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    • 4. 发明申请
    • PHOTOACTIVE MATERIAL
    • WO2022129594A1
    • 2022-06-23
    • PCT/EP2021/086628
    • 2021-12-17
    • CAMBRIDGE DISPLAY TECHNOLOGY LTD.SUMITOMO CHEMICAL CO., LTD.
    • MACIEJCZYK, MichalBOURCET, Florence
    • H01L51/46C07D403/00C08G61/00C08G73/00C07D409/00
    • A material comprising an electron-accepting unit of formula (I). According to some embodiments, the present disclosure provides a material comprising an electron-accepting unit of formula (I) wherein Ar is a substituted or unsubstituted benzene or 6-membered heteroaromatic ring containing N and C ring atoms; Ar1 is a substituted or unsubstituted 5- or 6-membered heteroaromatic ring containing N and C ring atoms; Ar2 is a substituted or unsubstituted 5- or 6-membered heteroaromatic ring or is absent; Ar3 is a 5-membered ring or a substituted or unsubstituted 6-membered ring; Ar4 is a 5-membered ring or a substituted or unsubstituted 6-membered ring or is absent; Ar5 is a substituted or unsubstituted monocyclic or polycyclic group containing at least one aromatic or heteroaromatic ring; Ar6 is a substituted or unsubstituted monocyclic or polycyclic group containing at least one aromatic or heteroaromatic ring or is absent; and each X is independently a substituent bound to a carbon atom of Ar3 and, where present, Ar4 with the proviso that at least one X group is an electron-withdrawing group and wherein the material further comprises a conjugated electron-donating unit. The material may be a polymer comprising repeat units of formula (I). The material may be a non-polymeric compound. An organic photodetector may contain a bulk heterojunction layer containing an electron acceptor or an electron donor wherein at least one of the electron acceptor and electron donor contains a unit of formula (I).