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1. 发明申请

WO2008059051A1 SYNTHESIS OF IMIDE COMPOUNDS 审中-公开
标题翻译：合成化合物
公开(公告)号：WO2008059051A1
公开(公告)日：2008-05-22
申请号：PCT/EP2007/062455
申请日：2007-11-16
申请人： PPG INDUSTRIES, INC. , IMPERIAL INNOVATIONS LIMITED , CAILLE, Jean-Claude , HII, King Kuok Mimi
发明人： CAILLE, Jean-Claude , HII, King Kuok Mimi
IPC分类号： C07C269/06 , C07C271/64 , C07D215/42
CPC分类号： C07C269/06 , C07C271/64
摘要： The invention relates to a process for the production of an imide (1) (2) (3) via the enantioselective addition of an amine (2) to an alkene (3) wherein Y is OR, wherein R is alkyl or Bn, said process comprising: incubating Pd(OTf) 2 with a phosphine ligand comprising one or more chiral biaryl groups to form an asymmetrical catalyst in situ ; and adding the amine (2) and the alkene (3) to the in situ generated catalyst to form an imide (1). The invention provides better enantioselectivity with good yield
摘要翻译：本发明涉及一种通过向其中Y为OR的烯烃（3）对映选择性加成胺（2）制备酰亚胺（1）（2）（3））的方法，其中R为烷基或Bn，所述方法包括：将Pd（OTf）2 N 2与包含一个或多个手性联芳基基团的膦配位体一起孵育以在原位形成不对称催化剂; 并将胺（2）和烯烃（3）加入到原位产生的催化剂中以形成酰亚胺（1）。本发明提供更好的对映选择性，具有良好的收率

2. 发明申请

WO1998032037A1 NOVEL PHOTOCHROMIC HETEROCYCLIC FUSED INDENONAPHTHOPYRANS 审中-公开
标题翻译：新型光电杂交熔融印花
公开(公告)号：WO1998032037A1
公开(公告)日：1998-07-23
申请号：PCT/US1997015433
申请日：1997-09-03
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , KUMAR, Anil
IPC分类号： G02B05/23
CPC分类号： C07D493/04 , C09K9/02 , G02B5/23
摘要： Described are novel photochromic heterocyclic fused indenonaphthopyran compounds having a substituted or unsubstituted heterocyclic ring fused to the g, h, i, n, or p side of the indenonaphthopyran. These compounds may be represented by either of graphic formulae (I), (I'). Also described are polymeric organic host materials that contain or that are coated with such compounds.
摘要翻译：描述了具有与茚并萘并吡喃的g，h，i，n或p侧稠合的取代或未取代杂环的新型光致变色杂环稠合茚并萘并吡喃化合物。这些化合物可以由图形式（I），（I'）中的任何一种表示。还描述了含有或涂覆有这些化合物的聚合物有机主体材料。

3. 发明申请

WO1998027009A1 AMORPHOUS PRECIPITATED SILICA CHARACTERIZED BY HIGH DISPERSION IN CURED ORGANIC RUBBER COMPOSITIONS 审中-公开
标题翻译：由固化有机橡胶组合物中的高分散度表征的非晶态二氧化硅
公开(公告)号：WO1998027009A1
公开(公告)日：1998-06-25
申请号：PCT/US1997021175
申请日：1997-11-13
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , SWIFT, Harold, E. , KRIVAK, Thomas, G. , JONES, Laurence, E.
IPC分类号： C01B33/12
CPC分类号： C01B33/193 , C01P2002/02 , C01P2004/51 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C08K3/36 , C08L21/00
摘要： Amorphous precipitated silica is characterized by a standard white area of less than 0.8 percent. The low standard white area is a characteristic of the silica which is indicative of high (i.e., very effective) dispersion when the silica is incorporated into organic rubber compositions which are cured. Cured organic rubber compositions comprising amorphous precipitated silica exhibit low white areas which indicate high dispersion of the silica in the compositions.
摘要翻译：无定形沉淀二氧化硅的特征在于标准白色面积小于0.8％。低标准白色区域是二氧化硅的特征，当将二氧化硅掺入固化的有机橡胶组合物中时，其表现出高的（即非常有效的）分散体。包含无定形沉淀二氧化硅的固化有机橡胶组合物表现出低白色区域，这表明二氧化硅在组合物中的高分散性。

