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    • 1. 发明申请
    • PRE-SULFIDING AND PRE-CONDITIONING OF RESIDUUM HYDROCONVERSION CATALYSTS FOR EBULLATED-BED HYDROCONVERSION PROCESSES
    • 用于EBULLED-BED HYDROCONVERSION工艺的残余氢化催化剂的预硫化和预调控
    • WO2011011200A2
    • 2011-01-27
    • PCT/US2010041272
    • 2010-07-08
    • LUMMUS TECHNOLOGY INCGUPTA AVINASHBALDASSARI MARIO CMUKHERJEE UJJAL K
    • GUPTA AVINASHBALDASSARI MARIO CMUKHERJEE UJJAL K
    • C10G47/06B01J8/26B01J27/043B01J27/047B01J37/20
    • C10G65/12B01J37/20C10G47/06C10G2300/107C10G2300/1074C10G2300/1077C10G2300/202C10G2300/703
    • A hydroconversion process is disclosed, including contacting of hydrogen and a residuum hydrocarbon with a pre-conditioned and at least partially sulfided hydroconversion catalyst for converting at least a portion of the residuum hydrocarbon into at least one of a hydrotreated product and a hydrocracked product. Pre-sulf?ding and preconditioning of the catalyst may include: intermittently or continuously: feeding a hydroconversion catalyst comprising a metal oxide to a pre-reactor; feeding hydrogen and the residuum hydrocarbon comprising sulfur-containing compounds to the pre-reactor; contacting the hydroconversion catalyst with hydrogen and the sulfur-containing compounds in the pre- reactor at conditions of temperature and pressure to concurrently: i) convert at least a portion of the metal oxide to a metal sulfide; and ii) pre-condition the catalyst; recovering a residuum hydrocarbon having a reduced sulfur content from the pre-reactor; and transporting the preconditioned and at least partially sulfided hydroconversion catalyst from the pre-reactor to the ebullated-bed hydroconversion reactor.
    • 公开了一种加氢转化方法,包括使氢气和残油烃与预处理和至少部分硫化的加氢转化催化剂接触,用于将至少一部分残油烃转化成加氢处理产物和加氢裂化产物中的至少一种。 催化剂的预硫化和预处理可以包括:间歇地或连续地:将包含金属氧化物的加氢转化催化剂供给到预反应器中; 将氢气和包含含硫化合物的残余烃进料到预反应器; 使所述加氢转化催化剂与所述预反应器中的氢气和所述含硫化合物在温度和压力的条件下接触,同时:i)将至少一部分所述金属氧化物转化为金属硫化物; 和ii)预处理催化剂; 从预反应器回收具有降低的硫含量的残油烃; 并将预处理和至少部分硫化的加氢转化催化剂从预反应器输送到沸腾床加氢转化反应器。