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1. 发明申请

WO1998028348A1 PRODUCTION OF POLYETHYLENE HAVING A BIMODAL MOLECULAR WEIGHT DISTRIBUTION 审中-公开
标题翻译：生产具有双模分子量分布的聚乙烯
公开(公告)号：WO1998028348A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007178
申请日：1997-12-19
申请人： FINA RESEARCH S.A. , DEBRAS, Guy , BODART, Philippe
发明人： FINA RESEARCH S.A.
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F210/16 , Y02P20/52 , C08F4/69 , C08F4/025 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/04 , C08F2500/05
摘要： A process for producing high density polyethylene having a bimodal molecular weight distribution, the process comprising pre-contacting a chromium-based catalyst with an alkyl metal oxane, the chromium-based catalyst comprising chromium oxide on a silica-containing support, to form a catalyst system wherein the atomic ratio of the metal of the oxane to the chromium is less than 1, and polymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms in the presence of the catalyst system. A catalyst system for polymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms to produce high density polyethylene, the catalyst system comprising in combination a chromium-based catalyst comprising chromium oxide on a silica-containing support and an alkyl metal oxane with which the chromium-based catalyst has been precontacted whereby the atomic ratio of the metal of the oxane to the chromium is less than 1. A process for producing high density polyethylene having a bimodal molecular weight distribution, the process comprising polymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms in the presence of a catalyst system comprising a chromium-based catalyst, comprising chromium oxide on a silica-containing support, and an alkyl metal oxane in an amount of around 0.45 wt.% based on the weight of the chromium-based catalyst.
摘要翻译：一种生产具有双峰分子量分布的高密度聚乙烯的方法，所述方法包括使铬基催化剂与烷基金属氧化物预接触，所述铬基催化剂在含二氧化硅的载体上包含氧化铬，以形成催化剂系统，其中氧化物与铬的金属的原子比小于1，并且在催化剂体系的存在下聚合乙烯或共聚乙烯和包含3至10个碳原子的α-烯烃共聚单体。一种用于聚合乙烯或共聚乙烯和含有3-10个碳原子的α-烯烃共聚单体以生产高密度聚乙烯的催化剂体系，所述催化剂体系包含在含二氧化硅的载体上包含氧化铬的铬基催化剂和烷基金属恶烷，其中铬基催化剂已经被预接触，由此氧化物与铬的金属的原子比小于1.一种制备具有双峰分子量分布的高密度聚乙烯的方法，该方法包括聚合乙烯或共聚乙烯和含有3至10个碳原子的α-烯烃共聚单体，催化剂体系包含铬基催化剂，其包含在含二氧化硅的载体上的氧化铬和一定量的烷基金属氧化物 0.45重量％，基于铬基催化剂的重量。

2. 发明申请

WO1996035729A1 PROCESS FOR PREPARING AND USING A SUPPORTED METALLOCENE-ALUMOXANE CATALYST 审中-公开
标题翻译：制备和使用支持的金属 - 铝 - 氧化物催化剂的方法
公开(公告)号：WO1996035729A1
公开(公告)日：1996-11-14
申请号：PCT/EP1996001941
申请日：1996-05-09
申请人： FINA RESEARCH S.A. , RAZAVI, Abbas , DEBRAS, Guy
发明人： FINA RESEARCH S.A.
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , C08F210/16 , C08F2500/12 , C08F2500/18 , C08F210/14
摘要： A process for the preparation of supported metallocene-alumonaxe catalysts comprising the steps of: a) reacting a metallocene with an alumoxane at a temperature comprised between 15 and 50 DEG C, b) recovering a mixture comprising an alkylmetallocenium cation and an anionic alumoxane oligomer, c) reacting said mixture with a support, and d) recovering a supported metallocene-alumoxane catalyst as a dry solid, the reaction with the support being carried out at a temperature comprised between 85 DEG C and 110 DEG C, preferably between 90 and 130 DEG C, and their use for the polymerization or copolymerization of olefins.
摘要翻译：一种制备负载型茂金属 - 铝氧烷催化剂的方法，包括以下步骤：a）在15-50℃的温度下使金属茂与铝氧烷反应，b）回收包含烷基金属茂阳离子和阴离子铝氧烷低聚物的混合物， c）使所述混合物与载体反应，和d）回收作为干固体的负载型茂金属 - 铝氧烷催化剂，与载体的反应在85℃至110℃之间，优选90至130℃的温度下进行 ℃，以及它们用于烯烃聚合或共聚的用途。