4. 发明申请

WO1998025995A1 PROCESS FOR IMPROVING ADHESION OF ELECTROCONDUCTIVE METAL OXIDE LAYERS TO POLYMERIC SUBSTRATES AND ARTICLES PRODUCED THEREBY 审中-公开
标题翻译：将电极性金属氧化物层粘附到聚合物基体上的方法及其生产的制品
公开(公告)号：WO1998025995A1
公开(公告)日：1998-06-18
申请号：PCT/US1997021549
申请日：1997-11-21
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , KNOX, Carol, L.
IPC分类号： C08J07/04
CPC分类号： C08J7/045
摘要： A process for forming an adherent electroconductive metal oxide surface on an organic polymeric substrate and the improved resultant article produced by the process are disclosed. The method includes the steps of coating the polymeric substrate with a composition containing at least one polymer-forming organosilane, which when cured forms a non-tintable coating, and depositing an electroconductive metal oxide on the cured silane coating to form an adherent layer, e.g., a film or coating, thereon. Also described are electrooptical articles such as electrochromic articles, which utilize such articles.
摘要翻译：公开了一种用于在有机聚合物基材上形成粘附的导电金属氧化物表面的方法和通过该方法生产的改进的所得物品。该方法包括以下步骤：用包含至少一种形成聚合物的有机硅烷的组合物涂覆聚合物基材，当其固化时形成不可着色的涂层，并且在固化的硅烷涂层上沉积导电金属氧化物以形成粘附层，例如，薄膜或涂层。还描述了使用这种制品的电光产品如电致变色制品。

5. 发明申请

WO1998024835A1 MULTILAYER PACKAGING MATERIAL FOR OXYGEN SENSITIVE FOOD AND BEVERAGES 审中-公开
标题翻译：用于氧气敏感食品和饮料的多层包装材料
公开(公告)号：WO1998024835A1
公开(公告)日：1998-06-11
申请号：PCT/US1997014214
申请日：1997-08-13
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , CARLBLOM, Leland, H. , SEINER, Jerome, A. , NIEDERST, Ken, W.
IPC分类号： C08J07/04
CPC分类号： C08J7/047 , C08G59/50 , C08J2367/02 , C08J2463/00 , Y10T428/1393 , Y10T428/31511 , Y10T428/31515 , Y10T428/31786
摘要： Disclosed is a multilayer packaging material which is suitable for use as a container for malt beverages and which is tinted so as to block at least 90 % of light with wavelengths of electromagnetic radiation ranging from 300 nm to 500 nm. The tinted multilayer packaging materials of the present invention includes: (a) at least one layer of a carbon dioxide (CO2)-permeable polymeric packaging material, and (b) at least one layer of a CO2-treated gas barrier coating, which has an oxygen permeability constant not more than 0.05 cubic centimeter-mil/100 square inches/atmosphere/day. The CO2-permeable packaging material can be any polymeric material through which CO2 can pass and which can be used as a packaging material for food or beverages. The gas barrier coating has an oxygen permeability constant, before CO2 treatment, of less than 0.3. This gas barrier coating includes the reaction product of a polyamine (A) and a polyepoxide (B). The polyamine (A) can be an initial polyamine or un ungelled polyamine adduct having active amine hydrogens. Polyepoxide (B) can be a polyepoxide having a plurality of glycidyl groups linked to an aromatic member.
摘要翻译：公开了一种多层包装材料，其适用于麦芽饮料的容器，其被着色以阻挡至少90％的具有300nm至500nm的电磁辐射波长的光。本发明的有色多层包装材料包括：（a）至少一层二氧化碳（CO 2） - 可渗透聚合物包装材料，和（b）至少一层经CO 2处理的气体阻隔涂层，其具有氧气渗透常数不大于0.05立方厘米/ 100平方英寸/大气/天。二氧化碳可透过的包装材料可以是CO 2可以通过的任何聚合物材料，其可用作食品或饮料的包装材料。阻气涂层在CO2处理之前的氧气渗透率常数小于0.3。该阻气涂层包括多胺（A）和聚环氧化物（B）的反应产物。多胺（A）可以是具有活性胺氢的初始多胺或未未凝胶化的多胺加合物。聚环氧化物（B）可以是具有连接到芳族成员的多个缩水甘油基的聚环氧化物。

