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    • 1. 发明申请
    • WATER ANALYSIS USING A PHOTOELECTROCHEMICAL METHOD
    • 使用光电化学方法进行水分析
    • WO2007016740A1
    • 2007-02-15
    • PCT/AU2006/001132
    • 2006-08-10
    • AQUA DIAGNOSTICS PTY. LTD.ZHAO, HuijunZHANG, Shanqing
    • ZHAO, HuijunZHANG, Shanqing
    • G01N27/30G01N33/18
    • G01N33/1806G01N27/305H01M14/005
    • A method of determining chemical oxygen demand in water samples containing chloride ions above 0.5mM concentration in which the samples are diluted and a known quantity of an organic substance is added to the diluted sample which is the subjected to an assay by a photoelectrochemical method using a titanium dioxide nanoparticulate semiconductor electrode and measuring the photo current produced until a stable value is reached and then using the difference between the initial and stable photocurrents as a measure of the chemical oxygen demand. An alternative method involves determining chemical oxygen demand in water samples containing chloride ions by measuring the chlorine content and measuring chemical oxygen demand by a photoelectrochemical method using a titanium dioxide nanoparticulate semiconductor electrode and adjusting the chemical oxygen demand measurement using the chlorine measurement.
    • 测定含有0.5mM浓度以上的氯离子的水样中化学需氧量的方法,其中样品被稀释,并将已知量的有机物质加入到通过光电化学方法进行测定的稀释样品中,使用 二氧化钛纳米颗粒半导体电极,并测量所产生的光电流,直到达到稳定值,然后使用初始和稳定光电流之间的差作为化学需氧量的量度。 一种替代方法包括通过使用二氧化钛纳米颗粒半导体电极的光电化学方法测量氯含量并测量化学需氧量来测定含有氯离子的水样品中的化学需氧量,并使用氯测量来调节化学需氧量测量。