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1. 发明申请

WO2013037672A1 COLOUR LASER MARKING METHODS OF SECURITY DOCUMENT PRECURSORS 审中-公开
标题翻译：安全文件前缀的彩色激光标记方法
公开(公告)号：WO2013037672A1
公开(公告)日：2013-03-21
申请号：PCT/EP2012/067216
申请日：2012-09-04
申请人： AGFA-GEVAERT , WAUMANS, Bart , CALLANT, Paul , GEUENS, Ingird
发明人： WAUMANS, Bart , CALLANT, Paul , GEUENS, Ingird
IPC分类号： B41M3/14 , B41M5/26 , B41M5/34 , B41M5/323
CPC分类号： B41M3/14 , B41M3/142 , B41M5/267 , B41M5/323 , B41M5/34
摘要： A method of colour laser marking a security document precursor including at least: a polymeric foil; at least one colourless colour forming layer for generating a colour different from black containing at least an infrared absorber, a colour forming compound and a polymeric binder; and a laser markable polymeric support or a laser markable layer for generating a black colour; comprising the steps of: -laser marking the colourless colour forming layer with an infrared laser used in pulsed mode at a pulse repetition rate of at least 15 kHz to generate a colour different from black; and -laser marking the laser markable polymeric support or the laser markable layer with the same infrared laser used in a pulsed mode at a pulse repetition rate of at most 5 kHz to generate a black colour.
摘要翻译：一种彩色激光标记安全文件前体的方法，所述安全文件前体至少包括：聚合物箔; 至少一个无色成色层，用于产生不同于至少含有红外线吸收剂的黑色，成色化合物和聚合物粘合剂; 以及用于产生黑色的可激光标记聚合物支撑体或激光可标记层; 包括以下步骤：用脉冲模式以至少15kHz的脉冲重复率使用红外激光器激光标记无色成色层，以产生不同于黑色的颜色; 以及以脉冲重复频率至多5kHz以脉冲模式使用相同红外激光的激光可标记聚合物支持体或激光可标记层标记以产生黑色。

2. 发明申请

WO1995007950A1 PROCESS FOR THE PRODUCTION OF CYANINE DYES 审中-公开
标题翻译：生产氰胺染料的方法
公开(公告)号：WO1995007950A1
公开(公告)日：1995-03-23
申请号：PCT/EP1994002975
申请日：1994-09-06
申请人： AGFA-GEVAERT NAAMLOZE VENNOOTSCHAP , ROSCHGER, Peter , MICHAELIS, Stephan , HASSENRÜCK, Karin , BERNETH, Horst , CALLANT, Paul
发明人： AGFA-GEVAERT NAAMLOZE VENNOOTSCHAP
IPC分类号： C09B23/01
CPC分类号： B41M5/3375 , B41M5/24 , B41M5/32 , B41M5/42 , B41M5/465 , C09B23/0008 , C09B23/0066 , G03C1/127 , G03C1/49827 , G03C1/49854 , G03C1/4989 , G03C5/164 , Y10S430/145 , Y10S430/146
摘要： The present invention relates to a process for the production of cyanine dyes with their methine chain showing group (M) and the charge compensation occurring by linked end groups through transformation of cationic cyanine dyes comprising group (D) with CH-acid compounds of the following formula (I) B1-CH2-B2 in an inert solvent, the substituents having the significance given in the description.
摘要翻译：本发明涉及一种生产花青染料的方法，它们的次甲基链显示基团（M），并且通过将包含（D）组的阳离子花青染料与下列化合物的CH-酸化合物转化而连接的端基产生电荷补偿式（I）B1-CH2-B2在惰性溶剂中，取代基具有在说明书中给出的含义。

3. 发明申请

WO2011051112A1 NOVEL CYANINE DYES AND LITHOGRAPHIC PRINTING PLATE PRECURSORS COMPRISING SUCH DYES 审中-公开
标题翻译：新型CYANINE染色剂和包含这种染色体的平版印刷机
公开(公告)号：WO2011051112A1
公开(公告)日：2011-05-05
申请号：PCT/EP2010/065512
申请日：2010-10-15
申请人： Agfa Graphics NV , CALLANT, Paul
发明人： CALLANT, Paul
IPC分类号： B41C1/10 , C09B23/12
CPC分类号： B41C1/1008 , B41C2210/02 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/262 , C09B23/0066
摘要： A lithographic printing plate precursor comprising a cyanine dye, characterized in that the cyanine dye comprises two different chromophoric groups, a chromophoric group that has its main absorption in the infrared region and another chromophoric group that has its main absorption in the visible light region. The cyanine dye has preferably a structure according to Formula I.
摘要翻译：一种包含花青染料的平版印刷版前体，其特征在于，所述花青染料包含两个不同的发色基团，在红外区域具有主要吸收的发色基团和在可见光区域具有其主要吸收的另一发色团。花青染料优选具有式I的结构。

