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    • 7. 发明申请
    • CONTINUOUS ADIABATIC INVERSE EMULSION POLYMERIZATION PROCESS
    • 连续自发反相乳液聚合方法
    • WO2017019471A1
    • 2017-02-02
    • PCT/US2016/043460
    • 2016-07-22
    • TECHNOLOGY INVESTMENT & DEVELOPMENT, LLC
    • KANE, JamesDURHAM, James, F.
    • B01F17/34C08F2/32B01F17/00
    • C08F2/32C08F2/01C08F6/20C08F220/56C08F220/34C08F2220/585C08F220/06
    • The present invention provides methods and systems for continuous polymerization of ethylenically unsaturated monomers in a water-in-oil inverse emulsion under adiabatic conditions without the need for external cooling during the polymerization. The method comprises neutralizing a monomer composition comprising at least one acidic vinyl monomer with a base in an aqueous medium comprising water and water ice to form an aqueous monomer solution therefrom; homogenizing and degassing to form an inverse monomer emulsion; initiating polymerization; passing the inverse emulsion through a tube reactor without cooling, and flash evaporating a portion of the water from inverse emulsion to cool and concentrate the resulting polymer-containing inverse emulsion. During neutralization, the aqueous medium comprises an amount of water ice sufficient to maintain a temperature of 30°C or less, and the polymerization is initiated by adding a free-radical polymerization initiator to the emulsion prior to passing the emulsion through the tube reactor.
    • 本发明提供了在绝热条件下在油包水反相乳液中连续聚合烯属不饱和单体的方法和系统,而不需要在聚合过程中进行外部冷却。 该方法包括在包含水和水冰的水性介质中中和包含至少一种酸性乙烯基单体的单体组合物与碱形成其中的单体水溶液; 匀化和脱气形成反相单体乳液; 引发聚合; 使反相乳液通过管式反应器而不冷却,并从反相乳液中闪蒸一部分水以冷却并浓缩得到的含聚合物的反相乳液。 在中和过程中,水介质包含一定量的足以保持30℃或更低温度的水冰,并且在将乳液通过管式反应器之前,通过向乳液中加入自由基聚合引发剂来开始聚合。