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    • 3. 发明申请
    • PROCESS FOR PRODUCING POWDERY POLYMERS BASED ON N-VINYL CAPROLACTAMS
    • 用于生产聚合物粉末基于N-乙烯基己内酰胺
    • WO1995015986A1
    • 1995-06-15
    • PCT/EP1994004027
    • 1994-12-03
    • BASF AKTIENGESELLSCHAFTBLANKENBURG, RainerSANNER, Axel
    • BASF AKTIENGESELLSCHAFT
    • C08F26/06
    • A61K8/817A61Q5/06A61Q19/00C05G3/0029C08F26/06C09K17/20C10M149/10C10M2217/028C10M2217/06
    • Powdery polymers based on n-vinyl caprolactams are produced by polymerising (A) 50 to 100 % by weight N-vinyl caprolactams with (B) 0 to 50 % by weight other N-vinyl lactams, vinyl heteroaromatics, vinyl esters, C1 to C10 alkyl acrylates or methacrylates or a mixture thereof and (C) 0 to 5 % by weight monoethylenically unsaturated monomers containing acid groups. For that purpose, (i) the monomers A, B and C are polymerised in a homogenous aqueous solution that contains 10 to 95 % by weight, in relation to the water, of a water-miscible organic solvent, or in a homogeneous mixture of 0 to 90 % by weight water and 100 to 10 % by weight methanol in the presence of a radical-forming initiator, and water is then substituted for the organic solvent; or (ii) the monomers A, B and C are polymerised in an aqueous emulsion in the presence of a radical-forming initiator and if required in the presence of an emulsifier. The thus obtained aqueous polymer solutions or dispersions are subjected to a usual drying process to produce powdery polymers.
    • 基于N-乙烯基己内酰胺粉状聚合物由聚合物伊辛(A)50至100%的(B)0至50%(重量)其它N-乙烯基内酰胺,乙烯基杂芳族化合物,乙烯基酯,C1至C10产生的重量的N-乙烯基己内酰胺 丙烯酸烷基酯或甲基丙烯酸酯或(重量)单烯属不饱和单体含有酸基团及其混合物和(C)0至5%。 为了该目的,(i)所述单体A,B和C以均匀wässrige溶液做下聚合含有10〜95%(重量),溶剂相对于水,可与水混溶的有机,或在的均匀混合物 0至90%重量的水和100%至10%通过在形成自由基的引发剂的存在重量的甲醇和水是然后substituiertem用于有机溶剂; 或(ii)的单体A,B和C被聚合在一个形成自由基的引发剂的水溶液的存在下乳化,并且如果在乳化剂的存在需要。 由此获得的聚合物wässrige溶液或分散体经受常规的干燥工艺生产粉状聚合物。