4. 发明申请

WO2008046773A1 NEGATIVE WORKING, HEAT-SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR 审中-公开
标题翻译：负面工作，感应式光刻印刷机前置
公开(公告)号：WO2008046773A1
公开(公告)日：2008-04-24
申请号：PCT/EP2007/060780
申请日：2007-10-10
申请人： AGFA GRAPHICS NV , ANDRIESSEN, Hieronymus , CALLANT, Paul , WILLIAMSON, Alexander
发明人： ANDRIESSEN, Hieronymus , CALLANT, Paul , WILLIAMSON, Alexander
IPC分类号： B41C1/10
CPC分类号： B41C1/1025 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24
摘要： A heat-sensitive negative-working lithographic printing plate precursor comprising: a support having a hydrophilic surface or which is provided with a hydrophilic layer; and an image-recording layer comprising hydrophobic thermoplastic polymer particles and an infrared light absorbing dye; characterized in that: said image-recording layer further comprises a compound, said compound comprising an aromatic moiety and at least one acidic group or salt thereof and having a most bathochromic light absorption peak at a wavelength between 300 nm and 450 nm.
摘要翻译：一种热敏负性平版印刷版原版，其包含：具有亲水表面的或具有亲水层的载体; 和包含疏水性热塑性聚合物颗粒和红外光吸收染料的图像记录层; 其特征在于：所述图像记录层还包含化合物，所述化合物包含芳族部分和至少一种酸性基团或其盐，并且在300nm至450nm之间的波长处具有最大的红移光吸收峰。

5. 发明申请

WO2012076354A2 COLOUR LASER MARKING METHODS OF SECURITY DOCUMENT PRECURSORS 审中-公开
标题翻译：安全文件前缀的彩色激光标记方法
公开(公告)号：WO2012076354A2
公开(公告)日：2012-06-14
申请号：PCT/EP2011/071161
申请日：2011-11-28
申请人： AGFA-GEVAERT , GEUENS, Ingrid , VAN AERT, Hubertus , CALLANT, Paul , WAUMANS, Bart
发明人： GEUENS, Ingrid , VAN AERT, Hubertus , CALLANT, Paul , WAUMANS, Bart
IPC分类号： B41M5/323 , B41M5/26 , B41M5/30 , B41M5/34
CPC分类号： B41M5/34 , B41M3/142 , B41M5/267 , B41M5/323 , B41M5/327 , B41M5/3336 , B41M5/3372 , B41M5/42 , B41M5/44 , B41M2205/04 , B41M2205/38
摘要： A method of colour laser marking a security document precursor including, in order, at least: a) a polymeric foil; b) at least one colourless colour forming layer for generating a colour different from black containing at least an infrared absorber, a colour forming compound and a polymeric binder; and c) either a lasermarkable polymeric support or a lasermarkable layer for generating a black colour;comprising the steps of: (1 ) laser marking a colour different from black in the colourless colour forming layer with an infrared laser used in continuous wave mode; and (2) laser marking a black colour by carbonization in the lasermarkable polymeric support or the lasermarkable layer with the same infrared laser used in a pulsed mode; and wherein at least one of the polymeric foil and the lasermarkable polymeric support is transparent for the infrared light of the infrared laser.
摘要翻译：一种彩色激光标记安全文件前体的方法，其包括以下步骤：至少：a）聚合物箔; b）至少一种无色成色层，用于产生与至少含有红外线吸收剂，成色化合物和聚合物粘合剂的黑色不同的颜色; 和c）用于产生黑色的可水印的聚合物支持体或可拉伸层;包括以下步骤：（1）用连续波模式中使用的红外激光在无色成色层中激光标记与黑色不同的颜色; 和（2）通过使用在脉冲模式中使用的相同红外激光的可水印聚合物支持体或可拉伸层中的碳化来激光标记黑色; 并且其中所述聚合物箔和所述可拉伸聚合物载体中的至少一种对于所述红外激光的红外光是透明的。

6. 发明申请

WO2010031758A1 A LITHOGRAPHIC PRINTING PLATE PRECURSOR 审中-公开
标题翻译：平版印刷机前驱板
公开(公告)号：WO2010031758A1
公开(公告)日：2010-03-25
申请号：PCT/EP2009/061927
申请日：2009-09-15
申请人： Agfa Graphics NV , CALLANT, Paul , VAN SEVEREN, Ineke
发明人： CALLANT, Paul , VAN SEVEREN, Ineke
IPC分类号： B41C1/10
CPC分类号： B41C1/1025 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24
摘要： A lithographic printing plate precursor comprising a coating provided on a support having a hydrophilic surface, the coating containing thermoplastic polymer particles and an infrared radiation absorbing dye characterized in that the dye contains a substituent selected from bromo and iodo.
摘要翻译：一种平版印刷版原版，其包含设置在具有亲水表面的载体上的涂层，所述涂层含有热塑性聚合物颗粒和红外辐射吸收染料，其特征在于所述染料含有选自溴和碘的取代基。

