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1. 发明申请

WO1996033154A1 PROCESS FOR PRODUCING ETHER COMPOUNDS 审中-公开
标题翻译：生产醚化合物的方法
公开(公告)号：WO1996033154A1
公开(公告)日：1996-10-24
申请号：PCT/JP1996001056
申请日：1996-04-18
申请人： IDEMITSU KOSAN CO., LTD. , YAMASAKI, Hirotaka , OGAWA, Akihisa , KAMIMORI, Shigeru , HIRAO, Yoshikazu , FUJITA, Keiji , YOSHIMOTO, Tokuyuki
发明人： IDEMITSU KOSAN CO., LTD.
IPC分类号： C07C43/10
CPC分类号： C08F8/04 , C07C41/28 , C08F16/16 , C07C43/04
摘要： A process for producing ether compounds which comprises reacting an acetal compound represented by the general formula (I) (wherein R s and R may be the same or different and each represents alkyl or cycloalkyl and R s may be the same or different from repeating unit to repeating unit; and n is an integer of from 1 to 50); with hydrogen in the presence of a solid catalyst comprising (A) 10 to 70 % by weight, in terms of metallic nickel, of nickel and (B) at least one material selected from among oxides of silicon, aluminum, magnesium, titanium and zirconium and synthetic and natural inorganic oxides comprising at least one of the above oxides as the constituting unit to thereby give an ether compound represented by general formula (II) or (III), wherein R , R and n are each as defined above, thus efficiently producing a vinyl ether polymer or a terminal ether compound without causing any troubles such as the corrosion of reactors.
摘要翻译：一种制备醚化合物的方法，其包括使由通式（I）表示的缩醛化合物（其中R 1和R 2）可以相同或不同，各自表示烷基或环烷基，R 1 可以与重复单元重复单元相同或不同; n为1〜50的整数）; 在含有（A）10-75重量％（以金属镍计）镍和（B）至少一种选自硅，铝，镁，钛和锆的氧化物的材料的固体催化剂存在下，和包含至少一种上述氧化物作为构成单元的合成和天然无机氧化物，从而得到通式（II）或（III）表示的醚化合物，其中R 1，R 2和n各自为如上所述，因此有效地生产乙烯基醚聚合物或末端醚化合物，而不会引起诸如反应器腐蚀的任何问题。

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