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    • 2. 发明申请
    • CONJUGATED COPOLYMERS FOR USE IN LUMINESCENT DEVICES
    • 用于发光装置的共轭共聚物
    • WO1998004610A1
    • 1998-02-05
    • PCT/GB1997002038
    • 1997-07-29
    • CAMBRIDGE DISPLAY TECHNOLOGY LIMITEDTOWNS, CarlGRIZZI, Ilaria
    • CAMBRIDGE DISPLAY TECHNOLOGY LIMITED
    • C08G61/02
    • H05B33/14C08G61/00C09K11/06H01L51/0035H01L51/0036H01L51/0038H01L51/5088H05B33/10H05B33/12Y10T428/31678Y10T428/31699Y10T428/31855Y10T428/31931Y10T428/31942
    • A process for the preparation of a conjugated poly(arylene vinylene) copolymer for use in a luminescent device, which comprises: (1) providing a precursor polymer comprising units of general formula -(-ArCHR -CR L-)-n, in which Ar is substituted or unsubstituted arylene, L is a leaving group, R and R are each independently H, alkyl, alkoxy, aryl or an electron-withdrawing group, and n is an integer; (2) reacting the precursor polymer with a reactant comprising a carboxylate, an aldehyde, a ketone, a sulphonate, a thioate, a disulphide, a xanthate, an amine, a pyridine, a hydrazide, a phenoxide, an alcohol with a boiling point above 100 DEG C, or a derivative thereof, under substitution conditions whereby a proportion of the leaving groups are substituted to form a substituted precursor copolymer comprising units of general formula -(-ArCHR -CR L-)-m -(-ArCHR -CR X-)-l, in which Ar, R , R and L are as defined above, X is a substituent group from the reactant, l and m are independently integers; and (3) converting the substituted precursor copolymer to a conjugated poly(arylene vinylene) copolymer by elimination of the leaving groups from the substituted precursor copolymer.
    • 一种用于制备用于发光装置的共轭聚(亚芳基亚乙烯基)共聚物的方法,其包括:(1)提供包含通式 - ( - ArCHR 1 -CR 2 -L- )-n,其中Ar是取代或未取代的亚芳基,L是离去基团,R 1和R 2各自独立地为H,烷基,烷氧基,芳基或吸电子基团,n是整数 ; (2)使前体聚合物与包含羧酸盐,醛,酮,磺酸盐,硫酸盐,二硫化物,黄原酸盐,胺,吡啶,酰肼,酚盐,沸点的醇的反应物反应 100℃以上的衍生物或其衍生物,其中一部分离去基团被取代以形成取代的前体共聚物,其包含通式为 - ( - ArCHR 1 -CR 2 - ) - m - ( - ArCHR 1 -CR 2)X - ) - ,其中Ar,R 1,R 2和L如上所定义,X是来自反应物的取代基,l和m 独立整数; 和(3)通过从取代的前体共聚物中消除离去基团将取代的前体共聚物转化为共轭聚(亚芳基亚乙烯基)共聚物。
    • 7. 发明申请
    • HIGH EFFICIENCY LUMINESCENT COPOLYMERS
    • 高效液相共聚物
    • WO1998013408A1
    • 1998-04-02
    • PCT/GB1997002653
    • 1997-09-26
    • CAMBRIDGE DISPLAY TECHNOLOGY LIMITEDTOWNS, CarlGRIZZI, Ilaria
    • CAMBRIDGE DISPLAY TECHNOLOGY LIMITED
    • C08G61/00
    • C08G61/00C09K11/06
    • A semiconductive conjugated copolymer, which is a random copolymer comprising monomer units of general formula: -(-Ar-CH=CHn-)- (-Ar-CHNu-CH2-)-m -(-CR R XCR R -)-y, wherein Ar is substituted or unsubstituted arylene; Nu is a nucleophile; X is a direct carbon to carbon single bond or the group -CR =CR -; each of R , R , R , R , R and R is independently H, amine, halogen, CN, alkyl, alkoxy, alkyl carboxylate, carboxylic acid, alkyl ester, carbonyl, alkyl ether, alkyl thioether, alkyl amide, substituted or unsubstituted aryl, aryloxy, aryl carboxylate, aryl ether, aryl ester, aryl thioether, aryl amide, aryl ketone, or heterocyclic in which one of R , R , R or R is optionally CQ=CH2, where Q is halogen, methyl, nitrile or H; n and y are integers; and m is an integer or zero.
    • 一种半导体共轭共聚物,其是包含以下通式的单体单元的无规共聚物: - ( - Ar-CH = CH n - ) - (-Ar-CHNu-CH 2 - ) - m - ( - CR 1 R 2) XCR 3 R 4 - ) - y,其中Ar是取代或未取代的亚芳基; Nu是亲核试剂; X是直接碳 - 碳单键或基团-CR 5 = CR 6 - ; R 1,R 2,R 3,R 4,R 5和R 6各自独立地为H,胺,卤素,CN,烷基,烷氧基,烷基羧酸酯,羧酸 ,烷基酯,羰基,烷基醚,烷基硫醚,烷基酰胺,取代或未取代的芳基,芳氧基,芳基羧酸酯,芳基醚,芳基酯,芳基硫醚,芳基酰胺,芳基酮或杂环,其中R 1, R 2,R 3或R 4任选地为CQ = CH 2,其中Q为卤素,甲基,腈或H; n和y是整数; m为整数或零。