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1. 发明申请

WO2010079057A1 MULTI STAGE PROCESS FOR PRODUCING HYDROCARBONS FROM SYNGAS 审中-公开
标题翻译：从SYNGAS生产石油烃的多阶段工艺
公开(公告)号：WO2010079057A1
公开(公告)日：2010-07-15
申请号：PCT/EP2009/067245
申请日：2009-12-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BRACHT, Maarten , HESSELINK, Maarten , NIJST, Christiaan , REMANS, Thomas Joris
发明人： BRACHT, Maarten , HESSELINK, Maarten , NIJST, Christiaan , REMANS, Thomas Joris
IPC分类号： C10G2/00
CPC分类号： C10G2/30 , C10K3/06
摘要： The invention pertains to a multi-stage process for the production of hydrocarbons from syngas comprising hydrogen and carbon monoxide, which comprises the steps of : a) providing a fresh syngas feed to a first stage Fischer-Tropsch reactor and allowing CO and hydrogen to convert into hydrocarbon products at a temperature in the range from 125 to 400°C and a pressure in the range from 5 to 150 bar absolute, and a gaseous hourly space velocity in the range from 500 to 10000 Nl/l/h; b) feeding the effluent from the first stage reactor to a separation unit; c) removing a gasous effluent stream comprising hydrogen and CO from the separation unit; d) removing one or more other streams comprising hydrocarbon and/or water from the separation unit; e) conveying a first portion of the gaseous effluent stream to a second stage Fischer-Tropsch reactor and allowing CO and hydrogen to convert into hydrocarbon products in the second stage Fischer-Tropsch reactor at a temperature in the range from 125 to 400°C and a pressure in the range from 5 to 150 bar absolute, and a gaseous hourly space velocity in the range from 500 to 10000 Nl/l/h, whereby the first stage Fischer-Tropsch reactor and the second stage Fischer-Tropsch reactor are separate reactors; f) feeding the effluent from the second stage Fischer- Tropsch reactor to the separation unit; g) removing a second portion of the gaseous effluent stream as off-gas.
摘要翻译：本发明涉及用于从包含氢气和一氧化碳的合成气生产碳氢化合物的多级方法，其包括以下步骤：a）向新的第一阶段费 - 托反应器提供新的合成气进料并允许CO和氢转化在125至400℃的温度和5至150巴绝对压力范围内的气体产物中，并且气时空速在500至10000Nl / l / h的范围内; b）将来自第一级反应器的流出物供给到分离单元; c）从分离单元中除去包含氢和CO的气体流出物流; d）从分离单元去除包含烃和/或水的一种或多种其它流; e）将第一部分气态流出物流输送到第二级费 - 托反应器，并允许CO和氢在第二级费 - 托反应器中在125-400℃的温度范围内转化成烃产物，以及 5至150巴绝对压力和500至10000Nl / l / h范围内的气时空速，其中第一级费 - 托反应器和第二级费 - 托反应器是分离的反应器 ; f）将来自第二级费 - 托反应器的流出物供给到分离单元; g）除去作为废气的气态流出物流的第二部分。

