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    • 4. 发明申请
    • BIAXIALLY ORIENTED POLYSTYRENE FILM CONTAINING SMALL RUBBER PARTICLES AND LOW RUBBER PARTICLE GEL CONTENT
    • 包含小橡胶颗粒和低橡胶颗粒凝胶含量的双向聚苯乙烯薄膜
    • WO2007016376A1
    • 2007-02-08
    • PCT/US2006/029492
    • 2006-07-27
    • DOW GLOBAL TECHNOLOGIES INC.HARELLE, LudovicDOLLINGER, Susan, E.SKAPIK, Stephen, J., IIIMCGEE, Robert, L.
    • HARELLE, LudovicDOLLINGER, Susan, E.SKAPIK, Stephen, J., IIIMCGEE, Robert, L.
    • C08L25/08C08L53/02
    • C08L53/02C08J5/18C08J2353/02C08L25/08C08L51/06Y10T428/24273Y10T428/24893Y10T428/254C08L2666/24C08L2666/06C08L2666/04
    • A biaxially oriented film has a machine direction- orientation (MDO) ratio of more than 1.2 and a transverse direction orientation (TDO) ratio of 2.0 or less, where the MDO ratio is greater than the TDO ratio; where the film contains a polymer composition containing a first high impact polystyrene (HIPS) component with a block copolymer grafted to polystyrene, a rubbery conjugated diene content of one to seven weight percent based on first HIPS weight, less than 10 weight -percent gel concentration, an average rubber particle size of between one and 0.01 micrometers, about 40 to about 90 volume percent of the rubber particles have diameters of less than about 0.4 microns and from about 10 to about 60 volume percent of the rubber particles have diameters between about 0.4 and about 2.5 microns, a majority of rubber particles with a core/shell morphology and a concentration that accounts for 30 to 100 weight- percent of the total polymer composition weight and one to five weight-percent rubbery diene based on total polymer composition weight. The film can also contain up to 70 weight percent of a general purpose polystyrene and up to 20 weight-percent of a second HIPS component that is different from the first HIPS component, both based on total polymer composition weight. The polymer composition accounts for at least 95 weight-percent of the film, with the balance of the film weight being additives.
    • 双轴取向膜的机械方向取向(MDO)比大于1.2,横向取向(TDO)比为2.0以下,MDO比大于TDO比; 其中该膜包含含有接枝到聚苯乙烯的嵌段共聚物的第一高抗冲聚苯乙烯(HIPS)组分的聚合物组合物,基于第一HIPS重量,小于10重量%凝胶浓度的橡胶状共轭二烯含量为1至7重量% 橡胶颗粒的平均橡胶粒度在1至0.01微米之间,约40至约90体积%的橡胶颗粒具有小于约0.4微米的直径,约10至约60体积%的橡胶颗粒具有约0.4的直径 和约2.5微米,大多数具有核/壳形态的橡胶颗粒和占总聚合物组合物重量的30至100重量%的浓度和基于总聚合物组合物重量的1至5重量%的橡胶二烯。 该膜还可以含有高达70重量%的通用聚苯乙烯和至多20重量%的与第一HIPS组分不同的第二HIPS组分,均基于总聚合物组合物重量。 聚合物组合物占膜的至少95重量%,其余的膜重量是添加剂。