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1. 发明申请

WO2009116057A3 A PROCESS FOR THE SYNTHESIS OF ALPHA-OLEFIN POLYMERIZATION PROCATALYSTS 审中-公开
公开(公告)号：WO2009116057A3
公开(公告)日：2009-09-24
申请号：PCT/IN2008/000533
申请日：2008-08-25
申请人： RELIANCE INDUSTRIES LIMITED , GUPTA, Virendrakumar , PATIL, Harshad, Ramdas , NAIK, Dhananjay, Ghelabhai
发明人： GUPTA, Virendrakumar , PATIL, Harshad, Ramdas , NAIK, Dhananjay, Ghelabhai
IPC分类号： C08F4/654 , C08F110/06 , B01J31/00
摘要： The invention relates to a process for the synthesis of a Ziegler Natta procatalyst, the process comprising first treating magnesium alkoxide with a twice used mixed solvent of TiCl 4 and chloro benzene to form a first stage product, then treating the first stage product with a once used mixed solvent of TiCl 4 and chlorobenzene to form a second stage product and finally treating the second stage product with mixed solvent recovered by treatment of effluent from the first treatment with benzoyl chloride so as to convert contaminant of formula TiCl 3 OR in the effluent to an addition complex which is precipitated, filtered off and hydrolyzed to recover ethyl benzoate and to form Ti(OH) 4 as a side product, the product after final treatment being subjected to a plurality of successive washing steps with used as well as recovered hexane.

2. 发明申请

WO2013093930A1 A HIGH SURFACE AREA SILICON DERIVATIVE FREE MAGNESIUM- TITANIUM CATALYST SYSTEM FOR ETHYLENE POLYMERIZATION AND PROCESS OF PREPARATION THEREOF 审中-公开
标题翻译：用于乙烯聚合的高表面积硅衍生自由基镁 - 催化剂体系及其制备方法
公开(公告)号：WO2013093930A1
公开(公告)日：2013-06-27
申请号：PCT/IN2012/000519
申请日：2012-07-26
申请人： RELIANCE INDUSTRIES LIMITED , PATIL, Harshad Ramdas , GUPTA, Virendrakumar , KOTHARI, Ajay Vinodlal
发明人： PATIL, Harshad Ramdas , GUPTA, Virendrakumar , KOTHARI, Ajay Vinodlal
IPC分类号： C08F10/00
CPC分类号： C08F110/02 , C08F10/00 , C08F4/6548 , C08F2500/02 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F2500/24
摘要： The present invention relates to a high surface area silicon derivative free magnesium- titanium catalyst system for ethylene polymerization comprising: magnesium mixed alkoxide and titanium chloride. The present invention also provides a simple process for the preparation of high surface area silicon derivative free magnesium-titanium catalyst system for ethylene polymerization by reacting magnesium alkoxide precursor with titanium compound using dialkyl dialkoxy silane as external donor. The invention further relates to the process for ethylene polymerization using the silicon derivative free magnesium-titanium catalyst system and polyethylene produced" by the catalyst system having narrow molecular weight distribution and higher bulk density.
摘要翻译：本发明涉及一种用于乙烯聚合的高表面积硅衍生物自由基镁 - 钛催化剂体系，其包括：镁混合醇盐和氯化钛。本发明还提供了一种通过使用二烷基二烷氧基硅烷作为外给体使烷氧基镁前体与钛化合物反应来制备用于乙烯聚合的高表面积硅衍生物自由基镁 - 钛催化剂体系的简单方法。本发明还涉及使用无硅衍生物的镁 - 钛催化剂体系的乙烯聚合方法和“通过具有窄分子量分布和较高堆积密度的催化剂体系生产的聚乙烯。