7. 发明申请

WO2006136543A3 INFRARED ABSORBING DYE 审中-公开
标题翻译：红外吸收染料
公开(公告)号：WO2006136543A3
公开(公告)日：2008-04-10
申请号：PCT/EP2006063327
申请日：2006-06-20
申请人： AGFA GRAPHICS NV , CALLANT PAUL , ANDRIESSEN HIERONYMUS , WILLIAMSON ALEXANDER , GEUKENS CHRISTEL , LOUWET JOS
发明人： CALLANT PAUL , ANDRIESSEN HIERONYMUS , WILLIAMSON ALEXANDER , GEUKENS CHRISTEL , LOUWET JOS
IPC分类号： B41C1/10 , C09B23/00 , C09B23/01 , C09B23/08 , C09B23/10
CPC分类号： B41C1/1008 , B41C1/10 , B41C1/1025 , B41C1/1041 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41M5/465 , C09B23/0066 , C09B23/0091 , C09B23/083 , C09B23/086 , C09B23/10
摘要： The present invention relates to an infrared absorbing dye as defined in claim 1. The present invention relates also to a heat- sensitive imaging element comprising said IR dye and more particularly to a heat-sensitive lithographic printing plate precursor comprising said IR dye. The present invention relates also to a method for making a lithographic printing plate whereby a print-out image of high contrast is formed upon exposure to IR- radiation or heating.
摘要翻译：本发明涉及如权利要求1所述的红外吸收染料。本发明还涉及包含所述IR染料的热敏成像元件，更具体地涉及包含所述IR染料的热敏平版印刷版原版。本发明还涉及一种制备平版印刷版的方法，由此在暴露于IR辐射或加热时形成高对比度的打印图像。

8. 发明申请

WO2006005688A1 METHOD FOR MAKING NEGATIVE-WORKING HEAT-SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR. 审中-公开
标题翻译：制造负离子热敏光刻印刷机前驱体的方法。
公开(公告)号：WO2006005688A1
公开(公告)日：2006-01-19
申请号：PCT/EP2005/053141
申请日：2005-07-01
申请人： AGFA-GEVAERT , VERMEERSCH, Joan , LOCCUFIER, Johan , CALLANT, Paul , JUNG, Jürgen , VAN DAMME, Marc
发明人： VERMEERSCH, Joan , LOCCUFIER, Johan , CALLANT, Paul , JUNG, Jürgen , VAN DAMME, Marc
IPC分类号： B41C1/10
CPC分类号： B41C1/1008 , B41C1/1025 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/26
摘要： A method for making a negative-working heat-sensitive lithographic printing plate precursor is provided which comprises the steps of (i) providing a support having a hydrophilic surface or which is provided with a hydrophilic layer, and (ii) applying on said support a coating which comprises a product DQ, wherein DQ is obtained by - the step of coating a solution or dispersion comprising a nucleophilic compound Q and a dye D selected from the list consisting of di- or tri-arylmethane dyes, cyanine dyes, styryl dyes and merostyryl dyes; or by - the step of coating a solution or dispersion comprising said compound Q and coating another solution or dispersion comprising said dye D; wherein D and Q interact to form interaction product DQ, having a white light optical density which is lower than the white light optical density of dye D, and wherein said interaction product DQ is capable of at least partially releasing a dye directly after exposure to infrared light or heat, thereby forming a visible image in said coating.
摘要翻译：提供了一种制备负性热敏平版印刷版原版的方法，其包括以下步骤：（i）提供具有亲水性表面的或具有亲水层的载体，和（ii）在所述载体上施加包括产物DQ的涂层，其中DQ是通过以下步骤获得的：涂覆包含亲核化合物Q和染料D的溶液或分散体的步骤，所述染料D选自二 - 或三 - 芳基甲烷染料，花青染料，苯乙烯基染料和美洛斯坦林染料; 或者通过以下步骤：涂布包含所述化合物Q的溶液或分散体并涂覆包含所述染料D的其它溶液或分散体; 其中D和Q相互作用以形成具有低于染料D的白光光密度的白光光密度的相互作用产物DQ，并且其中所述相互作用产物DQ能够在暴露于红外线之后直接至少部分地释放染料光或热，从而在所述涂层中形成可见图像。

