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1. 发明申请

WO2003047752A1 METHOD OF MAKING MIXED ZIEGLER-NATTA/METALLOCENE CATALYSTS 审中-公开
标题翻译：制备混合的ZIEGLER-NATTA / METALLOCENE催化剂的方法
公开(公告)号：WO2003047752A1
公开(公告)日：2003-06-12
申请号：PCT/US2002/031777
申请日：2002-10-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , SHIRODKAR, Pradeep, P.
发明人： MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , SHIRODKAR, Pradeep, P.
IPC分类号： B01J31/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F4/6541 , C08F4/651 , C08F4/6546 , C08F4/65904 , C08F210/14 , C08F2500/12 , C08F4/025
摘要： Methods of making mixed Ziegler-Natta/metallocene catalysts are disclosed. The methods include slurrying a dehydrated support in a hydrocarbon solvent, adding a dialkylmagnesium compound, then adding a non-metallocene group 4 or 5 metal compound, followed by adding a metallocene, an alumoxane, and optionally an aklyl aluminum compound and an electron donor compound, followed by drying the product. The alumoxane is added in an aromatic solvent.
摘要翻译：公开了制造混合的齐格勒 - 纳塔/茂金属催化剂的方法。所述方法包括将脱水载体在烃溶剂中制浆，加入二烷基镁化合物，然后加入非茂金属基团4或5金属化合物，然后加入茂金属，铝氧烷和任选的烷基铝化合物和电子给体化合物，然后干燥产品。将铝氧烷加入芳族溶剂中。

2. 发明申请

WO2003022890A1 METHOD FOR PREPARING POLYOLEFINS 审中-公开
标题翻译：制备聚烯烃的方法
公开(公告)号：WO2003022890A1
公开(公告)日：2003-03-20
申请号：PCT/US2002/021513
申请日：2002-07-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , DACKSON, Keith , SCHREGENBERGER, Sandra, D. , SHIRODKAR, Pradeep, P.
发明人： MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , DACKSON, Keith , SCHREGENBERGER, Sandra, D. , SHIRODKAR, Pradeep, P.
IPC分类号： C08F4/602
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F2400/02 , C08F2/00 , C08F4/6546 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/01 , C08F2500/02 , C08F2500/12 , C08F2500/07
摘要： A method is disclosed for preparing broad or bimodal molecular weight distribution polyolefins having a targeted property, such as, flow index, melt flow ratio, or weight fractions of higher or lower molecular weight components. The method uses a bimetallic catalyst containing a metallocene component and a non-metallocene component, and the activities of the metallocene and non-metallocene portions are controlled by adjusting the ratio of organoaluminum and modified methylaluminoxane cocatalyst. The method allows for monitoring and adjustment of polyolefin properties on a real-time basis, as the polyolefin is forming.
摘要翻译：公开了一种用于制备具有目标性质如流动指数，熔体流动比或更高或更低分子量组分的重量分数的宽双峰分子量分布聚烯烃的方法。该方法使用含有茂金属组分和非金属茂组分的双金属催化剂，通过调节有机铝和改性甲基铝氧烷助催化剂的比例来控制茂金属和非茂金属部分的活性。该方法允许在聚烯烃形成时实时监测和调节聚烯烃性能。

3. 发明申请

WO2002083753A1 PROPYLENE ETHYLENE COPOLYMERS 审中-公开
标题翻译：丙烯乙烯共聚物
公开(公告)号：WO2002083753A1
公开(公告)日：2002-10-24
申请号：PCT/US2001/012019
申请日：2001-04-12
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , COZEWITH, Charles , DATTA, Sudhin , HU, Weiguo
发明人： COZEWITH, Charles , DATTA, Sudhin , HU, Weiguo
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F210/06 , C08F4/65927 , C08F2500/20 , C08F2500/03 , C08F2500/21 , C08F2500/15
摘要： Ethylene propylene copolymers, substantially free of diene, are described. The copolymers will have a uniform distribution of both tacticity and comonomer between copolymer chains. Further, the copolymers will exhibit a statistically insignificant intramolecular difference of tacticity. The copolymers are made in the presence of a metallocene catalyst.
摘要翻译：描述了基本上不含二烯的乙烯丙烯共聚物。共聚物在共聚物链之间具有均匀分布的立构规整度和共聚单体。此外，共聚物将显示统计学上不明显的立构规整度的分子内差异。共聚物在茂金属催化剂的存在下制备。

