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    • 2. 发明申请
    • SILOXANE STAR-GRAFT POLYMERS, CERAMIC POWDERS COATED THEREWITH AND METHOD OF PREPARING COATED CERAMIC POWDERS
    • 硅氧烷星形聚合物,其中涂覆的陶瓷粉末和制备涂层陶瓷粉末的方法
    • WO1997038041A1
    • 1997-10-16
    • PCT/US1997005179
    • 1997-03-28
    • NANOPHASE TECHNOLOGIES CORPORATIONBROTZMAN, Richard, W., Jr.AIKENS, John, H.
    • NANOPHASE TECHNOLOGIES CORPORATION
    • C08G77/06
    • C04B35/62807C01P2004/80C01P2004/84C04B35/628C04B35/62886C04B2235/3217C04B2235/3232C04B2235/3272C04B2235/3284C04B2235/3418C04B2235/483C08G77/04C08K9/08C09C1/3081C09C1/3684C09C3/12Y10T428/2995Y10T428/2998
    • A coated ceramic powder comprises a plurality of ceramic particles and a siloxane star-graft coating polymer encapsulating at least a portion of the particles. The coating polymer comprises Si(w,x,y,z), where w, x, y and z are the mole percent tetrafunctional, trifunctional, difunctional and monofunctional monomeric units, respectively, and wherein w is about 20-100 and x, y and z are about 0-30, 0-50 and 0-10, respectively, and at least one of x, y and z is greater than zero. A method of preparing a coated ceramic powder comprises the steps of a) polymerizing a tetrafunctional siloxane monomer and at least one of a trifunctional siloxane monomer, a difunctional siloxane monomer and a monofunctional siloxane monomer, b) adding a quantity of ceramic powder to a reaction vessel, c) shear mixing the ceramic powder for a time sufficient to wet substantially all of the powder surface, d) adding the siloxane polymer prepared in step (a) to the reaction vessel containing the shear mixed ceramic powder, e) shear mixing the shear mixed ceramic powder and the siloxane polymer for a time sufficient to form a siloxane polymer coated ceramic powder, and f) separating the coated ceramic powder from the components remaining in the reaction vessel.
    • 涂覆的陶瓷粉末包括多个陶瓷颗粒和封装至少一部分颗粒的硅氧烷星形接枝涂层聚合物。 涂层聚合物包含Si(w,x,y,z),其中w,x,y和z分别是四官能,三官能,双官能和单官能单体单元的摩尔百分比,其中w为约20-100,x, y和z分别为0-30,0-50和0-10,x,y和z中的至少一个大于零。 制备涂覆的陶瓷粉末的方法包括以下步骤:a)使四官能硅氧烷单体和三官能硅氧烷单体,双功能硅氧烷单体和单官能硅氧烷单体中的至少一种聚合,b)向反应中加入一定量的陶瓷粉末 容器,c)将陶瓷粉末剪切混合足以使基本上所有粉末表面湿润的时间; d)将步骤(a)中制备的硅氧烷聚合物加入到含有剪切混合陶瓷粉末的反应容器中,e) 剪切混合陶瓷粉末和硅氧烷聚合物的时间足以形成硅氧烷聚合物涂覆的陶瓷粉末,以及f)将涂覆的陶瓷粉末与保留在反应容器中的组分分离。