3. 发明申请

WO1995014577A1 PROCESS FOR PRODUCING COLOUR CARDS 审中-公开
标题翻译：生产彩色卡片的方法
公开(公告)号：WO1995014577A1
公开(公告)日：1995-06-01
申请号：PCT/BE1994000089
申请日：1994-11-22
申请人： FINA RESEARCH S.A. , AKKERMAN, Matthias, Anthonie, Johannes , MULDER, Gerhardus, Johannis
发明人： FINA RESEARCH S.A.
IPC分类号： B41M03/00
CPC分类号： B41F23/044 , B41F23/0413 , B41M3/005 , F26B3/30
摘要： Wet colour cards prepared with water-based emulsion paints applied in layers of at least 75 g/m are dried using infra-red dryers irradiating the uncoated side of the cardboard or paper cards.
摘要翻译：使用以至少75g / m 2的层施加的水性乳液漆制备的湿色卡使用照射纸板或纸卡的未涂覆侧的红外干燥器进行干燥。

4. 发明申请

WO1995011930A1 METHOD FOR PRODUCING POLYETHYLENE HAVING A BROAD MOLECULAR WEIGHT DISTRIBUTION 审中-公开
标题翻译：用于生产具有宽分子量分布的聚乙烯的方法
公开(公告)号：WO1995011930A1
公开(公告)日：1995-05-04
申请号：PCT/BE1994000073
申请日：1994-10-25
申请人： FINA RESEARCH S.A.
发明人： FINA RESEARCH S.A. , DEBRAS, Guy , VANDAELE, Hugo
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F210/16 , C08F2/001 , C08F2/14 , C08F2500/04
摘要： A method for copolymerising ethylene in two liquid-phase loop reactors arranged in series wherein the average molecular weight is controlled, the comonomer is fed into the first reactor and the high and low molecular weight polymers are produced in the first and second reactors respectively. The method is improved in that one or more decanting legs of the first reactor are used for the transfer.
摘要翻译：一种串联布置的两个液相环管反应器中的乙烯共聚方法，其中平均分子量被控制，共聚单体进料到第一反应器中，高分子量和低分子量聚合物分别在第一和第二反应器中产生。改进方法是使用第一反应器的一个或多个倾析腿用于转移。

5. 发明申请

WO1991006582A1 SYNDIOTACTIC HOMOPOLYMERS OF OLEFINS 审中-公开
标题翻译： OLEFINS的合成共聚物
公开(公告)号：WO1991006582A1
公开(公告)日：1991-05-16
申请号：PCT/BE1990000062
申请日：1990-10-30
申请人： FINA RESEARCH S.A.
发明人： FINA RESEARCH S.A. , HASPESLAGH, Luc , FOLIE, Pascal
IPC分类号： C08F110/04
CPC分类号： C08F110/04 , C08F110/14 , C08F2500/02 , C08F2500/03 , C08F2500/16
摘要： Homopolymers of olefins having from 4 to 10 carbon atoms in which the microstructure of the polymer chain consists of blocks of repeating racemic dyads predominantly connected by units consisting of a meso triads. Also disclosed is a process for preparing said homopolymers by metallocene catalysis using an asymmetric bridged dicyclopentadienyl derivative of a metal of groups 4b, 5b or 6b.

6. 发明申请

WO1991005607A1 PROCESS FOR TREATING A SPENT NICKEL-BASED ABSORBENT 审中-公开
标题翻译：用于处理基于镍的吸收剂的方法
公开(公告)号：WO1991005607A1
公开(公告)日：1991-05-02
申请号：PCT/EP1990001691
申请日：1990-10-09
申请人： FINA RESEARCH S.A.
发明人： FINA RESEARCH S.A. , BODART, Philippe, Joseph, Ghislain , DEBRAS, Guy
IPC分类号： B01J20/34
CPC分类号： C10G25/12 , B01J20/0225 , B01J20/06 , B01J20/10 , B01J20/3204 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483
摘要： A spent absorbent material comprising a supported mixture of nickel oxide and metallic nickel may be reactivated a limited number of times by heating the material at 150-450 °C under a flow of non-oxidizing gas.