4. 发明申请

WO2003106341A1 SYNTHESIS OF ALUMINOPHOSPHATES AND SILICOALUMINOPHOSPHATES 审中-公开
标题翻译：合成磷酸氢钙和磷酸铝磷酸盐
公开(公告)号：WO2003106341A1
公开(公告)日：2003-12-24
申请号：PCT/US2003/018358
申请日：2003-06-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CAO, Guang , SHAH, MATU, J.
发明人： CAO, Guang , SHAH, MATU, J.
IPC分类号： C01B37/04
CPC分类号： C10G3/00 , B01J27/12 , B01J29/83 , B01J29/84 , B01J29/85 , B01J35/023 , B01J2229/42 , C01B37/04 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/62 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The invention is directed to a method of synthesising silicoaluminophosphate and aluminophosphate molecular sieves using synthesis templates that contain at least one template of general formula (I) R 1 R 2 N-R 3 (I) wherein - R 1 and R 2 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; - R 3 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms, 4 to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S. In particular, the present invention relates to the synthesis of silicoaluminophosphate molecular sieves of the CHA framework tγpe having a low silicon to aluminium atomic ratio.
摘要翻译：本发明涉及使用含有至少一个通式（I）R 1 R 2 NR 3（I）的模板的合成模板来合成硅铝磷酸盐和磷酸铝分子筛的方法，其中-R 1 和R 2独立地选自具有1至3个碳原子的烷基和具有1至3个碳原子的羟烷基; -R 3选自4-8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代，具有1至3个杂原子的4至8元杂环基所述杂环基任选被1至3个具有1至3个碳原子的烷基取代，所述杂环基中的杂原子选自O，N和S.特别地，本发明涉及合成具有低硅铝原子比的CHA骨架tgammape的硅铝磷酸盐分子筛。

5. 发明申请

WO2003044061A1 POLYMERIZATION MONITORING AND CONTROL USING LEADING INDICATORS 审中-公开
标题翻译：使用引导指标的聚合监测和控制
公开(公告)号：WO2003044061A1
公开(公告)日：2003-05-30
申请号：PCT/US2002/032765
申请日：2002-10-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , EHRMAN, Fred, D. , SHIRODKAR, Pradeep, P.
发明人： SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , EHRMAN, Fred, D. , SHIRODKAR, Pradeep, P.
IPC分类号： C08F2/34
CPC分类号： C08F10/02 , C08F4/65904 , C08F4/65916 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： Methods of monitoring and controlling polymerization reactions are disclosed. The ratio of concentrations of two reactor components are determined in a gas stream of a reactor to obtain a leading indicator function L. The value of L or a function of L, such as rescaled value or a reciprocal, is compared to a target value, and at least one reactor parameter is adjusted in response to a deviation between L or the function of L and the target value. Monitoring of the leading indicator permits rapid diagnosis of reactor problems, and rapid adjustments of reactor parameters, compared to laboratory analysis of samples of polymer properties.
摘要翻译：公开了监测和控制聚合反应的方法。在反应器的气流中确定两个反应器组分的浓度比，以获得前导指示函数L.将L或L的函数（例如重新缩放值或倒数）的值与目标值进行比较，并且响应于L或L的函数与目标值之间的偏差来调整至少一个电抗器参数。与聚合物性质样品的实验室分析相比，主要指标的监测可以快速诊断反应堆问题，并快速调整反应器参数。