9. 发明申请

WO2012076354A3 COLOUR LASER MARKING METHODS OF SECURITY DOCUMENT PRECURSORS 审中-公开
标题翻译：安全文件前缀的彩色激光标记方法
公开(公告)号：WO2012076354A3
公开(公告)日：2012-09-07
申请号：PCT/EP2011071161
申请日：2011-11-28
申请人： AGFA GEVAERT , GEUENS INGRID , VAN AERT HUBERTUS , CALLANT PAUL , WAUMANS BART
发明人： GEUENS INGRID , VAN AERT HUBERTUS , CALLANT PAUL , WAUMANS BART
IPC分类号： B41M5/26 , B41M5/30 , B41M5/323 , B41M5/34
CPC分类号： B41M5/34 , B41M3/142 , B41M5/267 , B41M5/323 , B41M5/327 , B41M5/3336 , B41M5/3372 , B41M5/42 , B41M5/44 , B41M2205/04 , B41M2205/38
摘要： A method of colour laser marking a security document precursor including, in order, at least: a) a polymeric foil; b) at least one colourless colour forming layer for generating a colour different from black containing at least an infrared absorber, a colour forming compound and a polymeric binder; and c) either a lasermarkable polymeric support or a lasermarkable layer for generating a black colour;comprising the steps of: (1) laser marking a colour different from black in the colourless colour forming layer with an infrared laser used in continuous wave mode; and (2) laser marking a black colour by carbonization in the lasermarkable polymeric support or the lasermarkable layer with the same infrared laser used in a pulsed mode; and wherein at least one of the polymeric foil and the lasermarkable polymeric support is transparent for the infrared light of the infrared laser.
摘要翻译：一种彩色激光标记安全文件前体的方法，其包括以下步骤：至少：a）聚合物箔; b）至少一种无色成色层，用于产生与至少含有红外线吸收剂，成色化合物和聚合物粘合剂的黑色不同的颜色; 和c）用于产生黑色的可水印的聚合物支持体或可拉伸层;包括以下步骤：（1）用连续波模式中使用的红外激光在无色成色层中激光标记与黑色不同的颜色; 和（2）通过使用在脉冲模式中使用的相同红外激光的可水印聚合物支持体或可拉伸层中的碳化来激光标记黑色; 并且其中所述聚合物箔和所述可拉伸聚合物载体中的至少一种对于所述红外激光的红外光是透明的。

10. 发明申请

WO2012076493A1 COLOUR LASER MARKING OF ARTICLES AND SECURITY DOCUMENTS PRECURSORS 审中-公开
标题翻译：文章和安全文件的颜色激光标记前提
公开(公告)号：WO2012076493A1
公开(公告)日：2012-06-14
申请号：PCT/EP2011/071842
申请日：2011-12-06
申请人： AGFA-GEVAERT , CALLANT, Paul , GEUENS, Ingrid , WAUMANS, Bart , VAN AERT, Hubertus
发明人： CALLANT, Paul , GEUENS, Ingrid , WAUMANS, Bart , VAN AERT, Hubertus
IPC分类号： B41M5/323 , B41M5/30 , B41M5/34 , B41M3/14 , B41M5/327
CPC分类号： B41M5/323 , B41J2/442 , B41M3/142 , B41M5/267 , B41M5/30 , B41M5/327 , B41M5/3275 , B41M5/3336 , B41M5/34 , B42D25/29 , B42D25/382 , B42D25/435 , B42D2033/30 , Y10S430/146 , Y10T428/24802
摘要： A method of colour laser marking an article having a polymeric foil with at least one colourless layer containing an infrared absorber, a polymeric binder and a colour forming compound; including the steps of: - laser marking the colourless layer with an infrared laser using a first laser operation mode to generate a blue or cyan colour; and - laser marking the same colourless layer with an infrared laser using a second laser operation mode to generate a black colour, wherein the first laser operation mode applies less energy to the colourless layer than the second laser operation mode. Also disclosed is an article, such as a security document, including a polymeric foil and a colourless layer containing laser marked graphical data having a blue or cyan colour and laser marked information having a black colour
摘要翻译：一种彩色激光标记具有聚合物箔的制品的方法，其具有至少一个含有红外线吸收剂，聚合物粘合剂和成色化合物的无色层; 包括以下步骤： - 使用第一激光操作模式用红外激光激光标记无色层以产生蓝色或青色; 以及 - 使用第二激光操作模式用红外激光器激光标记相同的无色层以产生黑色，其中所述第一激光操作模式对所述无色层施加比所述第二激光操作模式更少的能量。还公开了一种诸如安全文件的物品，包括聚合物箔和含有激光的无色层，标记的具有蓝色或青色的图形数据和具有黑色的激光标记信息

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