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    • 3. 发明申请
    • DENTAL FILLING MATERIALS WITH SURFACE MODIFIED ZIRCONIA PARTICLES
    • 牙齿填充材料与表面改性ZIRCONIA颗粒
    • WO2010049522A2
    • 2010-05-06
    • PCT/EP2009/064373
    • 2009-10-30
    • DENTOFIT A/SVAN LELIEVELD, AlexanderNIELSEN, Mette Skovgaard
    • VAN LELIEVELD, AlexanderNIELSEN, Mette Skovgaard
    • A61K6/083
    • A61K6/083A61K6/0073A61K6/087C08L33/04C08L63/00
    • The present application discloses a dental filling material comprising fillers and a polymerizable resin base, the fillers comprising metastable zirconia particles in the tetragonal and/or cubic crystalline phase with less than 30 % (v/v) in the monoclinic phase, and having surface functionalities of the formula: -Zr-O-Zr-O-C(=O)-X-C(R 1 )(R 2 )(R 3 ), wherein X = -O-, -NH-, -S-; R 1 / R 2 = hydrogen, opt.subst. C 1-30 -alkyl, a (meth)acrylate moiety moiety, a (meth)acrylate-C 1-12 -alkyl moiety, opt.subst. C 2-30 -alkenyl, opt.subst. C 5-30 -alkadienyl, opt.subst. C 8-30 -alkatrienyl, or when X = -NH-, R 1 / R 2 = =O; R 3 = hydrogen, C 1-6 -alkyl, hydroxy, halogen. A method of controlling the volumetric shrinkage of a dental filling material upon curing, and the dental filling material for use in medicine, in particular in dentistry, are also disclosed.
    • 本申请公开了一种包含填充剂和可聚合树脂基质的牙科填充材料,所述填料包含在单斜晶相中小于30%(v / v)的四方晶和/或立方晶相中的亚稳态氧化锆颗粒,并且具有表面官能度 其中X = -O-,-NH-,-S-; -Zr-O-Zr-OC(= O)-XC(R1)(R2)(R3) R1 / R2 =氢,opt.subst。 (甲基)丙烯酸酯部分部分,(甲基)丙烯酸酯-C 1-12烷基部分,优选。 C2-30-烯基,选择性 C5-30-链二烯基,opt.subst。 或当X = -NH-时,R 1 / R 2 = = O; R3 =氢,C1-6烷基,羟基,卤素。 还公开了一种在固化时控制牙科填充材料的体积收缩率的方法,以及用于医学,特别是牙科用的牙科填充材料。
    • 4. 发明申请
    • AN IMPROVED COMPOSITE MATERIAL, IN PARTICULAR A DENTAL FILLING MATERIAL
    • 改进的复合材料,特别是牙科填充材料
    • WO2007101442A2
    • 2007-09-13
    • PCT/DK2007/000114
    • 2007-03-07
    • DENTOFIT A/Svan LELIEVELD, Alexander
    • van LELIEVELD, Alexander
    • A61K6/083
    • A61K6/0073A61K6/083A61L27/446B82Y30/00C08L33/00
    • The present application discloses a composite material comprising one or more fillers and a polymerizable resin base, wherein said one or more fillers comprise at least one filler ingredient, said filler ingredient(s) being present in a metastable first phase and being able to undergo a martensitic transformation to a stable second phase, the volume ratio between said stable second phase and said metastable first phase of said filler ingredient(s) being at least 1.005, and wherein said one or more fillers include a fraction of nanofillers having a refractive index of at least 1.8, and wherein the ratio between (i) the refractive index of the combination of the polymerizable resin base and the nanofillers and (ii) the fraction of the one or more fillers not being said nanofillers is in the range of 1:0.9 to 1: 1.1.
    • 本申请公开了一种包含一种或多种填料和可聚合树脂基质的复合材料,其中所述一种或多种填料包含至少一种填料成分,所述填料成分存在于亚稳态第一相中并且能够经历 马氏体转化为稳定的第二相,所述填料成分的所述稳定的第二相与所述亚稳态第一相之间的体积比为至少1.005,并且其中所述一种或多种填料包括一部分纳米填料,其折射率为 至少1.8,并且其中(i)可聚合树脂基质和纳米填料的组合的折射率之间的比率和(ii)不是所述纳米填料的一种或多种填料的分数在1:0.9的范围内 至1:1.1。