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1. 发明申请

WO2007075718A1 A CURABLE EPOXY RESIN COMPOSITION HAVING A MIXED CATALYST SYSTEM AND LAMINATES MADE THEREFROM 审中-公开
标题翻译：具有混合催化剂体系的可固化环氧树脂组合物及其制备的层压体
公开(公告)号：WO2007075718A1
公开(公告)日：2007-07-05
申请号：PCT/US2006/048484
申请日：2006-12-19
申请人： DOW GLOBAL TECHNOLOGIES INC. , VALETTE, Ludovic , AOYAMA, Tomoyuki
发明人： VALETTE, Ludovic , AOYAMA, Tomoyuki
IPC分类号： C08G59/62 , C08G59/68
CPC分类号： C08G59/621 , C08G59/686 , C08G59/688 , H05K1/0326 , Y10T428/31525 , Y10T428/31529 , Y10T442/2418
摘要： A curable halogen-containing epoxy resin composition comprising: (a) at least one epoxy resin; (b) at least one hardener; wherein the hardener is a compound containing a phenolic hydroxyl functionality or a compound capable of generating a phenolic hydroxyl functionality upon heating; and (c) a catalytic amount of a catalyst system comprising a combination of: (i) at least a first catalyst compound comprising at least one nitrogen-containing catalyst compound; and (ii) at least a second catalyst compound comprising at least one phosphorus-containing catalyst compound; wherein at least one or more of the above components (a)-(c) is halogenated or contains halogen; or if none of the above components are halogenated wherein the resin composition includes (d) a halogenated or halogen-containing flame retardant compound that does not contain nitrogen. The stroke cure gel time of the resin composition is maintained from 90 seconds to 600 seconds when measured at 170cC; and the cured product formed by curing the curable epoxy resin composition contains well-balanced properties. The composition may be used to obtain a prepreg or a metal-coated foil, or a laminate by laminating the above prepreg and/or the above metal-coated foil. The laminate shows a combination of superior glass transition temperature, decomposition temperature, time to delamination at 288°C, adhesion to copper foil, and excellent flame retardancy.
摘要翻译：一种可固化含卤素的环氧树脂组合物，其包含：（a）至少一种环氧树脂; （b）至少一种硬化剂; 其中所述固化剂是含有酚羟基官能团的化合物或在加热时能够产生酚羟基官能团的化合物; 和（c）催化量的催化剂体系，其包含以下组合的组合：（i）至少包含至少一种含氮催化剂化合物的第一催化剂化合物; 和（ii）至少一种包含至少一种含磷催化剂化合物的第二催化剂化合物; 其中至少一种或多种上述组分（a） - （c）被卤化或含有卤素; 或者如果上述组分都不是卤化的，其中树脂组合物包括（d）不含氮的卤化或含卤阻燃化合物。当在170℃下测量时，树脂组合物的冲程固化凝胶时间保持在90秒至600秒; 并且通过固化可固化环氧树脂组合物形成的固化产物包含良好平衡的性质。该组合物可以用于通过层压上述预浸料和/或上述金属涂覆的箔来获得预浸料或金属涂覆的箔或层压体。该叠层体表现出优异的玻璃化转变温度，分解温度，288℃下的分层时间，对铜箔的粘附性和优异的阻燃性的组合。

