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1. 发明申请

WO1996019480A1 SUBSTITUTED PHTHALOCYANINES 审中-公开
标题翻译：取代的羟基苯甲酸
公开(公告)号：WO1996019480A1
公开(公告)日：1996-06-27
申请号：PCT/GB1995002996
申请日：1995-12-21
申请人： THE SECRETARY OF STATE FOR DEFENCE , McKEOWN, Neil, Bruce , CLARKSON, Guy, James , HUMBERSTONE, Paul
发明人： THE SECRETARY OF STATE FOR DEFENCE
IPC分类号： C07D487/22
CPC分类号： C07D487/22 , B82Y10/00 , C09K19/40 , G11B7/248
摘要： Phthalocyanines of formula (I) are described wherein M is a metal atom, metal compound or is 2H; one H being bonded to each of the two nitrogen atoms depicted as being bonded to M (positions 29 and 31 shown); R1-R25 may be the same or different and are chosen independently from the following groups: straight or branched chain alkyl containing up to 32 carbon atoms where 1 or more non-adjacent CH2 groups may be replaced by O and/or a double bond; H; F; and at least one of R2.3.9.10.16.17.23.24 is chosen from formula (II) wherein Y, X and Z are chosen independently from HO, DEG O, O, OR, H, C1-16 branched or straight chain alkyl or alkoxy; X and Z may also be selected from phenyl groups which may be, independently of each other, substituted with one or more C1-5 straight or branched chain alkyl groups; R may be C1-16 branched or straight chain alkyl or alkene wherein 1 or more non-adjacent CH2 groups may be replaced by O and may be terminated by an OH group; provided that at least one of Y, X and Z is chosen from HO, DEG O, O, OR. Compounds of the above formulae are useful in a broad range of applications, including electro-optical devices, Langmuir Blodgett films, molecular wires, in optical recording media and uses which exploit their redox properties.
摘要翻译：描述式（I）的酞菁，其中M是金属原子，金属化合物或是2H; 一个H键合到所示的两个氮原子中的每一个键合到M（所示的位置29和31）; R1-R25可以相同或不同，并且独立地选自以下基团：含有至多32个碳原子的直链或支链烷基，其中1个或更多个不相邻的CH 2基团可被O和/或双键取代; H; F; 并且R2.3.9.10.16.17.23.24中的至少一个选自式（II），其中Y，X和Z独立地选自HO，O，O，OR，H，C 1-16支链或直链烷基或烷氧基; X和Z也可以选自可以彼此独立地被一个或多个C 1-5直链或支链烷基取代的苯基; R可以是C1-16支链或直链烷基或烯烃，其中1个或更多个不相邻的CH 2基团可以被O代替，并且可以被OH基团封端; 条件是Y，X和Z中的至少一个选自HO，O，O，OR。上述式的化合物可用于广泛的应用，包括电光装置，Langmuir Blodgett膜，光学记录介质中的分子线以及利用其氧化还原性质的用途。

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