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    • 6. 发明申请
    • PESTICIDAL FLUOROALKENE DERIVATIVES
    • 杀虫荧光酮衍生物
    • WO2004013112A1
    • 2004-02-12
    • PCT/EP2003/008397
    • 2003-07-30
    • BASF AKTIENGESELLSCHAFTKORDES, MarkusVON DEYN, WolfgangSCHMIDT, ThomasSTEINER, GerdKUHN, David, G.HU, YulinCOTTER, Henry, Van, TuylCULBERTSON, Deborah, L.
    • KORDES, MarkusVON DEYN, WolfgangSCHMIDT, ThomasSTEINER, GerdKUHN, David, G.HU, YulinCOTTER, Henry, Van, TuylCULBERTSON, Deborah, L.
    • C07D263/52
    • A01N43/90A01N43/74C07D277/36C07D277/74
    • Pesticidal fluoroalkene derivatives (I) wherein A is oxygen, NR a ; R a is hydrogen; optionally halogenated alkyl, alkenyl, alkynyl; X is hydrogen, halogen; optionally halogenated alkyl or phenyl; R 1 ,R 2 are hydrogen, halogen, hydroxyl, cyano, nitro, mercapto, amino; alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, alkylcarbonyloxy, optionally halogenated or substituted by 1 to 3 R b groups: R b is cyano, nitro, halogen, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl; optionally halogenated alkyl, haloalkyl, alkenyl, alkenyloxy, alkynyl, alkoxy, haloalkoxy, alkylthio, alkylamino, dialkylamino, formyl, alkylcarbonyl, alkylsulfonyl, alkoxysulfonyl, alkylsulfonyloxy, alkoxycarbonyl, alkylcarbonyloxy, alkylaminocarbonyl, dialkylaminocarbonyl, alkylaminothiocarbonyl, dialkylaminothiocarbonyl, alkylenedioxy or cycloalkyl; Het is a monocyclic or bicyclic 3- to 10-membered heteroaromatic ring system containing 1 to 5 heteroatoms selected from oxygen, sulfur and nitrogen, optionally halogenated or substituted by 1 to 4 R c groups: R c is R b , alkoxyalkyl, alkylsulfinyl, alkylaminosulfonyl, di-alkylaminosulfonyl, alkylcarbonylamino, optionally substituted by halogen or 1 to 3 cyano, hydroxy, mercapto, amino, C1-C6-alkylthio, C1-C6-alkylamino, di-C1-C6-alkylamino, C1-C6-alkoxycarbonyl, C1-C6-alkylcarbonyloxy or nitro groups; cycloalkyl, cycloalkoxy, saturated or partially unsaturated heterocyclyl, heterocyclyloxy, aryl, aryloxy, arylthio, arylalkoxy, arylalkyl, hetaryl, hetaryloxy, hetarylthio, optionally substituted; m is 0-2; n is 0-3; p is 0-6, methods for the preparation of compounds I, compositions and methods comprising the compounds and compositions for the control of nematodes, insects, arachnids, harmful fungi and unwanted plants, and for treating, controlling, preventing and protecting warm-blodded animals, fish and humans against infestation and infection by helminths, arachnids and arthropod endo- and ectoparasites.
    • 杀虫氟代烯烃衍生物(I)其中A是氧,NR a; R a是氢; 任选卤代烷基,烯基,炔基; X是氢,卤素; 任选卤代烷基或苯基; R 1,R 2是氢,卤素,羟基,氰基,硝基,巯基,氨基; 烷基,烯基,炔基,烷氧基,烯氧基,烷硫基,烷基氨基,二烷基氨基,烷氧基羰基,烷基羰基氧基,任选被卤化或被1至3个R基团取代:R b是氰基,硝基,卤素,羟基,巯基,氨基 ,羧基,氨基羰基,氨基硫代羰基; 任选卤代烷基,卤代烷基,烯基,烯氧基,炔基,烷氧基,卤代烷氧基,烷硫基,烷基氨基,二烷基氨基,甲酰基,烷基羰基,烷基磺酰基,烷氧基磺酰基,烷基磺酰氧基,烷氧基羰基,烷基羰基氧基,烷基氨基羰基,二烷基氨基羰基,烷基氨基硫代羰基,二烷基氨基硫代羰基,亚烷基二氧基或环烷基。 Het是含有1至5个选自氧,硫和氮的杂原子的单环或双环3至10元杂芳族环系,任选被卤化或被1-4个R c取代:R c是R b 烷氧基烷基,烷基亚磺酰基,烷基氨基磺酰基,二烷基氨基磺酰基,烷基羰基氨基,任选被卤素取代或氰基,羟基,巯基,氨基,C 1 -C 6烷硫基,C 1 -C 6烷基氨基,二-C 1 -C 6烷基氨基, C 1 -C 6 - 烷氧基羰基,C 1 -C 6烷基羰基氧基或硝基; 环烷基,环烷氧基,饱和或部分不饱和的杂环基,杂环氧基,芳基,芳氧基,芳硫基,芳基烷氧基,芳烷基,杂芳基,杂芳氧基,杂芳硫基,任选取代的; m为0-2; n为0-3; p为0-6,制备化合物I的方法,包含用于控制线虫,昆虫,蜘蛛,有害真菌和不想要的植物的化合物和组合物的组合物和方法,以及用于治疗,控制,预防和保护温暖的 动物,鱼类和人类,通过蠕虫,蜘蛛和节肢动物内部和外寄生虫感染和感染。