6. 发明申请

WO2003033585A1 POLYMERIC MEMBRANE COMPOSITIONS 审中-公开
标题翻译：聚合膜组合物
公开(公告)号：WO2003033585A1
公开(公告)日：2003-04-24
申请号：PCT/US2002/027968
申请日：2002-09-03
申请人： EXXONMOBILE CHEMICAL PATENTS INC. , DHARMARAJAN, Raja, N. , YU, Thomas, C.
发明人： DHARMARAJAN, Raja, N. , YU, Thomas, C.
IPC分类号： C08L9/00
CPC分类号： C08L23/0815 , C08L23/10 , C08L2666/04
摘要： Blends of very low density polyethylene produced using metallocene catalyst (mVLDPE) and polypropylene are disclosed. The polymer blends include a metallocene-catalyzed VLDPE polymer having a density of less than 0.916 g/cm 3 , the mVLDPE polymer preferably being linear and without long chain branching, a polyproylene homopolymer, random copolymer, or impact copolymer, and optionally flame retardant additives. The polymer blends are particularly suitable in membrane applications where increased tear resistance and tensile strength are desirable, such as in roof membranes, geomembranes, and pond liners.
摘要翻译：公开了使用金属茂催化剂（mVLDPE）和聚丙烯生产的非常低密度聚乙烯的共混物。聚合物共混物包括密度小于0.916g / cm 3的茂金属催化的VLDPE聚合物，mVLDPE聚合物优选为直链且不具有长链支化，聚亚芳基均聚物，无规共聚物或抗冲共聚物，以及任选的火焰阻燃添加剂。聚合物共混物特别适用于需要增加的抗撕裂性和拉伸强度的膜应用中，例如在屋顶膜，土工膜和池塘衬里中。

7. 发明申请

WO2003000790A1 METALLOCENE-PRODUCED VERY LOW DENSITY POLYETHYLENES OR LINEAR LOWDENSITY POLYETHYLENES AS IMPACT MODIFIERS 审中-公开
标题翻译：金属生产非常低密度聚乙烯或线性低密度聚乙烯作为冲击改性剂
公开(公告)号：WO2003000790A1
公开(公告)日：2003-01-03
申请号：PCT/US2002/018688
申请日：2002-06-11
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , DUNAWAY, David, B.
发明人： DUNAWAY, David, B.
IPC分类号： C08L23/08
CPC分类号： C08L23/0815 , B32B27/32 , C08L23/10 , C08L33/10 , C08L2314/06 , C08L2666/04 , C08L2666/06
摘要： In one embodiment, the present invention is directed to an article, such as a blow-molded bottle, formed from a polymer blend composition. In one aspect, the article is formed by blow-molding techniques. In one aspect, the article is a blow-molded container having a Bruceton Mean Drop Height of 3.8 feet or above. In another aspect, the article is a blow-molded container having a volume of 60 fluid ounces or greater. In general, the polymer blend compositiorl comprises polypropylene and an impact modifier of metallocene-produced very low density polyethylene or linear low density polyethylene. In one embodiment, the polypropylene polymer comprises a random copolymer. In one embodiment, the metallocene-catalyzed linear very low density polyethylene polymer has one or more of the following: (a) a density of less than 0.916 g/cm3, (b) a composition distribution breadth index of 50 to 85% by weight, (c ) a molecular weight distribution Mw/Mn of 2.0 to 3.0, (d) a molecular weight distribution Mz/Mw of less than 2.0, and (e) two peaks in a TREF measurement. In one embodiment, the polymer blend composition comprises 5% to 85% of the impact modifier and 95% to 15% of the polypropylene polymer, based on the total combined weight of the polypropylene polymer and the impact modifier. In another embodiment, the polymer blend composition comprises 5% to 35% of the impact modifier and 95% to 65% of the polypropylene polymer, based on the total combined weight of the polypropylene polymer and the impact modifier.
摘要翻译：在一个实施方案中，本发明涉及由聚合物共混组合物形成的制品，例如吹塑瓶。在一个方面，制品通过吹塑技术形成。在一个方面，制品是具有3.8英尺或以上的Bruceton Mean Drop Height的吹塑容器。另一方面，制品是具有60流体盎司或更大的体积的吹塑容器。通常，聚合物共混物组合物包括聚丙烯和茂金属生产的极低密度聚乙烯或线性低密度聚乙烯的抗冲改性剂。在一个实施方案中，聚丙烯聚合物包含无规共聚物。在一个实施方案中，茂金属催化的线性极低密度聚乙烯聚合物具有以下一种或多种：（a）小于0.916g / cm 3的密度，（b）组合物分布宽度指数为50至85重量％，（c）2.0〜3.0的分子量分布Mw / Mn，（d）小于2.0的分子量分布Mz / Mw，（e）TREF测定中的两个峰。在一个实施方案中，基于聚丙烯聚合物和抗冲改性剂的总组合重量，聚合物共混组合物包含5％至85％的抗冲改性剂和95％至15％的聚丙烯聚合物。在另一个实施方案中，基于聚丙烯聚合物和抗冲改性剂的总组合重量，聚合物共混物组合物包含5％至35％的抗冲改性剂和95％至65％的聚丙烯聚合物。