6. 发明申请

WO1998023683A1 RADIATION CURABLE COMPOSITIONS BASED ON UNSATURATED POLYESTER, VINYL ETHER AND URETHANE VINYL ETHER COMPOUNDS 审中-公开
标题翻译：基于不饱和聚酯，乙烯基醚和脲基乙烯醚化合物的辐射可固化组合物
公开(公告)号：WO1998023683A1
公开(公告)日：1998-06-04
申请号：PCT/US1997021542
申请日：1997-11-21
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , FRIEDLANDER, Charles, B. , AMBROSE, Ronald, R. , DIEHL, David, A. , WEISSBERG, Alan, B. , NOVAK, Carolyn, A.
IPC分类号： C08L67/06
CPC分类号： C08L67/06 , C08F283/01 , C08L29/00 , C08L2666/04
摘要： Disclosed is a radiation curable composition which includes: (a) an unsaturated polyester compound, (b) a polymerizable vinyl ether compound, and (c) a polymerizable urethane vinyl ether compound. The unsaturated polyester compound is characterized as having more than 2.0 unsaturated ester groups per molecule and being the reaction product of unsaturated carboxylic acids and/or blends of unsaturated and saturated carboxylic acids with polyhydric alcohols and/or blends of polyhydric and monohydric alcohols. The polymerizable vinyl ether compound is characterized as including at least one of the following: (a) a compound having an average of greater than 1.0 reactive vinyl ether groups per molecule, and (b) a vinyl ether-containing group bonded to the unsaturated polyester compound such that there is an average of at least 1.0 reactive vinyl ether group per molecule. The polymerizable urethane vinyl ether compound is characterized as having a saturated urethane-containing backbone with vinyl ether groups. The polymerizable vinyl ether and urethane vinyl ether compounds are able to react, upon exposure to radiation, with the ethylenic unsaturation of the unsaturated polyester compound.
摘要翻译：公开了一种可辐射固化组合物，其包括：（a）不饱和聚酯化合物，（b）可聚合乙烯基醚化合物和（c）可聚合的氨基甲酸乙烯酯化合物。不饱和聚酯化合物的特征在于每分子具有多于2.0个不饱和酯基，并且是不饱和羧酸和/或不饱和羧酸与多元醇和/或多元醇和/或多元醇的共混物的混合物的反应产物。可聚合乙烯基醚化合物的特征在于包括以下至少一种：（a）每分子平均具有大于1.0个反应性乙烯基醚基团的化合物，和（b）与不饱和聚酯键合的含乙烯基醚基团化合物，使得每个分子平均具有至少1.0个反应性乙烯基醚基团。聚合性聚氨酯乙烯基醚化合物的特征在于具有含有乙烯基醚基团的饱和的含有氨基甲酸酯的主链。可聚合乙烯基醚和聚氨酯乙烯基醚化合物在暴露于辐射时能够与不饱和聚酯化合物的烯属不饱和键反应。

7. 发明申请

WO1998012272A1 COATING AGENT, PROCESS FOR PRODUCING THE SAME AND ITS USE, IN PARTICULAR FOR LACQUERING THE OUTSIDE OF PACKAGES 审中-公开
标题翻译：包衣剂生产和涂料的通过方法，尤其是在户外绘画EMBALLAGEN
公开(公告)号：WO1998012272A1
公开(公告)日：1998-03-26
申请号：PCT/EP1997004623
申请日：1997-08-25
申请人： PPG INDUSTRIES, INC. , KÖSTER, Bernhard , KEWELOH, Ludger , KIPP, Jörg , VOGDANIS, Lazaros , CHMIELEWSKI, Dietmar
发明人： PPG INDUSTRIES, INC.
IPC分类号： C09D167/00
CPC分类号： C09D167/00 , Y10T428/31529 , C08L2666/14
摘要： A coating agent which contains one or several hydroxyl group-containing, optionally modified polyesters and one or several cross-linking agents which react with the hydroxyl groups is characterised in that the coating agent contains as binder a mixture of A1) 35 to 95 wt % one or several hydroxyl groups-containing polyesters (A1) with an OH number from 15 to 210 mgKOH/g, an acid number from 10 to 120 mgKOH/g and a number average molecular weight from 500 to 6000 g/mol; A2) 2 to 50 wt % one or several water-dilutable, modified epoxy resin esters (A2); and A3) 0 to 20 wt % one or several water-dilutable, hydroxyl groups-containing, epoxy resin-modified alkyd resins (A3). The sum of the weight percentages of components (A1) to (A3) equals 100 wt % and the weight percentages are given in relation to the solids in the binders (A1) to (A3).
摘要翻译：本发明是一种涂布剂，含有一种或多种改性或未改性的聚酯和一种或朝向羟基的交联剂反应性更强的含羟基的，其特征在于，所述涂层剂作为粘合剂A1的混合物）35％至95％（重量）的一种或多种的含羟基的聚酯具有15-210毫克KOH /克，10至120毫克KOH /克和500至6000g / mol的数均分子量的酸值的OH值（A1）; 包含A2）2〜50重量％的一种或多种水，改性环氧树脂酯（A2）和A3）0至20重量％的一种或多种水可稀释的，含羟基的，epoxidharzmodifizierter醇酸树脂（A3），其中所述比例（重量）的总和组分（A1）至（A3）是在每种情况下100％（重量），并且其中在所述粘合剂（A1）至（A3）的固体含量每种情况下，重量百分比。

