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    • 86. 发明申请
    • MOCVD FORMATION OF CU2S
    • MOCVD形成CU2S
    • WO2004048637A1
    • 2004-06-10
    • PCT/US2003/021669
    • 2003-07-10
    • ADVANCED MICRO DEVICES, INC.
    • OGLESBY, Jane, V
    • C23C16/18
    • G11C13/0014B82Y10/00C23C16/305G11C13/0009G11C13/0016G11C13/0069G11C2013/009G11C2213/56H01L21/28556H01L2924/0002H01L2924/00
    • A system and methodology are disclosed for forming a passive layer (30, 106, 212) on a conductive layer (110, 402, 602, 808). The formation can be done during fabrication of an organic memory cell, where the passive layer (30, 106, 2,12) generally includes a conductivity facilitating compound (106, 406, 614, 1212), such as copper sulfide (CUZS). The conductivity facilitating compound (106, 406, 614, 1212) is deposited onto the conductive layer (110, 402, 602, 808) via plasma enhanced chemical vapor deposition (PECVD) (200, 800, 1200) utilizing a metal organic (MO) precursor (408, 616). The precursor (408, 616) facilitates depositing the conductivity facilitating compound (106, 406, 614, 1212) in the absence of toxic hydrogen sulfide (HZS), and at a relatively low temperature and pressure (e.g., between about 400 to 600 K and 0.05 to 0.5 Pa., respectively). The deposition process can be monitored and controlled to facilitate, among other things, depositing the conductivity facilitating compound to a desired thickness.
    • 公开了用于在导电层(110,402,602,808)上形成无源层(30,106,212)的系统和方法。 可以在有机存储器单元的制造期间进行形成,其中钝化层(30,106,2,12)通常包括导电性促进化合物(106,406,614,1212),例如硫化铜(CUZS)。 通过使用金属有机物(MO)的等离子体增强化学气相沉积(PECVD)(200,800,1200)将导电促进化合物(106,406,614,1212)沉积到导电层(110,402,602和808)上。 )前体(408,616)。 前体(408,616)有助于在不存在有毒硫化氢(HZS)的情况下沉积导电促进化合物(106,406,614,1212),并且在相对低的温度和压力(例如,约400-600K 和0.05〜0.5Pa)。 可以监测和控制沉积过程,以便促进导电促进化合物沉积到期望的厚度。
    • 87. 发明申请
    • CVD原料用の有機化合物及び該有機化合物を用いた金属又は金属化合物薄膜の製造方法
    • 用于CVD原材料的有机化合物和使用有机化合物生产金属或金属化合物薄膜的方法
    • WO2004024980A1
    • 2004-03-25
    • PCT/JP2003/009861
    • 2003-08-04
    • 田中貴金属工業株式会社斎藤 昌幸
    • 斎藤 昌幸
    • C23C16/18
    • C07C49/92C23C16/18Y10T428/31855
    • An organic compound for CVD raw material, comprising a first organometallic compound having a metal atom coordinating with ligands and, mixed therewith, at least one second organometallic compound comprising as a center atom the same metal atom as in the first organometallic compound, the center atom coordinating with different ligands, which second organometallic compound exhibits decomposition behavior different from that of the fist organometallic compound. In particular, raw material for CVD realizing characteristics of handling easiness and thin film adherence whose simultaneous achievement has been difficult can be produced by selecting a cyclopentadiene complex or derivative thereof as the first organometallic compound and selecting a beta-diketonate compound as the second organometallic compound and by mixing these.
    • 一种用于CVD原料的有机化合物,其包含具有与配体配位的金属原子的第一有机金属化合物,并与其混合至少一种第二有机金属化合物,其包含与第一有机金属化合物相同的金属原子作为中心原子,中心原子 与不同配体配位,第二有机金属化合物表现出与第一有机金属化合物不同的分解行为。 特别是,通过选择环戊二烯复合物或其衍生物作为第一有机金属化合物并选择β-二酮化合物作为第二有机金属化合物,可以制备CVD实现处理容易度特性和薄膜粘附难度同时达到的原料 并通过混合这些。