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1. 发明申请

WO1992015525A1 HYDROXIDE COMPOUNDS OF SPECIFIC COMPOSITION, METHOD FOR PREPARING THEM AND THEIR USE 审中-公开
标题翻译：特定组合物的氢氧化物化合物，其制备方法及其用途
公开(公告)号：WO1992015525A1
公开(公告)日：1992-09-17
申请号：PCT/DE1992000145
申请日：1992-02-21
申请人： BÄRLOCHER GMBH , RAZVAN, Coriolan , BECK, Reinhard , KÜRZINGER, Alfred , ROSENTHAL, Michael , PÜRZER, Albert, W.
发明人： BÄRLOCHER GMBH
IPC分类号： C01F07/00
CPC分类号： C08K3/30 , C01B13/14 , C01B13/363 , C01B25/45 , C01F7/002 , C01G9/006 , C01P2002/22 , C08K3/014 , C08K3/32 , C08L27/00
摘要： The invention discloses compounds of general formula (I), wherein X is a trivalent metal; Y is a divalent metal; A is an inorganic or organic anion of valency n; 0.1

2. 发明申请

WO1992013800A1 HYDROXIDE COMPOUNDS OF A CERTAIN COMPOSITION, PROCESS FOR MAKING THEM AND THEIR USE 审中-公开
标题翻译：某些组合物的羟基化合物，其制备方法及其使用
公开(公告)号：WO1992013800A1
公开(公告)日：1992-08-20
申请号：PCT/DE1992000095
申请日：1992-02-07
申请人： BÄRLOCHER GMBH , RAZVAN, Coriolan , BECK, Reinhard , KÜRZINGER, Alfred , ROSENTHAL, Michael , PÜRZER, Albert, W.
发明人： BÄRLOCHER GMBH
IPC分类号： C01F07/00
CPC分类号： C08K3/30 , C01B13/363 , C01F7/002 , C01G49/009 , C01P2002/22 , C08K3/32 , C08L27/06
摘要： The invention describes compounds of general formula (I) in which: X3+ is a trivalent metal; Y2+ is a divalent metal; An- is an inorganic or organic anion with the valency n; 0.1 « a « 0.5; 0 « b « 1; 0 « m « 2; and n is a whole number, and a process for making them. The compounds of the invention are particularly suitable as stabilisers for halogen-containing thermoplastic resins, especially PVC.

3. 发明申请

WO1992015523A1 BASIC CALCIUM ALUMINIUM HYDROXYPHOSPHITES, METHOD FOR PREPARING THEM AND USE THEREOF 审中-公开
标题翻译：碱性钙铝羟基磷灰石，其制备方法及其用途
公开(公告)号：WO1992015523A1
公开(公告)日：1992-09-17
申请号：PCT/DE1992000144
申请日：1992-02-21
申请人： BÄRLOCHER GMBH , RAZVAN, Coriolan , BECK, Reinhard , KÜRZINGER, Alfred , PÜRZER, Albert, W. , ROSENTHAL, Michael
发明人： BÄRLOCHER GMBH
IPC分类号： C01B25/163
CPC分类号： C08K3/32 , C01B25/163 , C08L27/06
摘要： The invention discloses basic calcium aluminium hydroxyphosphites of general formula: CaxAl2(OH)¿2(x+3-y)?(HPO3)y.H2O, wherein x is a number between 2 and 12; (2x+5)/2 > y > 0; m is a number between 0 and 12; being excepted y = 1, if x = 2 to 8. The compounds of the invention are particularly useful as stabilizers for halogenated polymers, in particular PVC.

4. 发明申请

WO1992012984A1 METHOD FOR THE DIRECT SYNTHESIS OF ORGANO-TIN CHLORIDES, AND THE USE OF SUCH CHLORIDES 审中-公开
标题翻译：用于直接合成有机氯化物的方法及其使用方法
公开(公告)号：WO1992012984A1
公开(公告)日：1992-08-06
申请号：PCT/DE1992000037
申请日：1992-01-21
申请人： BÄRLOCHER GMBH , MALGUZZI, Romualdo , SANDRI, Maurizio , ROSENTHAL, Michael , PÜRZER, Albert, W.
发明人： BÄRLOCHER GMBH
IPC分类号： C07F07/22
CPC分类号： C07F7/2208
摘要： A process for the direct synthesis of oroganotin chlorides of the formula RnSnCl4-n n = 1 - 2 and R being a linear or branched or cycloaliphatic alkyl having 4 to 18 carbon atoms, by reacting tin(II) chloride with alkyl chlorides, characterized in that the reaction is carried out in the presence of amines of the general formula A) R1a N ¢(CH2CH2O)m CH2CH2OR2!3-a and/or ammonium chlorides of the formula B) R1b N? ¢(CH2CH2O)m CH2CH2OR2!4-b C1? a = 0, 1 or 2; b = 0, 1, 2 or 3; R1 is a linear or branched or cycloaliphatic alkyl with 2 to 24 C atoms, aryl, alkyl aryl or substituted aryl and, if a = 2 or b = 2 or 3, the R1 groups may be the same or different; R2 is H, a linear or branched alkyl with 1 to 20 C atoms, aryl, substituted aryl or alkyl aryl; and 13 m = 1 - 20 The organotin chlorides produced in this fashion are especially suited as intermediate products for the production of thermostabilizers for PVC resins.

