE, In-SuLEE, Jong-KuCHUN, Sung-HoPARK, Seung-YoungYOON, Sung-Cheol
    • HONG, Sung-DonLEE, In-SuLEE, Jong-KuCHUN, Sung-HoPARK, Seung-YoungYOON, Sung-Cheol
    • C08J11/00
    • C08J3/12C08J11/04C08J2333/14C08J2365/00Y02P20/143Y02W30/70
    • The present invention provides an apparatus for recovering a polymer from polymer solution, and a method of recovering a polymer using the apparatus. The apparatus includes a polymer solution-storage tank for storing a polymer solution; a polymer solution feeding pump for pumping the polymer solution from the polymer solution storage tank; an antisolvent storage tank for storing an antisolvent; an antisolvent feeding pump for pumping the antisolvent from the antisolvent storage tank; a reaction chamber to which the polymer solution pumped by the polymer solution feeding pump and the antisolvent pumped by the antisolvent feeding pump are supplied; a high-speed mixer that is rotated in the reaction chamber at a speed range of 1000 to 30000 rpm, mixes the polymer solution with the antisolvent under a shearing force cor¬ responding to a tip speed of 5 to 30 m/sec, and precipitates a polymer; and a precipitate storage tank for storing the precipitation mixture of the polymer and the solvent/antisolvent.
    • 本发明提供了一种从聚合物溶液中回收聚合物的装置,以及使用该装置回收聚合物的方法。 该装置包括用于储存聚合物溶液的聚合物溶液 - 储存罐; 用于从聚合物溶液储罐泵送聚合物溶液的聚合物溶液进料泵; 用于储存抗溶剂的抗溶剂储罐; 用于从抗溶剂储罐泵出抗溶剂的反溶剂供给泵; 提供由聚合物溶液供给泵泵送的聚合物溶液和由反溶剂供给泵泵送的反溶剂的反应室; 在1000〜30000rpm的转速范围内在反应室内旋转的高速混合机,在与5〜30m /秒的叶尖速度相对应的剪切力下将聚合物溶液与抗溶剂混合, 聚合物 以及用于储存聚合物和溶剂/反溶剂的沉淀混合物的沉淀储存罐。