2. 发明申请

WO2008068305A3 PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM 审中-公开
标题翻译：生产纯化合成气流的方法
公开(公告)号：WO2008068305A3
公开(公告)日：2008-07-24
申请号：PCT/EP2007063413
申请日：2007-12-06
申请人： SHELL INT RESEARCH , DIERICKX JAN LODEWIJK MARIA , HESSELINK MAARTEN , SMIT CORNELIS JACOBUS
发明人： DIERICKX JAN LODEWIJK MARIA , HESSELINK MAARTEN , SMIT CORNELIS JACOBUS
IPC分类号： B01D53/86 , B01D53/04 , B01D53/14 , C01B3/50
CPC分类号： B01D53/04 , B01D53/14 , B01D53/864 , B01D2253/102 , B01D2253/112 , B01D2256/16 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/504 , B01D2257/60 , C01B3/12 , C01B3/52 , C01B3/56 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C10J3/00 , C10J2300/1656 , C10K1/002 , C10K1/003 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/007 , C10K1/02 , C10K1/16 , C10K1/165 , C10K1/20 , C10K1/32 , C10K3/04 , Y02C10/06 , Y02C10/08 , Y02P20/152 , Y02P20/52
摘要： A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising hydrogen sulphide, carbonyl sulphide, carbon dioxide, hydrogen cyanide and ammonia besides the main constituents carbon monoxide and hydrogen, the process comprising the steps of : (a) contacting one part of the feed synthesis gas stream with methanol at low temperature and at elevated pressure to remove hydrogen sulphide, carbonyl sulphide, carbon dioxide, hydrogen cyanide and ammonia, thereby obtaining methanol enriched in these compounds and a synthesis gas stream depleted in these compounds; (b) contacting another part of the feed synthesis gas stream with a water gas shift catalyst in the presence of water to react at least part of the carbon monoxide with water, thereby obtaining a shifted synthesis gas stream enriched in hydrogen and in carbon dioxide; (c) contacting the shifted synthesis gas stream with methanol at low temperature and at elevated pressure to remove carbon dioxide, hydrogen sulphide, carbonyl sulphide and ammonia, thereby obtaining solvent enriched in these compounds and a gas stream mainly comprising hydrogen and depleted in carbon dioxide; (d) contacting the synthesis gas stream obtained in step (a) and optionally the gas stream obtained in step (c) with a first solid adsorbent comprising sulphur-impregnated activated carbon and/or activated carbon to remove metals and/or metal carbonyl compounds to obtain a synthesis gas stream depleted in metals and/or metal carbonyl compounds; (e) contacting the synthesis gas stream depleted in metals and/or metal carbonyl compounds in the presence of water with a second solid adsorbent comprising one or more metals or oxides of the metals or combinations thereof, wherein the metals are selected from the group of Ag, Sn, Mo, Fe and Zn at elevated temperature to obtain the purified synthesis gas stream.
摘要翻译：一种从包含硫化氢，硫化氢，二氧化碳，氰化氢和氨的原料合成气流中生产纯化的合成气流的方法，除了主要成分一氧化碳和氢之外，该方法包括以下步骤：（a）使一种一部分原料合成气流与甲醇在低温和升高的压力下，以除去硫化氢，羰基硫化物，二氧化碳，氰化氢和氨，从而获得富含这些化合物的甲醇和这些化合物中的合成气流; （b）在水存在下使另一部分原料合成气流与水煤气变换催化剂接触，使至少部分一氧化碳与水反应，从而获得富含氢气和二氧化碳的转移合成气流; （c）在低温和升高的压力下使转移的合成气流与甲醇接触以除去二氧化碳，硫化氢，硫化羰和氨，从而获得富含这些化合物的溶剂和主要包含氢气和二氧化碳的气流 ; （d）将步骤（a）中获得的合成气流和任选的步骤（c）中获得的气流与包含浸硫活性炭和/或活性炭的第一固体吸附剂接触以除去金属和/或金属羰基化合物以获得贫化金属和/或金属羰基化合物的合成气流; （e）在水存在下将贫的金属和/或金属羰基化合物的合成气流与包含一种或多种金属或金属的氧化物或其组合的第二固体吸附剂接触，其中金属选自 Ag，Sn，Mo，Fe和Zn，以获得纯化的合成气流。