8. 发明申请

WO1998010024A1 ELECTRODEPOSITABLE COATING COMPOSITION CONTAINING BISMUTH AND AMINO ACID MATERIALS AND ELECTRODEPOSITION METHOD 审中-公开
标题翻译：含有双胺和氨基酸材料的电沉积涂料组合物和电沉积方法
公开(公告)号：WO1998010024A1
公开(公告)日：1998-03-12
申请号：PCT/US1997015327
申请日：1997-09-02
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , KOLLAH, Raphael, O. , SCOTT, Matthew, S. , McCOLLUM, Gregory, J. , BETHOSKI, Joseph, A.
IPC分类号： C09D05/44
CPC分类号： C09D5/4492 , C08G18/161 , C08G18/643
摘要： An electrodepositable coating composition is provided comprising (a) an active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (b) a curing agent for transurethanation, transamidation or transesterification curing like at least a partially capped polyisocyanate curing agent; and (c) a catalytic mixture of bismuth and an amino acid or amino acid precursor. Optionally, an auxiliary acid may be present to increase the effectiveness of the amino acid in the mixture with bismuth.
摘要翻译：提供了一种可电沉积的涂料组合物，其包含（a）可电沉积在阴极上的含活性氢的阳离子盐基树脂; （b）如至少部分封端的多异氰酸酯固化剂的经氨基甲酸酯化，酰胺转移或酯交换固化的固化剂; 和（c）铋和氨基酸或氨基酸前体的催化混合物。任选地，可以存在辅助酸以增加混合物中氨基酸与铋的有效性。