3. 发明申请

WO2012160574A3 CONTROLLED MORPHOLOGY HIGH ACTIVITY POLYOLEFIN CATALYST SYSTEM 审中-公开
标题翻译：控制形态高活性聚烯烃催化剂体系
公开(公告)号：WO2012160574A3
公开(公告)日：2013-03-14
申请号：PCT/IN2012000350
申请日：2012-05-15
申请人： RELIANCE IND LTD , SINGH SAURABH , GUPTA VIRENDRAKUMAR , SINGALA KAMLESH J , PATEL VALLABHBHAI S
发明人： SINGH SAURABH , GUPTA VIRENDRAKUMAR , SINGALA KAMLESH J , PATEL VALLABHBHAI S
IPC分类号： B01J31/02 , B01J27/138 , B01J35/08 , C08F10/00
CPC分类号： C08F4/76 , B01J27/138 , B01J31/02 , B01J35/08 , C08F10/00 , C08F4/651 , C08F4/6543 , C08F4/6545
摘要： A high activity polyolefin catalyst system comprising titanium containing pro- catalyst component, a co-catalyst component and an external electron donor compound is provided wherein the high activity polyolefin catalyst system is having controlled morphology and less fines. The present invention is more directed to provide a method for the preparation of titanium containing pro- catalyst component from solid spherical shaped magnesium containing pro- catalyst precursor wherein the spherical morphology of the pro-catalyst precursor is maintained through out the reaction in order to achieve titanium-containing pro- catalyst having controlled morphology. The polymerization of lower olefins in the presence of high activity polyolefin catalyst having controlled morphology provides polyolefins with minimal polymer fines.
摘要翻译：提供了一种包含钛的催化剂组分，助催化剂组分和外部电子给体化合物的高活性聚烯烃催化剂体系，其中高活性聚烯烃催化剂体系具有受控的形态和较少的细粉。本发明更有针对性地提供一种从固体球形含镁催化剂前体制备含钛催化剂组分的方法，其中前催化剂前体的球形形态通过反应维持以实现具有受控形态的含钛催化剂。在具有受控形态的高活性聚烯烃催化剂存在下，低级烯烃的聚合提供具有最小聚合物细粉的聚烯烃。

4. 发明申请

WO2009141831A3 A CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：一种用于烯烃聚合的催化剂体系
公开(公告)号：WO2009141831A3
公开(公告)日：2010-02-25
申请号：PCT/IN2008000534
申请日：2008-08-25
申请人： RELIANCE IND LTD , GUPTA VIRENDRAKUMAR , PATIL HARSHAD RAMDAS , NAIK DHANANJAY GHELABHAI , KAUR SUKHDEEP , SINGH GURMEET , VYAS PRIYANSHU BHARATKUMAR
发明人： GUPTA VIRENDRAKUMAR , PATIL HARSHAD RAMDAS , NAIK DHANANJAY GHELABHAI , KAUR SUKHDEEP , SINGH GURMEET , VYAS PRIYANSHU BHARATKUMAR
IPC分类号： C08F4/642 , C08F4/647 , C08F10/00
CPC分类号： C08F10/06 , C08F110/06 , C08F4/6494 , C08F4/6495 , C08F4/6465 , C08F2500/12
摘要： The invention relates to a catalyst system for polymerization of olefins, the catalyst system comprising a titanium-containing procatalyst carrying internal electron donor(s), an organoaluminium cocatalyst and a mixture of external electron donors, the mixture comprising a carboxylic acid ester or derivatives thereof, an alkoxy silane and a nitrogen based compound. The invention also relates to a process for polymerization of olefin(s) and to the polyolefin synthesized by the process.
摘要翻译：本发明涉及一种用于烯烃聚合的催化剂体系，所述催化剂体系包含含有载体内电子给体的含钛前催化剂，有机铝助催化剂和外电子给体的混合物，所述混合物包含羧酸酯或其衍生物，烷氧基硅烷和氮基化合物。本发明还涉及一种聚合烯烃和通过该方法合成的聚烯烃的方法。