7. 发明申请

WO1998002469A1 SYNDIOTACTIC/ATACTIC BLOCK POLYOLEFINS, CATALYSTS AND PROCESSES FOR PRODUCING THE SAME 审中-公开
标题翻译：合成/嵌段嵌段聚合物，催化剂及其制备方法
公开(公告)号：WO1998002469A1
公开(公告)日：1998-01-22
申请号：PCT/EP1997003649
申请日：1997-07-10
申请人： FINA RESEARCH S.A. , RAZAVI, Abbas
发明人： FINA RESEARCH S.A.
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F110/06 , C08F2500/16 , C08F2500/03
摘要： Metallocene catalysts useful for the preparation of syndiotactic/atactic block polyolefins have the general formula: R"(C4R'mC5C4R'n) XMeQ wherein X is a hetero-atom ligand with one or two lone pair electrons selected from the elements of Group VA or VIA which can be substituted or non-substituted; (C4Rm'C5C4R'n') is a fluorenyl or a symmetrically substituted fluorenyl or cyclopentadienyl ring; R' is hydrogen or hydrocarbyl radical having from 1-20 carbon atoms, a halogen, an alkoxy, and alkoxy alkyl or an alkylamino or alkylsilylo radical, each R' may be the same or different and m and n independently are 0, 1, 2, 3 or 4, with the proviso that the bilateraly symmetry is maintained; R" is a structural bridge between X and the (C4R'mC5C4R'n) ring to impart stereorigidity; Q is a hydrocarbyl radical having 1-20 carbon atoms or is a halogen; Me is a Group IIIB, IVB, VB, or VIB metal as positioned in the Periodic Table of Elements; and Me can be in any of its theoretically possible oxidation states. Olefin monomers (particularly propylene) polymerised using those catalysts to form syndiotactic/atactic block polymers of high molecular weight and comprising at least 70 % of syndiotactic triads.
摘要翻译：可用于制备间同立构/无规嵌段聚烯烃的茂金属催化剂具有以下通式：R“（C4R'mC5C4R'n）XMeQ其中X是具有一个或两个孤对电子的杂原子配体，其选自组VA或可以被取代或未被取代的（A）R 4 R 5'是C 1 -C 6亚烷基，和烷氧基烷基或烷基氨基或烷基硅烷基，每个R'可以相同或不同，m和n分别是0,1,2,3或4，条件是保持双方对称性; R“是 X和（C4R'mC5C4R'n）环之间的结构桥，赋予立体刚度; Q是具有1-20个碳原子的烃基或是卤素; Me是位于元素周期表中的IIIB，IVB，VB或VIB族金属; 而我可以处于任何理论上可能的氧化态。使用这些催化剂聚合的烯烃单体（特别是丙烯）形成高分子量的间同立构/无规嵌段聚合物并且包含至少70％的间同立构三单元组。

