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1. 发明申请

WO2007128137A1 POLY(ARYLENE ETHER)S WITH GRAFTING CAPABILITY FROM A BISPHENOL OR BISTHIOPHENOL MONOMER 审中-公开
标题翻译：来自二苯醚或二苯醚单体的聚亚烷基醚（ARYLENE ETHER）S
公开(公告)号：WO2007128137A1
公开(公告)日：2007-11-15
申请号：PCT/CA2007/000850
申请日：2007-05-03
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , LI, Zhao , DING, Jianfu , GUIVER, Michael
发明人： LI, Zhao , DING, Jianfu , GUIVER, Michael
IPC分类号： C07C321/30 , C07C317/14 , C07D213/50 , C07D271/10
CPC分类号： C07C323/18 , C08G65/4006 , C08G75/23 , C08J5/2256 , C08J5/2262
摘要： A monomer of formula (I) may be used to prepare a poly(arylene ether) of formula (II) wherein k is 1 or 2, n is a non-zero number from 0 to 1, j is 0, 1 or 2, Q is O or S, L is a leaving group, Z is F or CI, Z' is F, CI or an organic group, and R is hydrogen or an organic moiety. Such poly(arylene ether)s are useful as membrane materials, for example for gas separation, water desalination, and proton exchange membranes in fuel cells.
摘要翻译：式（I）的单体可用于制备式（II）的聚（亚芳基醚），其中k为1或2，n为0至1的非0数，j为0,1或2， Q是O或S，L是离去基团，Z是F或Cl，Z'是F，Cl或有机基团，R是氢或有机基团。这种聚（亚芳基醚）可用作膜材料，例如用于燃料电池中的气体分离，水脱盐和质子交换膜。

2. 发明申请

WO2010003224A1 PROTON-CONDUCTING POLYMERIC POLY(ARYLENE ETHER)S WITH PENDANT PHENYL SULFONIC ACIDS 审中-公开
标题翻译：导电聚丙烯（ARYLENE ETHER）S与辅助苯酚磺酸
公开(公告)号：WO2010003224A1
公开(公告)日：2010-01-14
申请号：PCT/CA2009/000925
申请日：2009-07-03
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , KIM, Dae, Sik , GUIVER, Michael, D.
发明人： KIM, Dae, Sik , GUIVER, Michael, D.
IPC分类号： C08G65/00 , C08J5/00 , C08J5/22 , H01M8/02
CPC分类号： C08J5/2256 , C08G65/40 , C08G65/4006 , C08G65/48 , C08J5/2262 , C08J2371/12 , H01B1/122 , H01M4/8663 , H01M8/04119 , H01M8/04197 , H01M8/1025 , H01M8/1039 , H01M2300/0082
摘要： Disclosed are sulfonated polymers of formula (I) or a salt thereof: wherein X is (a) or (b), R is hydrogen or an organic moiety, n is an integer from 10 to 10,000, p is 1 or 2, and m is 0 or 1 for a particular monomer unit such that the polymer has a degree of sulfonation of 0.50 or greater. Such polymers are useful in proton exchange membranes (PEMs) having high ion exchange capacity with higher proton conductivity than Nafion™, while having lower methanol permeability and lower water uptake than previously disclosed polymers.
摘要翻译：公开了式（I）的磺化聚合物或其盐：其中X为（a）或（b），R为氢或有机部分，n为10至10,000的整数，p为1或2，m 对于特定的单体单元，为0或1，使得聚合物的磺化度为0.50或更大。这种聚合物可用于具有高于Nafion的高离子交换能力和更高的质子传导性的质子交换膜（PEM），同时具有比以前公开的聚合物更低的甲醇渗透性和更低的吸水率。