9. 发明申请

WO1998007770A1 CATIONIC ELECTROCOATING COMPOSITIONS, METHOD OF MAKING, AND USE 审中-公开
标题翻译：阳离子电动组合物，制备方法和使用
公开(公告)号：WO1998007770A1
公开(公告)日：1998-02-26
申请号：PCT/US1997013363
申请日：1997-07-29
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , KAUFMAN, Marvin, L. , O'NEILL, Patrick , KARABIN, Richard, F. , McCOLLUM, Gregory, J.
IPC分类号： C08G18/64
CPC分类号： C08G18/643 , C09D5/4434 , Y10T428/31511 , Y10T428/31551
摘要： An electrodepositable composition that has: (A) an active hydrogen-containing cationic resin, electrodepositable on a cathode, having: (1) a polyepoxide; (2) an oxygen-substituted diamine compound having formula (I) where n is an integer from 2 to 4; and where R or R are the same or different and either one or both contain at least one oxygen and are alkyl, cycloalkyl, substituted alkyl, or substituted cycloalkyl having from 1 to 6 carbon atoms, or R and R are alkanol groups having from 2 to 6 carbon atoms, or R , R , and the N atom form a cyclic group which is substituted or unsubstituted such as morpholine and 1-(3-aminopropyl)imidazole; and (B) at least partially blocked isocyanate or polyisocyanate curing agent. The diamine compound of formula (I) can be used alone or in conjunction with one or more secondary amines, nonhydroxy group containing amines and/or amines with ring structures. Optionally, the polyepoxide can be chain extended with active hydrogen-containing compounds other than polyoxyalkylene polyamines. Also provided is a method of producing an active hydrogen-containing cationic resin composition, electrodepositable on a cathode, comprised of: (a) mixing together in a suitable reaction vessel a polyepoxide, or the precursors of the polyepoxide, a polycarboxylic acid, a blocked isocyanate curing agent; (b) adding to the mixture of (a) a base catalyst and the diamine compound of formula (I); (c) polymerizing the mixture of (b) to form a resinous composition; and (d) neutralizing the resinous composition of (c) by adding the resinous composition to a dilute mixture of acid and water to form an aqueous dispersed electrodepositable cationic resin composition.
摘要翻译：一种电沉积组合物，其具有：（A）可阴离子电解的活性含氢阳离子树脂，其具有：（1）聚环氧化物; （2）具有式（I）的氧取代的二胺化合物，其中n是2至4的整数; 并且其中R 1或R 2相同或不同，并且一个或两个都含有至少一个氧，并且是具有1至6个碳原子的烷基，环烷基，取代的烷基或取代的环烷基或R 1 且R 2为具有2至6个碳原子的链烷醇基，或R 1，R 2，并且N原子形成取代或未取代的环状基团，例如吗啉和1-（3- 丙基）咪唑; 和（B）至少部分封端的异氰酸酯或多异氰酸酯固化剂。式（I）的二胺化合物可以单独使用或与一种或多种仲胺，含羟基的胺和/或具有环结构的胺结合使用。任选地，聚环氧化物可以用除聚氧化烯多胺以外的活性含氢化合物链延伸。还提供了一种生产可阴离子电沉积的含活性氢的阳离子树脂组合物的方法，其包括：（a）在合适的反应容器中将聚环氧化物或多环氧化物的前体，多元羧酸，封端异氰酸酯固化剂; （b）向（a）碱催化剂和式（I）的二胺化合物的混合物中加入; （c）使（b）的混合物聚合以形成树脂组合物; 和（d）通过将树脂组合物加入酸和水的稀混合物中和（c）的树脂组合物，形成水分散的可电沉积阳离子树脂组合物。

10. 发明申请

WO1997047701A1 COATING COMPOSITION BASED ON POLYGLYCIDYL RESIN AND POLYACID CURING AGENT 审中-公开
标题翻译：基于聚硅氧烷树脂和聚氨酯固化剂的涂料组合物
公开(公告)号：WO1997047701A1
公开(公告)日：1997-12-18
申请号：PCT/US1997009285
申请日：1997-05-30
申请人： PPG INDUSTRIES, INC.
发明人： PPG INDUSTRIES, INC. , WOZNIAK, Mark, A. , SINGER, Debra, L. , KESICKI, Stephen, A. , SIMPSON, Dennis, A. , OLSON, Kurt, G.
IPC分类号： C09D133/14
CPC分类号： C09D151/003 , C08F265/04 , C08L33/068 , C08L2205/02 , C09D133/068 , C08L2666/04 , C08L2666/28
摘要： A curable coating composition made from a polyepoxide and a polyacid where the polyepoxide is at least one blend of at least two epoxy-containing acrylic copolymers, each containing (a) an ethylenically unsaturated monomer having at least one epoxy group and (b) a polymerizable ethylenically unsaturated monomer which is free of epoxy groups. The two epoxy-containing acrylic copolymers can be polymerized separately and blended together or preferably the two epoxy-containing acrylic copolymers are polymerized in the same reaction vessel using a successive step polymerization process. The curable coating composition is useful as an automotive topcoat in a composite color-plus-clear coating and provides for improved intercoat adhesion. A method of making the polyepoxide where the at least two epoxy-containing copolymers are polymerized in the same reaction vessel using a successive step polymerization.
摘要翻译：由聚环氧化物和多元酸制成的可固化涂料组合物，其中聚环氧化物是至少两种含环氧基的丙烯酸共聚物的共混物，每一种含有（a）具有至少一个环氧基的烯键式不饱和单体和（b）可聚合的不含环氧基的烯属不饱和单体。两种含环氧基的丙烯酸共聚物可以单独聚合并混合在一起，或者优选使用连续步骤聚合方法将两个含环氧基的丙烯酸类共聚物在相同的反应容器中聚合。可固化涂料组合物可用作复合颜色 - 透明涂料中的汽车顶涂层，并提供改善的涂层间粘附性。一种制备聚环氧化物的方法，其中至少两种含环氧基的共聚物在相同的反应容器中使用连续步骤聚合聚合。

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