8. 发明申请

WO1995010578A1 HYDROCRACKING AND HYDRODEWAXING PROCESS 审中-公开
标题翻译：水力发电和水力发电工艺
公开(公告)号：WO1995010578A1
公开(公告)日：1995-04-20
申请号：PCT/EP1994003323
申请日：1994-10-07
申请人： AKZO NOBEL N.V. , FINA RESEARCH S.A. , SONNEMANS, Johannes, Wilhelmus, Maria , NOOIJ, Franciscus, Maria , GROOTJANS, Jacques, François, Jeanne
发明人： AKZO NOBEL N.V. , FINA RESEARCH S.A.
IPC分类号： C10G65/12
CPC分类号： C10G45/12 , C10G45/64 , C10G65/12 , F02B3/06
摘要： Process for reducing the wax content of wax-containing hydrocarbon feedstocks to produce middle distillate products including low freeze point jet fuel and/or low pour point and low cloud point diesel fuel and heating oil. The process comprises contacting the feedstock with a hydrocracking catalyst containing a carrier, at least one hydrogenation metal component selected from Group VIB and Group VIII metals, and a large pore zeolite, e.g., a Y type zeolite, in a hydrocracking zone in the presence of hydrogen at elevated temperature and pressure, and contacting the entire effluent from the hydrocracking zone with a dewaxing catalyst containing a crystalline, intermediate pore size molecular sieve selected from metallosilicates, e.g., borosilicates, ironsilicates, and aluminosilicates, and silicoaluminophosphates, e.g., SAPO-11, in a hydrodewaxing zone in the presence of hydrogen at elevated temperature and pressure.
摘要翻译：用于降低含蜡烃原料的蜡含量以生产中间馏分产物的方法，包括低冷凝点喷气燃料和/或低倾点和低浊点柴油燃料和加热油。该方法包括使原料与含有载体的加氢裂化催化剂，至少一种选自VIB族和VIII族金属的加氢金属组分和大孔沸石（例如Y型沸石）在加氢裂化区中在存在氢气，并使来自加氢裂化区的全部流出物与脱蜡催化剂接触，脱蜡催化剂含有选自金属硅酸盐，例如硼硅酸盐，硅酸盐和铝硅酸盐的结晶中等孔径分子筛，和硅铝磷酸盐，例如SAPO-11 在加氢脱蜡区中，在氢气存在下在升高的温度和压力下进行。

9. 发明申请

WO1995010548A1 PROCESS FOR PRODUCING POLYETHYLENE HAVING A BROAD MOLECULAR WEIGHT DISTRIBUTION 审中-公开
标题翻译：生产具有广泛分子量分布的聚乙烯的方法
公开(公告)号：WO1995010548A1
公开(公告)日：1995-04-20
申请号：PCT/BE1993000065
申请日：1993-10-15
申请人： FINA RESEARCH S.A. , DEBRAS, Guy
发明人： FINA RESEARCH S.A.
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F210/16 , C08F2/14 , C08F2/001 , C08F210/14 , C08F2500/07 , C08F2500/04 , C08F2500/13
摘要： A process for the homo- or co-polymerization of ethylene in two liquid full loop reactors in series wherein the average molecular mass is regulated with hydrogen, characterised by the introduction of the comonomer (if any) in the first reactor, and by very low and very high hydrogen concentration respectively in the first and second reactor.
摘要翻译：在两个串联的液体全循环反应器中均匀或共聚乙烯的方法，其中平均分子量用氢调节，其特征在于在第一反应器中引入共聚单体（如果有的话），并且非常低在第一和第二反应器中分别具有非常高的氢浓度。

10. 发明申请

WO1990015846A1 THERMOSETTING POWDER COMPOSITIONS FOR PRIMER COATINGS SUITABLE FOR PVdF-BASED TOP COATINGS 审中-公开
标题翻译：适用于基于PVDF的顶部涂料的预涂涂料的热成型粉末组合物
公开(公告)号：WO1990015846A1
公开(公告)日：1990-12-27
申请号：PCT/BE1990000035
申请日：1990-06-22
申请人： FINA RESEARCH S.A.
发明人： FINA RESEARCH S.A. , RIJKSE, Ludwig, Karl , SIETSES, Willem , GILLARD, Michel
IPC分类号： C09D05/03
CPC分类号： C09D163/00 , B05D5/083 , B05D7/16 , B05D7/546 , C08L2666/02 , C08L2666/04
摘要： Powder compositions comprising 5-15 wt % of a thermosetting binder system based on a resin compatible with PVdF, 50-90 wt % of a thermosetting binder system based on a resin incompatible with PVdF, 0-35 wt % of pigments and 0-3 wt % of levelling agent are suitable for later application of a pigmented PVdF-based top coating. Preferred compositions are based on an epoxy system comprising about 8 wt % of fluorinated or acrylic resin, 5-25 wt % of pigments and 0.7-1 wt % of levelling agent.

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