3. 发明申请

WO2004029132A1 PROTON EXCHANGE MEMBRANE MATERIALS BASED ON SULFONATED POLY(PHTHALAZINONES) 审中-公开
标题翻译：基于磺化聚（PHTHALAZINONES）的原子交换膜材料
公开(公告)号：WO2004029132A1
公开(公告)日：2004-04-08
申请号：PCT/CA2003/001399
申请日：2003-09-25
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , GAO, Yan , GUIVER, Michael, D. , ROBERTSON, Gilles, P. , JIAN, Xigao
发明人： GAO, Yan , GUIVER, Michael, D. , ROBERTSON, Gilles, P. , JIAN, Xigao
IPC分类号： C08G73/00
CPC分类号： C08J5/2256 , C08G65/4037 , C08G65/48 , C08G73/0694 , C08J2379/04 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M2300/0082
摘要： A novel class of proton exchange membrane materials, sulfonated poly(phthalazinones), were prepared by modification of poly(phthalazinone). Sulfonation reactions were conducted at room temperature using mixtures of 95-98 % concentrated sulfuric acid and 27-33 % fuming sulfuric acid with different acid ratios in order to get SPPEK with degree of sulfonation (DS) in the range of 0.6 to 1.0. The presence of sulfonic acid groups was confirmed by FT-IR analysis, and the DS and structures were characterized by NMR. The introduction of sulfonic groups into the polymer chains led to an increase in the glass transition temperature and a decrease in the decomposition temperature. Membrane films were cast from solution in N,N -dimethylformamide or N,N -dimethylacetamide. Water uptakes and swelling ratios of the membrane films increased with DS and sulfonated polymers with DS > 1.2 were water soluble at 80°. Proton conductivity increased with DS and temperature up to 95°, reaching 10 -2 S/cm.
摘要翻译：通过改性聚（酞嗪酮）制备了一类新颖的质子交换膜材料，磺化聚（2,3-二氮杂萘酮）。使用95-98％浓硫酸和27-33％发烟硫酸的混合物在室温下进行磺化反应，以使得具有0.6-1.0的磺化度（DS）的SPPEK。通过FT-IR分析证实磺酸基团的存在，并通过NMR表征DS和结构。在聚合物链中引入磺基导致玻璃化转变温度的升高和分解温度的降低。从N，N-二甲基甲酰胺或N，N-二甲基乙酰胺中的溶液中浇铸膜膜。 DS的水膜吸收和溶胀比随DS增加，DS> 1.2的磺化聚合物的水溶性在80°。质子传导率随DS增加，温度高达95°，达到10 -2 S / cm。

4. 发明申请

WO2010124359A1 CARBOXYLATED POLYMERS OF INTRINSIC MICROPOROSITY (PIMS) WITH TUNABLE GAS TRANSPORT PROPERTIES 审中-公开
标题翻译：具有气体输送特性的内在微孔（PIMS）的羧基化聚合物
公开(公告)号：WO2010124359A1
公开(公告)日：2010-11-04
申请号：PCT/CA2010/000323
申请日：2010-03-10
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , DU, Naiying , GUIVER, Michael D. , ROBERTSON, Gilles P. , SONG, Jingshe
发明人： DU, Naiying , GUIVER, Michael D. , ROBERTSON, Gilles P. , SONG, Jingshe
IPC分类号： C08J5/18 , C08G65/40 , C08L71/10
CPC分类号： C08G65/48 , C08J5/18 , C08J2371/02 , C08L71/02
摘要： A film of a carboxylated polymer of formula (I): wherein the sum of x, y and z is an integer from 10 to 10,000 and degree of hydrolysis is 0.05 or greater provides gas separation materials in which the degree of hydrolysis may be used to tune the selectivity of the gases to an optimal required range. Such films may be prepared by casting a film of a polymer of formula (II): wherein n is an integer from 10 to 10,000, and hydrolyzing all or a portion of the -CN groups to form -COOH groups.
摘要翻译：式（I）的羧化聚合物的膜：其中x，y和z的总和为10至10,000的整数，水解度为0.05或更大提供可以使用水解度的气体分离材料将气体的选择性调整到最佳所需范围。这样的膜可以通过浇铸式（II）的聚合物的膜来制备：其中n是10至10,000的整数，并且将全部或部分-CN基团水解形成-COOH基团。