5. 发明申请

WO2009141831A2 A CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：一种用于烯烃聚合的催化剂体系
公开(公告)号：WO2009141831A2
公开(公告)日：2009-11-26
申请号：PCT/IN2008/000534
申请日：2008-08-25
申请人： RELIANCE INDUSTRIES LIMITED , GUPTA, Virendrakumar , PATIL, Harshad, Ramdas , NAIK, Dhananjay, Ghelabhai , KAUR, Sukhdeep , SINGH, Gurmeet , VYAS, Priyanshu, Bharatkumar
发明人： GUPTA, Virendrakumar , PATIL, Harshad, Ramdas , NAIK, Dhananjay, Ghelabhai , KAUR, Sukhdeep , SINGH, Gurmeet , VYAS, Priyanshu, Bharatkumar
IPC分类号： C08F4/646 , C08F4/647 , C08F10/00
CPC分类号： C08F10/06 , C08F110/06 , C08F4/6494 , C08F4/6495 , C08F4/6465 , C08F2500/12
摘要： The invention relates to a catalyst system for polymerization of olefins, the catalyst system comprising a titanium-containing procatalyst carrying internal electron donor(s), an organoaluminium cocatalyst and a mixture of external electron donors, the mixture comprising a carboxylic acid ester or derivatives thereof, an alkoxy silane and a nitrogen based compound. The invention also relates to a process for polymerization of olefin(s) and to the polyolefin synthesized by the process.
摘要翻译：本发明涉及一种用于烯烃聚合的催化剂体系，所述催化剂体系包含含有载体内电子给体的含钛前催化剂，有机铝助催化剂和外电子给体的混合物，所述混合物包含羧酸酯或其衍生物，烷氧基硅烷和氮基化合物。本发明还涉及一种聚合烯烃和通过该方法合成的聚烯烃的方法。

6. 发明申请

WO2012156989A1 CATALYST SYSTEM FOR POLYMERIZATION OF PROPYLENE 审中-公开
标题翻译：丙烯聚合催化剂体系
公开(公告)号：WO2012156989A1
公开(公告)日：2012-11-22
申请号：PCT/IN2012/000335
申请日：2012-05-08
申请人： RELIANCE INDUSTRIES LIMITED , PATIL, Harshad Ramdas , VYAS, Priyanshu, Bharatkumar , GUPTA, Virendrakumar
发明人： PATIL, Harshad Ramdas , VYAS, Priyanshu, Bharatkumar , GUPTA, Virendrakumar
IPC分类号： C08F10/06
CPC分类号： C08F110/06 , C08F10/06 , C08F4/6465 , C08F4/6494 , C08F4/6543 , C08F2500/12 , C08F2500/21
摘要： The present invention relates to a catalyst system for polymerization of propylene, process for preparing polypropylene and to polypropylene prepared by said process. The dual external donor composition of present invention has synergistic effects. It improves the efficiency of polymerization process and product properties for homo grade of polypropylene.
摘要翻译：本发明涉及用于聚合丙烯的催化剂体系，制备聚丙烯的方法和通过所述方法制备的聚丙烯。本发明的双重外源供体组合物具有协同效应。提高了聚丙烯的均聚效率和产品性能。

7. 发明申请

WO2009116057A2 A PROCESS FOR THE SYNTHESIS OF ALPHA-OLEFIN POLYMERIZATION PROCATALYSTS 审中-公开
标题翻译：合成α-烯烃聚合方法的方法
公开(公告)号：WO2009116057A2
公开(公告)日：2009-09-24
申请号：PCT/IN2008000533
申请日：2008-08-25
申请人： RELIANCE IND LTD , GUPTA VIRENDRAKUMAR , PATIL DHANANJAY GHELABHAI
发明人： GUPTA VIRENDRAKUMAR , PATIL DHANANJAY GHELABHAI
IPC分类号： C08F4/654 , C08F4/649 , C08F10/00
CPC分类号： C08F10/00 , C08F110/06 , Y10T428/2982 , C08F4/6541 , C08F4/651 , C08F2500/12
摘要： The invention relates to a process for the synthesis of a Ziegler Natta procatalyst, the process comprising first treating magnesium alkoxide with a twice used mixed solvent of TiCl4 and chloro benzene to form a first stage product, then treating the first stage product with a once used mixed solvent of TiCl4 and chlorobenzene to form a second stage product and finally treating the second stage product with mixed solvent recovered by treatment of effluent from the first treatment with benzoyl chloride so as to convert contaminant of formula TiCl3OR in the effluent to an addition complex which is precipitated, filtered off and hydrolyzed to recover ethyl benzoate and to form Ti(OH)4 as a side product, the product after final treatment being subjected to a plurality of successive washing steps with used as well as recovered hexane.
摘要翻译：本发明涉及一种合成齐格勒纳塔前催化剂的方法，该方法包括首先用二氯化钛和氯苯混合溶剂处理烷醇镁，形成第一级产物，然后用一次使用的方法处理第一级产物混合溶剂的TiCl4和氯苯形成第二阶段产物，最后通过处理来自第一次处理的流出物用苯甲酰氯回收的混合溶剂处理第二阶段产物，以将流出物中式TiCl 3OR的污染物转化成加成络合物，沉淀，过滤并水解回收苯甲酸乙酯并形成作为副产物的Ti（OH）4，最终处理后的产物经过多次连续洗涤步骤，并用回收的己烷。