2. 发明申请

WO2010078688A1 METAL STABILIZERS FOR EPOXY RESINS 审中-公开
标题翻译：环氧树脂的金属稳定剂
公开(公告)号：WO2010078688A1
公开(公告)日：2010-07-15
申请号：PCT/CN2009/000013
申请日：2009-01-06
申请人： DOW GLOBAL TECHNOLOGIES INC. , AOYAMA, Tomoyuki , GONG, Frank, Y. , HOEVEL, Bernd , MULLINS, Michael, J. , REN, Perrin, Shaoping , STORER, Joey, W. , SUE, Hung-Jue , VALETTE, Ludovic , WORKU, Anteneh, Z. , THIBAULT, Raymond, J.
发明人： AOYAMA, Tomoyuki , GONG, Frank, Y. , HOEVEL, Bernd , MULLINS, Michael, J. , REN, Perrin, Shaoping , STORER, Joey, W. , SUE, Hung-Jue , VALETTE, Ludovic , WORKU, Anteneh, Z. , THIBAULT, Raymond, J.
IPC分类号： C08L63/02 , C08K3/22 , C08K5/56 , C09D163/02 , C09J163/02
CPC分类号： C09J163/00 , C08J5/24 , C08J2363/00 , C08K3/014 , C08K3/22 , C08K3/34 , C08K5/005 , C08K5/0091 , C08K5/098 , C08K5/39 , C08K2003/168 , C08K2003/2296 , C08K2003/321 , C08K2003/387 , C08L63/00 , C09D163/00 , H05K1/0373 , C08L2666/04
摘要： A composition comprising: a) an epoxy resin; b) a hardener; and c) a stabilizer comprising a metal-containing compound, the metal-containing compound comprising a metal selected from the group consisting of Group 11-13 metals and combinations thereof, wherein the composition is prepared from a halogen-containing compound is disclosed.
摘要翻译：一种组合物，其包含：a）环氧树脂; b）硬化剂; 和c）包含含金属化合物的稳定剂，所述含金属化合物包含选自组11-13金属的金属及其组合，其中所述组合物由含卤素的化合物制备。

3. 发明申请

WO2007075769A1 A CURABLE EPOXY RESIN COMPOSITION AND LAMINATES MADE THEREFROM 审中-公开
标题翻译：可固化的环氧树脂组合物和层压材料
公开(公告)号：WO2007075769A1
公开(公告)日：2007-07-05
申请号：PCT/US2006/048578
申请日：2006-12-20
申请人： DOW GLOBAL TECHNOLOGIES INC. , VALETTE, Ludovic , AOYAMA, Tomoyuki
发明人： VALETTE, Ludovic , AOYAMA, Tomoyuki
IPC分类号： C08G59/40 , C08G59/42 , C08J5/24 , C08L63/00 , H05K1/00
CPC分类号： C08G59/621 , C08G59/30 , C08G59/4014 , C08G59/4223 , C08J5/24 , C08J2363/02 , C08K5/13 , H05K1/0326 , Y10T428/31511 , Y10T428/31529 , Y10T442/30
摘要： A curable halogen-containing epoxy resin composition comprising: (a) at least one epoxy resin; (b) at least one hardener; wherein the hardener is a compound containing a phenolic hydroxyl functionality or a compound capable of generating a phenolic hydroxyl functionality upon heating; (c) a catalytic amount of a nitrogen- containing catalyst; (d) a non-nitrogen containing catalyst adjuvant compound capable of reducing the concentration of the nitrogen-containing catalyst; wherein at least one of the above components (a)-(d) is halogenated or wherein the resin composition includes (e) a halogenated flame retardant compound. The stroke cure gel time of the resin composition is maintained from 90 seconds to 600 seconds when measured at 1700C; and the resultant cured product formed by curing the curable epoxy resin composition contains well-balanced properties. The composition may be used to obtain a prepreg or a metal-coated foil, or a laminate by laminating the above prepreg and/or the above metal-coated foil. The laminate shows a combination of superior glass transition temperature, decomposition temperature, time to delamination at 288°C, adhesion to copper foil, and excellent flame retardancy.
摘要翻译：一种可固化含卤素的环氧树脂组合物，其包含：（a）至少一种环氧树脂; （b）至少一种硬化剂; 其中所述固化剂是含有酚羟基官能团的化合物或在加热时能够产生酚羟基官能团的化合物; （c）催化量的含氮催化剂; （d）能够降低含氮催化剂浓度的不含氮的催化剂助剂; 其中上述组分（a） - （d）中的至少一种是卤化的或其中树脂组合物包含（e）卤化阻燃化合物。当在170℃下测量时，树脂组合物的冲程固化凝胶时间保持为90秒至600秒; 通过固化可固化环氧树脂组合物形成的所得固化产物具有良好平衡的性能。该组合物可以用于通过层压上述预浸料和/或上述金属涂覆的箔来获得预浸料或金属涂覆的箔或层压体。该层压体显示出优异的玻璃化转变温度，分解温度，288℃下分层时间，对铜箔的粘附性和优异的阻燃性的组合。

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