5. 发明申请

WO2010048694A1 LADDER POLYMERS WITH INTRINSIC MICROPOROSITY AND PROCESS FOR PRODUCTION THEREOF 审中-公开
标题翻译：具有内在微结构的梯形聚合物及其生产方法
公开(公告)号：WO2010048694A1
公开(公告)日：2010-05-06
申请号：PCT/CA2009/001472
申请日：2009-10-16
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , DU, Naiying , GUIVER, Michael D. , ROBERTSON, Gilles P.
发明人： DU, Naiying , GUIVER, Michael D. , ROBERTSON, Gilles P.
IPC分类号： C07D339/08 , B01D71/06 , B01J20/26 , C08G65/40 , C08J5/18 , B01D53/02
CPC分类号： C08J9/00 , B01D53/02 , B01D53/228 , B01D71/76 , B01D2253/202 , B01D2256/12 , B01D2256/22 , B01D2257/102 , B01J20/26 , B01J20/262 , B01J20/28033 , B01J20/2808 , C07D339/08 , C08G65/40 , C08G65/4006 , C08G75/23 , C08L2205/05
摘要： A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C 1 -C 8 alkyl, C2-C8 alkenyl or C 3 -C 8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both -CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.
摘要翻译：式（I）的聚合物：其中：n为10至5000的整数; m为10〜5000的整数; Ar1和Ar3相同或不同，是衍生自四羟基芳族单体的残基，四羟基芳族单体是其中R相同或不同，为H或C 1 -C 8烷基，C 2 -C 8烯基或C 3 -C8环烷基并且Ar 2和Ar 4相同或不同，并且是衍生自四卤代芳族单体的残基，其中X是F，Cl或Br的四卤代芳族单体，R 1和R 2相同或不同，其中 y为1〜8的整数; 条件是当Ar 1与Ar 3相同且Ar 2与Ar 4相同时，R 1和R 2不能同时为-CN可用作气体分离，气相分离，吸附剂或催化剂的材料。

6. 发明申请

WO2008009102A1 POLY(ARYL ETHER) WITH PENDENT SULFONIC ACID PHENYL GROUPS 审中-公开
标题翻译： POLY（ARYL ETHER）WITH OREND SULFONIC ACID PHENYL GROUPS
公开(公告)号：WO2008009102A1
公开(公告)日：2008-01-24
申请号：PCT/CA2007/001229
申请日：2007-07-13
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , LIU, Baijun , GUIVER, Michael, D. , ROBERTSON, Gilles, P.
发明人： LIU, Baijun , GUIVER, Michael, D. , ROBERTSON, Gilles, P.
IPC分类号： C08G65/40 , C08G65/48 , C08J5/22 , H01M8/02 , H01M8/10
CPC分类号： C08J5/2256 , C08G65/48 , C08J2371/12 , H01M8/1011 , H01M8/1027 , H01M2008/1095 , H01M2300/0082 , Y02E60/523
摘要： A sulfonated poly(aryl ether) (SPAE) having a poly(aryl ether) (PAE) main chain and a sulfonated phenyl group pendent from the main chain are useful in proton exchange membranes (PEMs), particularly for fuel cells. The pendent phenyl group can provide an easily sulfonable site that may be sulfonated under mild conditions, providing the ability to precisely control the sulfonic acid content of the SPAE.
摘要翻译：具有聚（芳基醚）（PAE）主链和主链侧基的磺化苯基的磺化聚（芳基醚）（SPAE）可用于质子交换膜（PEM），特别是用于燃料电池。侧基苯基可以提供易于磺化的位点，其可在温和条件下磺化，提供精确控制SPAE的磺酸含量的能力。