5. 发明申请

WO1992022558A2 METHOD FOR THE DIRECT SYNTHESIS OF ORGANO-TIN CHLORIDES, AND THEIR USE 审中-公开
标题翻译：直接合成有机氯化物的方法及其应用
公开(公告)号：WO1992022558A2
公开(公告)日：1992-12-23
申请号：PCT/DE1992000408
申请日：1992-05-13
申请人： BÄRLOCHER GMBH , MALGUZZI, Romualdo , SANDRI, Maurizio , ROSENTHAL, Michael , PÜRZER, Albert, W.
发明人： BÄRLOCHER GMBH
IPC分类号： C07F07/22
CPC分类号： C07F7/2208
摘要： Disclosed is a method of synthesizing directly organo-tin chlorides of formula: RnSnCl4-n, in which n = 1 or 2 and R is a straight-chain or branched-chain or cycloaliphatic alkyl group with 4 to 18 C-atoms, by reacting metallic tin and/or tin(II) chloride with alkyl chlorides. The method is characterized in that the reaction is carried out in the presence of diamines of formula (A): R1R2N(CH2CH2O)mCH2CH2NR3R4 and/or ammonium chloride of formula (B1) or (B2), in which R1, R2, R3, R4, R5 and R6, independently of each other, may be a straight-chain or branched-chain or cycloaliphatic alkyl with 2 to 24 C-atoms, aryl, alkylaryl or substituted aryl, and m is from 1 to 20. The compounds thus prepared are suitable for use as intermediates in the preparation of thermostabilizers for PVC resins.

6. 发明申请

WO1992015545A1 BASIC CALCIUM ALUMINIUM HYDROXIDE DICARBOXYLATES, METHOD FOR PREPARING THEM AND USE THEREOF 审中-公开
标题翻译：碱性钙铝氢氧化二甲基硅氧烷，其制备方法及其用途
公开(公告)号：WO1992015545A1
公开(公告)日：1992-09-17
申请号：PCT/DE1992000143
申请日：1992-02-21
申请人： BÄRLOCHER GMBH , RAZVAN, Coriolan , BECK, Reinhard , KÜRZINGER, Alfred , PÜRZER, Albert, W. , ROSENTHAL, Michael
发明人： BÄRLOCHER GMBH
IPC分类号： C07C57/15
CPC分类号： C07C63/28 , C07C55/08 , C07C55/10 , C07C55/14 , C07C57/145 , C07C57/15 , C07C63/20 , C07C63/24 , C08K5/098 , C08L27/06
摘要： The invention concerns basic calcium aluminium hydroxide dicarboxylates of the following formula: CaxAl2(OH)¿2(x+3-y)?Ay . m H2O, wherein x is a number between 2 and 12; (2x+5)/2 > y > 0; m is a number between 0 and 12; and A is an aliphatic, aromatic or heteroaromatic dicarboxylic acid anion or combinations thereof; y = 1 being excepted when x = 2 to 8. A method for preparing them is also disclosed. The compounds of the invention are particularly useful as stabilizers for halogenated thermoplastic resins, in particular PVC.

7. 发明申请

WO1991011421A1 BASIC CALCIUM ALUMINIUM HYDROXIDE DICARBOXYLATES, PROCESS FOR PRODUCING THEM AND THEIR USE 审中-公开
标题翻译：碱性钙氢氧化二甲基硅氧烷，其生产方法及其使用
公开(公告)号：WO1991011421A1
公开(公告)日：1991-08-08
申请号：PCT/EP1991000077
申请日：1991-01-17
申请人： BÄRLOCHER GMBH , RAZVAN, Coriolan , BECK, Reinhard , KÜRZINGER, Alfred , PÜRZER, Albert, W. , ROSENTHAL, Michael
发明人： BÄRLOCHER GMBH
IPC分类号： C07C57/15
CPC分类号： C07C63/28 , C07C55/08 , C07C55/10 , C07C55/14 , C07C57/145 , C07C57/15 , C07C63/20 , C07C63/24 , C08K3/22 , C08L27/06
摘要： The invention describes basic calcium aluminium hydroxyde dicarboxylates of the general formula: CaxAl2(OH)2(x+2)A. m H2O in which x = 2 - 8; m = 0 -12; and A is an aliphatic, aromatic or heteroaromatic dicarboxylic acid anion or combinations thereof, and a process for their production. The compounds of the invention are especially suitable as stabilisers for halogen-containing thermoplastic resins, especially PVC.