3. 发明申请

WO2008068305A2 PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM 审中-公开
标题翻译：生产纯化合成气流的方法
公开(公告)号：WO2008068305A2
公开(公告)日：2008-06-12
申请号：PCT/EP2007/063413
申请日：2007-12-06
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DIERICKX, Jan Lodewijk Maria , HESSELINK, Maarten , SMIT, Cornelis Jacobus
发明人： DIERICKX, Jan Lodewijk Maria , HESSELINK, Maarten , SMIT, Cornelis Jacobus
IPC分类号： B01D53/86 , B01D53/14 , B01D53/04 , C01B3/50
CPC分类号： B01D53/04 , B01D53/14 , B01D53/864 , B01D2253/102 , B01D2253/112 , B01D2256/16 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/504 , B01D2257/60 , C01B3/12 , C01B3/52 , C01B3/56 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C10J3/00 , C10J2300/1656 , C10K1/002 , C10K1/003 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/007 , C10K1/02 , C10K1/16 , C10K1/165 , C10K1/20 , C10K1/32 , C10K3/04 , Y02C10/06 , Y02C10/08 , Y02P20/152 , Y02P20/52
摘要： A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising hydrogen sulphide, carbonyl sulphide, carbon dioxide, hydrogen cyanide and ammonia besides the main constituents carbon monoxide and hydrogen, the process comprising the steps of : (a) contacting one part of the feed synthesis gas stream with methanol at low temperature and at elevated pressure to remove hydrogen sulphide, carbonyl sulphide, carbon dioxide, hydrogen cyanide and ammonia, thereby obtaining methanol enriched in these compounds and a synthesis gas stream depleted in these compounds; (b) contacting another part of the feed synthesis gas stream with a water gas shift catalyst in the presence of water to react at least part of the carbon monoxide with water, thereby obtaining a shifted synthesis gas stream enriched in hydrogen and in carbon dioxide; (c) contacting the shifted synthesis gas stream with methanol at low temperature and at elevated pressure to remove carbon dioxide, hydrogen sulphide, carbonyl sulphide and ammonia, thereby obtaining solvent enriched in these compounds and a gas stream mainly comprising hydrogen and depleted in carbon dioxide; (d) contacting the synthesis gas stream obtained in step (a) and optionally the gas stream obtained in step (c) with a first solid adsorbent comprising sulphur-impregnated activated carbon and/or activated carbon to remove metals and/or metal carbonyl compounds to obtain a synthesis gas stream depleted in metals and/or metal carbonyl compounds; (e) contacting the synthesis gas stream depleted in metals and/or metal carbonyl compounds in the presence of water with a second solid adsorbent comprising one or more metals or oxides of the metals or combinations thereof, wherein the metals are selected from the group of Ag, Sn, Mo, Fe and Zn at elevated temperature to obtain the purified synthesis gas stream
摘要翻译：一种从包含硫化氢，硫化氢，二氧化碳，氰化氢和氨的原料合成气流中生产纯化的合成气流的方法，除了主要成分一氧化碳和氢之外，该方法包括以下步骤：（a）使一种一部分原料合成气流与甲醇在低温和升高的压力下，以除去硫化氢，羰基硫化物，二氧化碳，氰化氢和氨，从而获得富含这些化合物的甲醇和这些化合物中的合成气流; （b）在水存在下使进料合成气流的另一部分与水煤气变换催化剂接触，使至少部分一氧化碳与水反应，从而获得富含氢气和二氧化碳的经转换的合成气流; （c）在低温和升高的压力下使转移的合成气流与甲醇接触以除去二氧化碳，硫化氢，硫化羰和氨，从而获得富含这些化合物的溶剂和主要包含氢气和二氧化碳的气流 ; （d）将步骤（a）中获得的合成气流和任选的步骤（c）中获得的气流与包含浸硫活性炭和/或活性炭的第一固体吸附剂接触以除去金属和/或金属羰基化合物以获得贫化金属和/或金属羰基化合物的合成气流; （e）在水存在下将贫的金属和/或金属羰基化合物的合成气流与包含一种或多种金属或金属的氧化物或其组合的第二固体吸附剂接触，其中金属选自 Ag，Sn，Mo，Fe和Zn，以获得纯化的合成气流

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