8. 发明申请

WO2004054714A1 MODIFIED METALLOALUMINIUMOPHOSPHATE MOLECULAR SIEVES, PREPARATION AND USE THEREOF IN METHANOL TO OLEFINS PROCESS 审中-公开
标题翻译：改性金属钼酸盐分子筛，在甲醇中制备和使用烯烃方法
公开(公告)号：WO2004054714A1
公开(公告)日：2004-07-01
申请号：PCT/US2003/009092
申请日：2003-03-24
申请人： EXXONMOBIL CHEMICAL PATENTS INC. A Corporation of the State of Delaware , MEES, Filip , VANSANT, Etienne , WANG, Kun , HALL, Richard, B. , JANSSEN, Marcel, J. , MARTENS, Luc, R., M. , VERBERCKMOES, An , CAO, Guang
发明人： MEES, Filip , VANSANT, Etienne , WANG, Kun , HALL, Richard, B. , JANSSEN, Marcel, J. , MARTENS, Luc, R., M. , VERBERCKMOES, An , CAO, Guang
IPC分类号： B01J37/02
CPC分类号： B01J37/0209 , B01J29/84 , B01J29/85 , B01J2229/14 , B01J2229/30 , C07C1/20 , C07C2531/14 , C10G3/49 , C10G3/62 , C10G2300/4081 , C10G2300/708 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The invention is directed to a method for modifying a microporous metalloaluminophosphate molecular sieve, the method comprising the steps of a) introducing a compound containing at least one M-X group within the cages of said microporous molecular sieve; and b) reacting said compound containing at least one M-X group with the acid groups located in the cages of the molecular sieve, wherein the compound containing at least one M-X group is selected from the group consisting of compounds of formula MX 3 , compounds of formulaM 2 X 6 , and mixtures thereof, M being a metal belonging to Group 13 of the Periodic Table, and X independently being a hydrogen or halogen atom. Preferably, X is a hydrogen atom. The present invention also relates to modified metalloaluminophosphate molecular sieves, preferably modified silicoaluminophosphate molecular sieves, as well as to the use of these modified molecular sieves in catalytic processes, such as processes for the conversion of oxygenated hydrocarbon feedstocks.
摘要翻译：本发明涉及一种改性微孔金属铝磷酸盐分子筛的方法，该方法包括以下步骤：a）将含有至少一个M-X基团的化合物引入所述微孔分子筛的笼中; 和b）使含有至少一个MX基团的化合物与位于分子筛的笼中的酸基反应，其中含有至少一个MX基团的化合物选自式MX3化合物，式M2X6化合物，和它们的混合物，M是属于周期表第13族的金属，X独立地是氢或卤素原子。优选地，X是氢原子。本发明还涉及改性的金属铝磷酸盐分子筛，优选改性的硅铝磷酸盐分子筛，以及这些改性分子筛在催化方法中的用途，例如转化含氧烃原料的方法。