8. 发明申请

WO2009116056A2 PROPYLENE POLYMERIZATION CATALYST SYSTEM 审中-公开
标题翻译：丙烯聚合催化剂体系
公开(公告)号：WO2009116056A2
公开(公告)日：2009-09-24
申请号：PCT/IN2008/000532
申请日：2008-08-25
申请人： RELIANCE INDUSTRIES LIMITED , GUPTA, Virendrakumar , PATIL, Harshad, Ramdas , NAIK, Dhananjay, Ghelabhai
发明人： GUPTA, Virendrakumar , PATIL, Harshad, Ramdas , NAIK, Dhananjay, Ghelabhai
IPC分类号： C08F4/649 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/04
摘要： The invention relates to a catalyst system for polymerization of propylene, the catalyst system comprising a Ziegler Natta procatalyst, an organoaluminium cocatalyst, a monoester of an aromatic carboxylic acid as the internal donor and ethyl-4-isopropoxy benzoate as the selectivity control agent. The invention also relates to a process for polymerization using the catalyst system as well as to polymers prepared by the process.
摘要翻译：本发明涉及一种用于丙烯聚合的催化剂体系，该催化剂体系包含齐格勒纳塔催化剂，有机铝助催化剂，作为内给体的芳族羧酸的单酯和作为选择性控制剂的乙基-4-异丙氧基苯甲酸酯。本发明还涉及使用催化剂体系的聚合方法以及通过该方法制备的聚合物。

