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    • 2. 发明申请
    • PROCESS FOR THE ELECTROLYTIC DEPOSITION OF METAL LAYERS
    • 法金属层电解分离
    • WO1997019206A1
    • 1997-05-29
    • PCT/EP1996005140
    • 1996-11-21
    • ATOTECH DEUTSCHLAND GMBHDAHMS, WolfgangMEYER, HeinrichKRETSCHMER, Stefan
    • ATOTECH DEUTSCHLAND GMBH
    • C25D05/18
    • C25D3/38C25D5/18H05K3/241Y10S205/92
    • The invention relates to a process for the electrolytic deposition of metal layers, in particular copper layers, of specific physico-mechanical and optical characteristics and of even thickness. With known processes using dissolving anodes and direct current, only an uneven metal layer distribution can be achieved on articles of complex shape. The problem of uneven layer thickness at different points on article surfaces can be alleviated by using a pulsed current or pulsed voltage process, but this does not solve the other problem of continually changing geometry during deposition as the anodes dissolve. This problem can be eliminated by using non-dissolving anodes. To ensure adequate anode stability and a high lustre of the layers even at points on the workpiece surface where the metal is deposited with high current density, compounds of an electrochemically reversible redox system must be added to the deposition solution.
    • 本发明涉及一种用于金属层,特别是铜层,具有均匀的层厚度一定的物理 - 机械性能和光学性能的电解沉积的方法。 根据使用可溶性阳极和施加直流知的方法,金属分布的唯一的非均匀层可在复杂形状的工件来实现。 使用脉冲电流或脉冲电压的方法,虽然该问题可以减少在这些层在材料表面的不同位置具有不同的厚度。 但没有进一步的问题是由连续阳极的溶解沉积过程中变化的几何关系来解决。 这可以通过使用不溶性阳极被消除。 为了确保亦在其中金属沉积有高的电流密度的工件表面的位置处的膜的阳极和高光泽度的足够的稳定性,有必要添加一种电化学可逆的氧化还原系统的沉积化合物。
    • 7. 发明申请
    • PROCESS FOR THE ELECTROLYTIC DEPOSITION OF COPPER LAYERS
    • 方法覆铜层电解沉积
    • WO1998026114A1
    • 1998-06-18
    • PCT/EP1997006786
    • 1997-12-04
    • ATOTECH DEUTSCHLAND GMBHSENGE, GerdDAHMS, Wolfgang
    • ATOTECH DEUTSCHLAND GMBH
    • C25D03/38
    • C25D3/38C25D3/58C25D5/18H05K3/241H05K3/423
    • A process for the electrolytic deposition of copper layers, in particular on printed circuit boards, has the following steps: an electroconductive substrate and anodes which are dissolved during electrolytic deposition are brought into contact with a deposition bath which contains copper ions, compounds which increase the electroconductivity of the deposition bath, additives for influencing the material properties of the copper layers, additional compounds of an electrochemically reversible redox system, and additives or mixtures of additives. The substrate and the anodes are connected to a current supply and the copper layers are deposited on the substrate by a pulsed current or pulsed voltage process. This process allows metallic layers with good optical and mechanical properties to be deposited even after only a short stay in the bath.
    • 对于铜层的电解沉积,特别是在印刷电路板上,其包括以下步骤的方法被用于:导电基底和溶解电解沉积的阳极被带到与镀浴接触,铜离子的电镀液,所述沉积浴的电导率增加的化合物, 包含用于影响铜层的材料性质,电化学可逆的氧化还原系统的另外的化合物和溶剂或溶剂混合物的添加剂。 所述基板和所述阳极连接到电源。 铜层是由脉冲电流或脉冲电压方法沉积在衬底上。 当该方法的金属层可以以良好的光学和机械材料特性的槽的短训练期间之后进行沉积。