8. 发明申请

WO1991009039A2 PROCESS FOR DIRECT SYNTHESIS OF ORGANOTIN COMPOUNDS AND USE OF SAID COMPOUNDS 审中-公开
标题翻译：有机化合物的直接合成方法和合成化合物的使用
公开(公告)号：WO1991009039A2
公开(公告)日：1991-06-27
申请号：PCT/EP1990002219
申请日：1990-12-17
申请人： BÄRLOCHER GMBH , MALGUZZI, Romualdo , SANDRI, Maurizio , ROSENTHAL, Michael , PÜRZER, Albert, W.
发明人： BÄRLOCHER GMBH
IPC分类号： C07F07/22
CPC分类号： C07F7/2208
摘要： Process for direct synthesis of organotin compounds of formula (1): RnSnCl4-n, where n = 1 to 4 and R is a linear or branched or cycloaliphatic alkyl with 4 to 8 C atoms, by reacting metallic tin with alkyl chlorides, characterized in that the reaction is carried out in the presence of amines of general formula (A): R aN[(CH2CH2O)mCH2CH2OR ]3-a, and/or ammonium chlorides of formula (B): R bN[(CH2CH2O)mCH2CH2OR ]4-bCl, where a = 0, 1 or 2, b = 0, 1, 2 or 3, R is a linear or branched or cycloaliphatic alkyl with 2 to 24 C atoms, aryl, alkylaryl or substituted aryl and, if a = 2 or b = 2 or 3, the R groups can be the same or different, R is H, linear or branched alkyl with 1 to 20 C atoms, aryl, substituted aryl or alkylaryl, and m = 1 to 20.
摘要翻译：用于直接合成式（1）的有机锡化合物的方法：RnSnCl4-n，其中n = 1至4，R为具有4至8个C原子的直链或支链或脂环族烷基，金属锡与烷基氯反应，其特征在于反应在通式（A）的胺存在下进行：R 1 a [[CH 2 CH 2 O] m CH 2 CH 2 OR 2] 3-a和/或式（B）的氯化铵：R 1 > bN [（CH 2 CH 2 O）mCH 2 CH 2 OR 2] 4-bCl，其中a = 0,1或2，b = 0,1,2或3，R 1是具有2至24个直链或支链或直链或支链的烷基 C原子，芳基，烷基芳基或取代的芳基，如果a = 2或b = 2或3，R 1可以相同或不同，R 2是H，具有1至20个的直链或支链烷基 C原子，芳基，取代的芳基或烷芳基，m = 1至20。

9. 发明申请

WO1994016006A1 USE OF MONOSALICYLATES OF BIVALENT METALS TO STABILIZE CHLORINE-CONTAINING POLYMERS 审中-公开
标题翻译： MONOSALICYLATEN二价金属的用于稳定含氯聚合物USE
公开(公告)号：WO1994016006A1
公开(公告)日：1994-07-21
申请号：PCT/EP1994000002
申请日：1994-01-03
申请人： BÄRLOCHER GMBH , RAZVAN, Coriolan , HACKER, Peter , KÜRZINGER, Alfred , REITH, Walter , ROSENTHAL, Michael
发明人： BÄRLOCHER GMBH
IPC分类号： C08K05/00
CPC分类号： C08K5/098 , C08L27/06
摘要： The invention concerns the use of at least one optionally substituted salicylate of at least one bivalent metal, the salicylate and metal being present in a molar ratio of about 1:1, to stabilize chlorine-containing polymers such as vinyl chloride polymers and in particular poly(vinyl chloride) against degradation by heat and light.

10. 发明申请

WO1992013914A1 USE OF COMPOUNDS OF THE HYDROCALUMITE TYPE AS STABILISERS FOR HALOGEN-CONTAINING THERMOPLASTIC RESINS 审中-公开
标题翻译：用作含卤化物热稳定树脂的稳定剂的氢氯酸盐类化合物的使用
公开(公告)号：WO1992013914A1
公开(公告)日：1992-08-20
申请号：PCT/DE1992000093
申请日：1992-02-07
申请人： BÄRLOCHER GMBH , KÜRZINGER, Alfred , BECK, Reinhard , RAZVAN, Coriolan , ROSENTHAL, Michael , PÜRZER, Albert, W.
发明人： BÄRLOCHER GMBH
IPC分类号： C08K03/22
CPC分类号： C08K3/22 , C08L27/06
摘要： The use of compounds of the hydrocalumite type of the general formula: AlCax(OH)2x+3.mH2O, in which x = 1-4 and m = 0-8, as stabilisers for halogen-containing thermoplastic resins, especially PVC.

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