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    • 1. 发明申请
    • MODIFIED NACREOUS LUSTRE PIGMENTS FOR WATER PAINT SYSTEMS
    • 珠光修饰用于水性涂料系统
    • WO1998013426A1
    • 1998-04-02
    • PCT/EP1997004999
    • 1997-09-12
    • MERCK PATENT GMBHHÜLS AGGLAUSCH, RalfFORNOFF, NicoleDUSCHEK, JoachimSTANDKE, BurkhardEDELMANN, Roland
    • MERCK PATENT GMBHHÜLS AG
    • C09C01/00
    • A61Q1/02A61K8/0241A61K2800/412A61K2800/436A61K2800/621A61K2800/624C01P2004/84C08K9/02C08K9/06C09C1/0015C09C1/0021C09C2200/102C09C2200/401C09C2200/407C09C2200/408C09C2200/409C09C2220/106C09D5/36
    • Modified nacreous lustre pigments for water paint systems are based on a plate-like substrate coated with metal oxides and a covering layer located on the top metal oxide layer. The covering layer is made of at least two oxides, a mixture of oxides and/or mixed oxides from the group of silicium dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and of a water-based oligomer silane system. The oligomer silane system can be described for example by the following approximate structure: [HO[Si(A)(OH)Z(CH3)1-ZO]a[Si(B)(OH)Y(CH3)1-YO]b[Si(C)(OH)W(CH3)1-WO]c[Si(D)(OH)V(CH3)1-VO]d[H.(HX)e, in which A is an aminoalkyl radical derived from the general formula (V), B is an glycidetheralkyl radical derived from the general formula (VI), C is an acryloxyalkyl or methacryloxyalkyl radical of general formula (VII), D is an alkyl radical of general formula (VIII), HX is a monobasic acid, wherein X is an inorganic or organic acid radical, such as chloride, nitrate, formiate, acetate, v equals 0 or 1, w equals 0 or 1, y equals 0 or 1, z equals 0 or 1, a+b+c+d>/=4, a /=1, and when 0.5
    • 改性珠光颜料用于水基涂料系统的基础上,涂有金属氧化物,薄片状基材和位于最上层的金属氧化物层上的覆盖层,其中所述覆盖层包括选自二氧化硅,氧化铝,氧化铈,二氧化钛中的至少两种氧化物和/或混合氧化物和/或混合氧化物,和 氧化锆和基于水的低聚硅烷是。 低聚硅烷系统可以被描述于,例如,具有以下近似的结构:HO [硅(A)(OH)z(CH 3)1-ZO] A [硅(B)(OH)Y(CH 3)1-YO] B [硅( C)(OH)W(CH 3)1-WO] C [硅(D)(OH)V(CH 3)1-VO] D [H.(HX)E,其中A =氨基烷基由通式衍生(V ),B = Glycidetheralkylrest导出的通式(VI)通式(VII)中,D =烷基的通式(VIII),HX =一元酸,其中X =无机酸或有机酸中的,C =丙烯酰氧基或Methacryloxyalkylrest的基团,例如 如 氯化物,硝酸盐,甲酸盐,乙酸盐,v等于0或1,w是0或1,y是0或1,z是等于0或1且a + b + C + D> / = 4,和 / = 1和0.5