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    • 3. 发明申请
    • PROCESS FOR POLYMERISING OR OLIGOMERISING A HYDROCARBON
    • 聚合或低聚烃的方法
    • WO2009060343A1
    • 2009-05-14
    • PCT/IB2008/054457
    • 2008-10-29
    • SASOL TECHNOLOGY (PROPRIETARY) LIMITEDGILDENHUYS, Johannes, Jochemus
    • GILDENHUYS, Johannes, Jochemus
    • C07C2/36C07C2/12C07C11/107
    • C07C2/36C07C2531/14C07C2531/24Y02P20/582C07C11/107
    • A process (10) for polymerising or oligomerising a hydrocarbon includes feeding a liquid hydrocarbon reactant (32) and a liquid evaporative cooling medium into a bulk liquid phase (14) which includes polymeric or oligomeric product admixed with a catalyst, and allowing at least a portion of the liquid hydrocarbon reactant and the liquid evaporative cooling medium to vapouhse to form bubbles rising through the bulk liquid phase (14), with the hydrocarbon reactant polymerising or oligomerising to form the polymeric or oligomeric product and with the evaporation of both the liquid hydrocarbon reactant and the liquid evaporative cooling medium effecting heat removal from the bulk liquid phase (14). Gaseous components are withdrawn (26) from a head space, cooled (28) and separated (30). Condensed hydrocarbon reactant and condensed cooling medium are recycled (32) to the bulk liquid phase (14).
    • 用于聚合或低聚烃的方法(10)包括将液体烃反应物(32)和液体蒸发冷却介质进料到主体液相(14)中,所述本体液相(14)包括与催化剂混合的聚合物或低聚产物,并允许至少一种 液体烃反应物和液体蒸发冷却介质的一部分蒸发以形成通过本体液相(14)上升的气泡,烃反应物聚合或低聚形成聚合物或低聚产物,并且蒸发液态烃 反应物和液体蒸发冷却介质从体液相(14)中进行热去除。 气体组分从顶部空间中取出(26),冷却(28)并分离(30)。 冷凝的碳氢化合物反应物和冷凝的冷却介质被循环(32)到大部分液相(14)。