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    • 2. 发明申请
    • PROCESS FOR IN SITU UPGRADING OF A HEAVY HYDROCARBON USING ASPHALTENE PRECIPITANT ADDITIVES
    • 使用ASPHALTENE PRIPIPTIANT添加剂重组重油的方法
    • WO2015065798A1
    • 2015-05-07
    • PCT/US2014/061922
    • 2014-10-23
    • CHEVRON U.S.A. INC.
    • OVALLES, CesarROGEL, Estrella
    • C09K8/594C10G1/04E21B43/16
    • E21B43/16C09K8/594C09K2208/10C10G73/38C10G2300/302C10G2300/4037E21B43/28
    • Disclosed is a process for in situ upgrading of a heavy hydrocarbon comprising the steps of: (a) positioning a well in a reservoir containing a heavy hydrocarbon having an initial API gravity of less than or equal to about 20, an n-heptane asphaltene content as measured by the ASTM D-6560 of at least about 1 wt.%, and a viscosity at 35°C greater than about 350 centistokes (cSt); (b) injecting one or more hydrocarbon solvents and one or more asphaltene precipitant additives into the well in any order at a ratio by volume of the solvent to the heavy hydrocarbon of at least from about 0.1:1 to about 20:1 under reservoir conditions so as to provide an upgraded hydrocarbon in the reservoir, wherein the upgraded hydrocarbon has an improved API gravity greater than the initial API gravity, a reduction in the asphaltene content, and a lower viscosity; and (c) producing the upgraded hydrocarbon from the well. The process of the present invention can be also carried out at higher temperatures such as by injecting steam with the one or more hydrocarbon solvents and the one or more asphaltene precipitant additives into the well in any order.
    • 公开了一种重质烃的原位升级方法,包括以下步骤:(a)将井定位在含有初始API重量小于或等于约20的重烃的储层中,正庚烷沥青质含量 通过ASTM D-6560测量为至少约1重量%,并且在35℃下的粘度大于约350厘沲(cSt); (b)在储存条件下,溶剂与重质烃的体积比至少约0.1:1至约20:1的任何顺序将一种或多种烃溶剂和一种或多种沥青质沉淀剂添加剂注入孔中 以便在储层中提供升级的烃,其中改质的烃具有比初始API重力更大的API重力,沥青质含量的降低和较低的粘度; 和(c)从井中生产升级的烃。 本发明的方法也可以在更高的温度下进行,例如通过以一种或多种烃溶剂和一种或多种沥青质沉淀剂添加剂将蒸汽以任何顺序注入井中。
    • 6. 发明申请
    • PROCESS, METHOD, AND SYSTEM FOR REMOVING MERCURY FROM PIPELINES
    • 从管道中去除汞的方法,方法和系统
    • WO2016154394A1
    • 2016-09-29
    • PCT/US2016/023931
    • 2016-03-24
    • CHEVRON U.S.A. INC.
    • O'REAR, Dennis JohnGRICE, Kevin J.PRADHAN, VijayDASSEY, Adam J.HAKAM, AlyTIWARY, Asheesh
    • B08B9/027B08B9/043B08B9/055
    • B08B9/0553B08B7/0064B08B9/043
    • Hydroprocessing facilities may operate for extended periods of time before detection of mercury in the inlet facilities, as mercury adsorbs onto the metallic pipelines (100) used to transport the hydrocarbon fluids, e.g., gas, produced waters, from the wells to processing facilities ("flowlines"). Once the pipelines (100) become "saturated" with mercury, mercury will break through and be detected at the inlet facilities. A mercury management /control scheme is disclosed wherein either a chemical or a thermal treatment step is used to clean the pipeline, managing mercury accumulation in the pipeline for a reduced mercury concentration in the fluid exiting the flowlines. The heating during the thermal treatment step is done by using any of laser treatment, a combustor, or an induction coil. During the chemical treatment step an aqueous sulfidic solution comprising at least 0.1 wt. % of a sulfide, a polysulfide or a combination thereof is used.
