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    • 9. 发明申请
    • POLY(ARYLETHERIMIDES) FOR NEGATIVE BIREFRINGENT FILMS FOR LCDS
    • 用于液晶显示器的阴性双膜的POLY(ARYLETHERIMIDES)
    • WO2009045537A1
    • 2009-04-09
    • PCT/US2008/011514
    • 2008-10-06
    • AKRON POLYMER SYSTEMSHARRIS, Frank W.SUN, LiminZHANG, DongCHENG, Stephen Z. D.
    • HARRIS, Frank W.SUN, LiminZHANG, DongCHENG, Stephen Z. D.
    • C09K19/00
    • C08G73/1039C08G73/1042C08G73/1067C08J5/18C08J2379/08G02B5/3083G02F1/133634Y10T428/1027Y10T428/1036Y10T428/1041Y10T428/31721
    • A negative birefringence film prepared from a poly(aryletherimide) which is the reaction product of a dianhydride and a diamine, where the dianhydride is 4,4'-[4,4'-(p-ρhenyleneoxy)isopropylidene]bis(phthalic anhydride) (BisADA), bis(3,4-dicarboxyphenyl)ether dianhydride (ODPA), 4,4'-bis(3,4-dicarboxyphenoxy)biphenyl dianhydride (BPEDA), 1,4-bis(3,4-dicarboxyphenyloxy)phenyl dianhydride (BPQDA), 3, 3', 4, 4'-tetracarboxylicbiphenyl dianhydride (BPDA), or 2,2-bis(3,4-dicarboxyphenyl)-l,l,l,3,3,3-hexafluoropropane dianhydride (6FD A), alone or a mixture with one or more of: BPDA, 6FDA, Bis- AF-D A, BPQDA, and BPEDA, and ODPA; and where the diamine is 6FOD A, 6FOBDA3 BTBDA, 3,3'-dimethyl-4,4'-diarnino biphenyl (OTOL), l,4-bis(2-trifluoromethyl-4-aminophenoxy)-2- t -butylbenzene, or mixtures thereof and wherein when a mixture of dianhydrides is present, they are present in a molar amount of between 99 to 1 (99:1) and 1 to 99 (1 :99), and the film has a negative birefringence greater than 0.01, at a thickness of less than 15 μm, when the poly(aryletherimide) is solution cast or coated onto a substrate.
    • 由二酐与二酐反应的聚(芳基醚酰亚胺)制备的负双折射膜,其中二酐是4,4' - [4,4' - (对 - 亚硫酰氧基)异丙叉]双(邻苯二甲酸酐 )(BisADA),双(3,4-二羧基苯基)醚二酐(ODPA),4,4'-双(3,4-二羧基苯氧基)联苯二酐(BPEDA),1,4-双(3,4-二羧基苯氧基) 苯基二酐(BPQDA),3,3',4,4'-四羧基联苯二酐(BPDA)或2,2-双(3,4-二羧基苯基)-1,1,3,3,3-六氟丙烷二酐 (6FD A),单独或与以下一种或多种的混合物:BPDA,6FDA,Bis-AF-D A,BPQDA和BPEDA以及ODPA; 其中二胺为6FOD A,6FOBDA3 BTBDA,3,3'-二甲基-4,4'-二氨基联苯(OTOL),1,4-双(2-三氟甲基-4-氨基苯氧基)-2-叔丁基苯, 或其混合物,并且其中当存在二酸酐的混合物时,它们以99至1(99:1)和1至99(1:99)的摩尔量存在,并且该膜的负双折射率大于0.01 ,当聚(芳基醚酰亚胺)溶液浇铸或涂覆在基材上时,厚度小于15μm。