9. 发明申请

WO2011077447A2 A SEMI-CONTINUOUS PROCESS FOR THE SYNTHESIS OF A CATALYST FOR USE IN THE MANUFACTURE OF POLYOLEFINS 审中-公开
标题翻译：用于合成聚烯烃用催化剂的半连续方法
公开(公告)号：WO2011077447A2
公开(公告)日：2011-06-30
申请号：PCT/IN2010/000809
申请日：2010-12-14
申请人： RELIANCE INDUSTRIES LIMITED , SINGALA, Kamlesh , SINGH, Saurabh , GUPTA, Virendrakumar
发明人： SINGALA, Kamlesh , SINGH, Saurabh , GUPTA, Virendrakumar
IPC分类号： C08F4/652
CPC分类号： C08F10/06 , C01G23/0536 , C01P2004/51 , C08F110/06 , Y10S526/908 , C08F4/651 , C08F2/14 , C08F2/00 , C08F2500/12
摘要： This invention provides a semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins comprising of following steps: (a) mixing a reaction mixture essentially consisting of titanium compound having at least one titanium halogen bond and a chlorinated solvent in feed section; (b) charging a first reactor with said reaction mixture; (c) continuously removing excess reactants from said first reactor as a filtrate through a filtrate section placed at the bottom of said first reactor; (d) feeding said filtrate to at least one further reactor connected to said first reactor to retain the carried over fine particles from said first reactor; continuously removing excess reactants from said at least further reactor as a filtrate through a filtrate section placed at the bottom of said at least one further reactor and, if desired, feeding said filtrate to next said at least one further reactor; (e) repeating step (d) for n number of times in series, wherein reactors are arranged in series or parallel; (f) subjecting the said filtrate from the last of said at least one further reactor to a distillation section to remove impurities and recover the distillate; and continuously charging the distillate from the distillation section to the feed section; wherein a desired equilibrium between fresh and recovered distillate and a desired resultant concentration of reactant feed are maintained; and (g) optionally treating the residue from distillation section with an alkali to obtain titanium hydroxide and calcining said titanium hydroxide to obtain titanium oxide as a by product.
摘要翻译：本发明提供了用于合成用于制造聚烯烃的窄粒径分布齐格勒纳塔主催化剂的半连续方法及其系统，其包括以下步骤：（a）将反应混合物在进料段中主要由具有至少一个钛卤素键的钛化合物和氯化溶剂组成的混合物; （b）用所述反应混合物装入第一反应器; （c）通过位于所述第一反应器底部的滤液部分作为滤液连续地从所述第一反应器中除去过量的反应物; （d）将所述滤液加入到与所述第一反应器连接的至少一个另外的反应器中以保留来自所述第一反应器的所述携带的细颗粒; 作为滤液通过放置在所述至少一个其他反应器底部的滤液部分连续地从所述至少另一个反应器中除去过量的反应物，并且如果需要，将所述滤液进料到下一个所述至少一个另外的反应器中; （e）重复步骤（d）n次串联，其中反应器串联或并联排列; （f）将来自所述至少一个另外的反应器的最后一个的所述滤液置于蒸馏段以除去杂质并回收馏出物; 并将来自蒸馏部分的馏出物连续加入进料部分; 其中维持新鲜馏分和回收馏分之间的期望平衡以及期望的反应物进料的所得浓度; 和（g）任选地用碱处理来自蒸馏段的残余物以获得氢氧化钛并煅烧所述氢氧化钛以获得作为副产物的氧化钛。

10. 发明申请

WO2009116057A8 A PROCESS FOR THE SYNTHESIS OF ALPHA-OLEFIN POLYMERIZATION PROCATALYSTS 审中-公开
标题翻译：合成α-烯烃聚合方法的方法
公开(公告)号：WO2009116057A8
公开(公告)日：2010-02-25
申请号：PCT/IN2008000533
申请日：2008-08-25
申请人： RELIANCE IND LTD , GUPTA VIRENDRAKUMAR , PATIL HARSHAD RAMDAS , NAIK DHANANJAY GHELABHAI
发明人： GUPTA VIRENDRAKUMAR , PATIL HARSHAD RAMDAS , NAIK DHANANJAY GHELABHAI
IPC分类号： C08F4/654 , C08F4/649 , C08F10/00
CPC分类号： C08F10/00 , C08F110/06 , Y10T428/2982 , C08F4/6541 , C08F4/651 , C08F2500/12
摘要： The invention relates to a process for the synthesis of a Ziegler Natta procatalyst, the process comprising first treating magnesium alkoxide with a twice used mixed solvent of TiCl4 and chloro benzene to form a first stage product, then treating the first stage product with a once used mixed solvent of TiCl4 and chlorobenzene to form a second stage product and finally treating the second stage product with mixed solvent recovered by treatment of effluent from the first treatment with benzoyl chloride so as to convert contaminant of formula TiCl3OR in the effluent to an addition complex which is precipitated, filtered off and hydrolyzed to recover ethyl benzoate and to form Ti(OH)4 as a side product, the product after final treatment being subjected to a plurality of successive washing steps with used as well as recovered hexane.
摘要翻译：本发明涉及一种合成齐格勒纳塔前催化剂的方法，该方法包括首先用二氯化钛和氯苯混合溶剂处理烷醇镁，形成第一级产物，然后用一次使用的方法处理第一级产物混合溶剂的TiCl4和氯苯形成第二阶段产物，最后通过处理来自第一次处理的流出物用苯甲酰氯回收的混合溶剂处理第二阶段产物，以将流出物中式TiCl 3OR的污染物转化成加成络合物，沉淀，过滤并水解回收苯甲酸乙酯并形成作为副产物的Ti（OH）4，最终处理后的产物经过多次连续洗涤步骤，并使用回收的己烷。

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