    • 在检测入口设施中的汞之前,加氢处理设施可能会长时间运行,因为汞吸附到用于将烃流体(例如,天然气,产水)从井运输到处理设施的金属管道(100) 输油管线“)。 一旦管道(100)用汞“饱和”,汞将突破,并在入口设施被检测到。 公开了一种汞管理/控制方案,其中使用化学或热处理步骤来清洁管道,管理管道中的汞积聚以减少离开流线的流体中的汞浓度。 在热处理步骤期间的加热通过使用激光处理,燃烧器或感应线圈中的任何一个来完成。 在化学处理步骤期间,将含有至少0.1wt。 使用硫化物,多硫化物或其组合的%。
    • 7. 发明申请
    • PROCESS, METHOD AND SYSTEM FOR REMOVING HEAVY METALS FROM FLUIDS
    • 从流体中除去重金属的方法,方法和系统
    • WO2016069450A2
    • 2016-05-06
    • PCT/US2015/057321
    • 2015-10-26
    • CHEVRON U.S.A. INC.
    • O'REAR, Dennis JohnCOOPER, Russell Evan
    • C10G31/06
    • C10G31/06C10G7/00
    • Particulate mercury, in the form of metacinnabar, is removed from crude oil by thermally treating the crude oil at temperatures in a range from 150°C to 350°C and at a pressure sufficient to limit the amount of crude vaporizing to no more than 10 wt. %. In the thermal treatment, the particulate mercury is converted into elemental mercury, which can be removed by directly adsorption from the crude onto a support. In one embodiment, the elemental mercury can be removed by stripping the crude with a gas, and then adsorbing the mercury onto a support. The crude oil can be optionally treated prior to stabilization and contains 0.1 wt. % or more of C 4 -hydrocarbons. Following the thermal treatment, the treated crude is cooled and the pressure is reduced. The C 4 - hydrocarbons then vaporize from the crude and carry the elemental mercury with them. The elemental mercury in this hydrocarbon gas stream may then be removed by a solid adsorbent.
    • 通过在150℃至350℃的温度下对原油进行热处理并在足以将原油汽化量限制在不超过10的压力下从原油中除去颗粒状的金属微粒形式的汞 重量。 %。 在热处理中,颗粒状汞转化为元素汞,可通过将粗品直接吸附到载体上来除去。 在一个实施方案中,可以通过用气体汽提粗品,然后将汞吸附到载体上来除去元素汞。 原油可以在稳定化之前任选地处理,并且含有0.1wt。 %以上的C4烃。 热处理后,将处理后的粗品冷却并降低压力。 然后,C4-烃从原油中蒸发并携带元素汞。 然后可以通过固体吸附剂除去该烃气流中的元素汞。
    • 8. 发明申请
    • STABLE SUPPORT FOR FISCHER-TROPSCH CATALYST
    • 稳定支持FISCHER-TROPSCH催化剂
    • WO2016039896A1
    • 2016-03-17
    • PCT/US2015/043924
    • 2015-08-06
    • CHEVRON U.S.A. INC.
    • JOTHIMURUGESAN, KandaswamyLACHEEN, Howard Steven
    • B01J37/02C07C1/04B01J37/18B01J35/10B01J35/00B01J23/84B01J23/847B01J23/89
    • B01J37/0205B01J23/8472B01J23/898B01J35/002B01J35/1038B01J35/1042B01J37/18C10G2/33
    • A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes contacting a gamma alumina catalyst support material with a first solution containing a vanadium compound, to obtain a modified catalyst support material. The first solution can contain both a vanadium compound and a phosphorus compound. The modified catalyst support material is calcined at a temperature of at least 500C. The calcined modified catalyst support has a pore volume of at least 0.35 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support loses no more than 15% of its pore volume when exposed to water vapor. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component to obtain a catalyst precursor. The first solution can contain an organic compound such as glutaric acid. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability as measured by losing no more than 22% of its pore volume when exposed to water vapor.
    • 已经开发了制备费 - 托催化剂前体和由前体制备的费 - 托催化剂的方法。 该方法包括使γ氧化铝催化剂载体材料与含有钒化合物的第一溶液接触,以获得改性的催化剂载体材料。 第一种溶液可以含有钒化合物和磷化合物。 改性的催化剂载体材料在至少500℃的温度下煅烧。 经煅烧的改性催化剂载体的孔体积至少为0.35cc / g。 改性的催化剂载体在酸溶液中比相当的未改性的催化剂载体更难溶解。 当暴露于水蒸气时,改性催化剂载体的孔隙体积不超过15%。 将改性的催化剂载体与包含活性钴催化剂组分的前体化合物的第二溶液接触以获得催化剂前体。 第一溶液可以含有有机化合物如戊二酸。 催化剂前体被还原以活化催化剂前体以获得费 - 托催化剂。 催化剂具有增强的水热稳定性,当暴露于水蒸汽时,其通过损失不超过其孔体积的22%来测量。