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    • 1. 发明申请
    • MOLECULAR ARRANGEMENT WITH A STRUCTURAL CONFIGURATION AND USE THEREOF FOR QUANTUM-MECHANICAL INFORMATION PROCESSING
    • 具有结构培训和分子排列及其中量子力学信息处理中的应用
    • WO0184714A3
    • 2002-03-21
    • PCT/DE0101673
    • 2001-05-02
    • HAHN MEITNER INST BERLIN GMBHWAIBLINGER MARKUSHARNEIT WOLFGANGWEIDINGER ALOIS
    • WAIBLINGER MARKUSHARNEIT WOLFGANGWEIDINGER ALOIS
    • C07C235/10B01J20/28C01B31/00C01D7/14C07C235/06G06N99/00G07C3/12G11C13/02H01L51/30G06N1/00G11C11/00H01L51/20
    • G11C13/02B82Y10/00B82Y30/00C07C235/06G06N99/002G11C13/0014G11C13/025H01L51/0046H01L51/0595
    • Cage-type molecules differ significantly physically but are so chemically similar that until now it has been impossible to arrange them in relation to each other in controllable structures. According to the invention however, molecular arrangements with geometrically regular, periodic structural configurations with extremely precisely selectable intervals and angles can be produced in a self-organised manner by chemically modifying the molecular cages by specifically applying addends. Suitable type pairs (P') consisting of complementary and selective addends (A', B') are used. These addends (A', B'), which are generally bondable on two sides, are bonded with specific selectable sites of the cage molecules (A', B') with one end and form adducts (A2, B2) with the same. The other end is configured to be chemically highly selective so that the addends (A', B') bind exclusively with each other according to the chemical lock-and-key principle. By using stable, endohedral fullerenes (Z@Cx with X = 60) as cage-type molecules, filled with an electron spin carrying atom (Z), it is possible to produce spatially extremely precisely arranged electron spin systems for spin quantum computing, with very high detection sensitivity due to the use of electron spin resonance.
    • 笼状分子物理地不同,虽然显著,但有这样的大的化学相似性,使得它们尚未被布置成彼此可控结构内。 根据本发明,但是,可以实现通过分子笼的化学改性自组织由具有规则几何形状,周期结构加数分子组装的选择性连接,也以高精度选择的距离和角度的配置。 在这种情况下,合适类型的对“彼此互补的和选择性的加数(A(P)”,B“)中使用。 这通常两个侧粘合的加数(A“ B‘)由一个端部到笼分子的结合的可选择的位置(A’,B”)测定,并与这些加合物(A2,B2)构成。 在化学上高选择性地形成在另一端部,从而彼此结合的化学键锁定原理后加数(A“ B”),排他。 在一种使用稳定的富勒烯富勒烯(Z @ CX它x≥60)作为笼状分子(Z)的,被提供有填充电子自旋轴承原子,空间高精度布置用于自旋量子计算电子自旋系统可以实现的,一个通过使用Elektronenspinesonanz的 具有非常高的检测灵敏度。