7. 发明申请

WO2011057384A1 POLYMERS OF INTRINSIC MICROPOROSITY CONTAINING TETRAZOLE GROUPS 审中-公开
标题翻译：含有四唑基团的内在微球的聚合物
公开(公告)号：WO2011057384A1
公开(公告)日：2011-05-19
申请号：PCT/CA2010/001722
申请日：2010-10-28
申请人： NATIONAL RESEARCH COUNCIL OF CANADA , DU, Naiying , GUIVER, Michael D.
发明人： DU, Naiying , GUIVER, Michael D.
IPC分类号： C08G65/48 , C08G65/40
CPC分类号： C08G65/48 , C08G65/4006
摘要： The invention provides a tetrazole-containing polymer of intrinsic microporosity comprising (10) or more subunits, wherein one or more of the subunits comprise one or more tetrazolyl moieties. In one embodiment, a polymer of intrinsic microporosity (PIM-1 ) was modified using a "click chemistry" [2 + 3] cycloaddition reaction with sodium azide and zinc chloride to yield new PIMs containing tetrazole units. Polymers of the present invention are useful as high-performance materials for membrane-based gas separation, materials for ion exchange resins, materials for chelating resins, materials for superabsorbents, materials for ion conductive matrixes, materials for catalyst supports or materials for nanoparticle stabilizers.
摘要翻译：本发明提供了含有（10）个或更多个亚基的本征微孔的含四唑的聚合物，其中一个或多个亚基包含一个或多个四唑基部分。在一个实施方案中，使用与叠氮化钠和氯化锌进行“点击化学”[2 + 3]环加成反应来修饰本征微孔性聚合物（PIM-1），以产生含有四唑单元的新的PIM。本发明的聚合物可用作用于膜基气体分离的高性能材料，用于离子交换树脂的材料，用于螯合树脂的材料，用于超吸收剂的材料，用于离子导电基质的材料，用于催化剂载体的材料或用于纳米颗粒稳定剂的材料。

8. 发明申请

WO2005080483A1 METHOD FOR CROSS-LINKING SULFONATED POLYMERS 审中-公开
标题翻译：交联磺化聚合物的方法
公开(公告)号：WO2005080483A1
公开(公告)日：2005-09-01
申请号：PCT/CA2005/000261
申请日：2005-02-23
申请人： UNIVERSITÉ LAVAL , CONSEIL NATIONAL DE RECHERCHES CANADA , KALIAGUINE, Serge , MIKHAILENKO, Serguei , WANG, Keping , GUIVER, Michael D. , ROBERTSON, Gilles P. , XING, Peixiang
发明人： KALIAGUINE, Serge , MIKHAILENKO, Serguei , WANG, Keping , GUIVER, Michael D. , ROBERTSON, Gilles P. , XING, Peixiang
IPC分类号： C08J5/22
CPC分类号： B01D71/82 , B01D67/0006 , B01D67/0011 , B01D71/52 , B01D2323/12 , B01D2323/30 , C08J3/24 , C08J5/2287 , C08J2371/12 , H01M8/1025 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： A method for the preparation of a cross-linked, sulfonated, proton exchange membrane for fuel cells, which includes: providing a sulfonated polymer, for example SPEEK; dissolving the sulfonated polymer in a polar casting solvent; adding at least one polyol cross-linking agent to obtain a solution, the cross-linking agent being added in a ratio of at least 1 polyol molecules per repeat unit of the sulfonated polymer to generate cross-linking; casting the solution to obtain the membrane; and curing the membrane.
摘要翻译：一种用于制备用于燃料电池的交联磺化质子交换膜的方法，其包括：提供磺化聚合物，例如SPEEK; 将磺化聚合物溶解在极性浇铸溶剂中; 加入至少一种多元醇交联剂以获得溶液，交联剂以磺化聚合物每重复单元的至少1个多元醇分子的比率加入以产生交联; 浇注溶液以获得膜; 并固化膜。

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