9. 发明申请

WO2003084660A2 INTERIOR SURFACE MODIFICATIONS OF MOLECULAR SIEVES WITH ORGANOMETALLIC REAGENTS AND THE USE THEREOF FOR THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：分子筛与有机试剂的内部表面改性及其用于将氧化物转化成烯烃的用途
公开(公告)号：WO2003084660A2
公开(公告)日：2003-10-16
申请号：PCT/US2003/005991
申请日：2003-02-28
申请人： EXXONMOBIL CHEMICAL PATENTS INC , WANG, Kun , BARE, Richard, E. , LEVIN, Doron , VARTULI, James, C. , CAO, Guang , HALL, Richard, B.
发明人： WANG, Kun , BARE, Richard, E. , LEVIN, Doron , VARTULI, James, C. , CAO, Guang , HALL, Richard, B.
IPC分类号： B01J29/00
CPC分类号： C10G3/44 , B01J23/06 , B01J29/85 , B01J29/90 , B01J37/0201 , B01J38/12 , B01J2229/186 , B01J2229/34 , C01B37/08 , C01B39/026 , C07C1/20 , C07C2529/85 , C07C2531/12 , C10G3/49 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/04 , C07C11/06
摘要： A method for making an organometallic treated molecular sieve is described in which a molecular sieve having at least one hydroxyl group and at least [A10 2 ] and [P0 2 ] tetrahedral units and having an average pore dimension less than or equal to about 5A is contacted with a solution comprising an organometallic compound and a non-proton donating solvent. The resulting organometallic treated molecular sieve has enhanced ethylene and/or propylene selectivity when used in the conversion of organic oxygenates to olefins. The ethylene and/or propylene selectivity, as well as catalyst life, are further enhanced when the resulting organometallic treated molecular sieve is combined with an oxide of at least one metal selected from Groups 2, 3 and Group 4 of the Periodic Table.
摘要翻译：描述了一种制备有机金属处理分子筛的方法，其中具有至少一个羟基和至少[A102]和[P02]四面体单元并且具有小于或等于约5A的平均孔尺寸的分子筛与包含有机金属化合物和非质子供体溶剂的溶液。所得到的有机金属处理分子筛当用于有机含氧化合物转化为烯烃时具有增强的乙烯和/或丙烯选择性。当得到的有机金属处理分子筛与选自元素周期表第2,3族和第4族中的至少一种金属的氧化物结合时，乙烯和/或丙烯选择性以及催化剂寿命进一步提高。

10. 发明申请

WO2003048044A1 METHOD OF SYNTHESIZING MOLECULAR SIEVES 审中-公开
标题翻译：合成分子筛的方法
公开(公告)号：WO2003048044A1
公开(公告)日：2003-06-12
申请号：PCT/US2002/028788
申请日：2002-09-10
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： CAO, Guang , SHAH, Matu
IPC分类号： C01B37/08
CPC分类号： C10G3/49 , B01J29/06 , B01J29/83 , B01J29/85 , B01J37/0045 , C01B37/04 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2529/83 , C07C2529/85 , C10G2400/20 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The invention is directed to a method of synthesizing a molecular sieve. In particular, the invention is directed to a method for synthesizing a molecular sieve, especially a silicoaluminophosphate molecular sieve, in the presence of a templating agent and a polymeric base. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s ), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要翻译：本发明涉及合成分子筛的方法。特别地，本发明涉及在模板剂和聚合物基质的存在下合成分子筛，特别是硅铝磷酸盐分子筛的方法。本发明还涉及将分子筛配制成可用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的方法中的催化剂。

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