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    • 1. 发明申请
    • BLEACHING COMPOSITIONS
    • 漂白组合物
    • WO1995014759A1
    • 1995-06-01
    • PCT/GB1994002583
    • 1994-11-25
    • WARWICK INTERNATIONAL GROUP LIMITEDCROWTHER, Jan, DarrelHAQUE, EkramCOLES, Barrie
    • WARWICK INTERNATIONAL GROUP LIMITED
    • C11D03/39
    • C07D207/27C11D3/392
    • Bleach activators and the peroxygen-based oxidising species formed in situ from a peroxygen source and a bleach activator, the bleach activator having formula (I) in which R represents an optionally substituted alkenyl function having at least 2 carbon atoms in the alkenyl chain which forms a cyclic structure with -N- and -C(O)- and R represents a C1-30 alkyl or aryl group; or has the formula -R - COX where X may be OH, OM (where m is a metal ion), -ONR 4 (where R are each independently selected from H and C1-4 alkyl), a halogen atom, amine, C1-30 alkyl or alkoxy or a leaving group and R is a C1-30 alkylene or arylene group with the proviso that where R is (CH2)5, R represents a C3-9 branched alkyl group or a C10-30 alkyl or aryl group or a C9-10 branched aralkyl group; or has the formula -R -COX and R is a C3-10 branched alkyl group or C11-30 alkylene or arylene group, or a C9-10 branched alkarylene. Compositions including these bleach activators in combination with conventional bleach activators such as tetraacylated alkylene diamines, particularly TAED or SNOBS give particularly useful cleaning properties.
    • 漂白活化剂和由过氧源和漂白活化剂原位形成的过氧基氧化物质,具有式(I)的漂白活化剂,其中R表示在烯基链中具有至少2个碳原子的任选取代的烯基官能团,其形成 具有-N-和-C(O) - 和R 1的环状结构表示C1-30烷基或芳基; 或具有式-R 2 -COX,其中X可以是OH,OM(其中m是金属离子),-ONR 3(其中R 3各自独立地选自H和C 1-4烷基 ),卤素原子,胺,C 1-3烷基或烷氧基或离去基团,R 2是C 1-30亚烷基或亚芳基,条件是其中R是(CH 2)5,R 1表示 C3-9支链烷基或C10-30烷基或芳基或C9-10支链芳烷基; 或具有式-R 2 -COX和R 2是C 3-10支链烷基或C 11-30亚烷基或亚芳基或C 9-10支链亚烷基。 包括这些漂白活化剂与常规漂白活化剂如四酰化亚烷基二胺,特别是TAED或SNOBS的组合物提供特别有用的清洁性能。