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81. 发明申请

WO1994023344A1 COMPOSITION AND USE 审中-公开
标题翻译：组成和使用
公开(公告)号：WO1994023344A1
公开(公告)日：1994-10-13
申请号：PCT/GB1994000654
申请日：1994-03-29
申请人： ZENECA LIMITED , CAMPBELL, James, Stanley , GREGORY, Peter
发明人： ZENECA LIMITED
IPC分类号： G03G09/097
CPC分类号： G03G9/09783
摘要： A toner resin composition comprising a toner resin and a negative charging charge control agent (CCA) which is a di- or trivalent metal salt of a naphthalene oxy-carboxylic acid wherein the hydroxy group and carboxylic acid group are attached to adjacent carbon atoms of an aromatic ring. The CCA is preferably the zinc, aluminium or iron salt of 3-hydroxy-2-naphthoic acid.
摘要翻译：一种调色剂树脂组合物，其包含调色剂树脂和作为萘氧基羧酸的二价或三价金属盐的负带电电荷控制剂（CCA），其中羟基和羧酸基团连接到相邻的碳原子上芳香环。 CCA优选为3-羟基-2-萘甲酸的锌，铝或铁盐。

82. 发明申请

WO1994021606A1 PENTAFLUOROSULPHANYLPHENYL AND PENTAFLUOROSULPHANYLPYRIDIL SUBSTITUTED HETEROAROMATIC COMPOUNDS WITH INSECTICIDAL OR ACARICIDAL ACTIVITY 审中-公开
标题翻译：卟啉二苯醚和P UL UL ANY IL IL IL IL ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY ITY
公开(公告)号：WO1994021606A1
公开(公告)日：1994-09-29
申请号：PCT/GB1994000612
申请日：1994-03-24
申请人： ZENECA LIMITED , SALMON, Roger , PEARSON, David, Philip, John , PARRY, David, Rees , KOZAKIEWICZ, Anthony, Marian
发明人： ZENECA LIMITED
IPC分类号： C07D207/36
CPC分类号： C07D213/64 , A01N43/36 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N47/02 , C07C381/00 , C07D207/36 , C07D231/12 , C07D231/28 , C07D231/38 , C07D233/56 , C07D233/64 , C07D233/84 , C07D233/88 , C07D239/36 , C07D249/08
摘要： Compounds with insecticidal or acaricidal activity have formula (IA) or (IB), wherein Ra represents hydrogen or from 1 to 4 optional substituents and Rb represents from 1 to 3 optional substituents and wherein A represents an optionally substituted N-linked nitrogen-containing five or six membered aromatic heterocyclic ring, for example imidazole, pyrrole, pyrazole, pyrimidinone and pyridone.
摘要翻译：具有杀虫或杀螨活性的化合物具有式（IA）或（IB），其中R a表示氢或1至4个任选的取代基，R b表示1至3个任选的取代基，并且其中A表示任选取代的N-连接的含氮五或六元芳族杂环，例如咪唑，吡咯，吡唑，嘧啶酮和吡啶酮。

83. 发明申请

WO1994020479A1 N-(BETA-BRANCHED ALKYL)-1,2-BENZISOTHIAZOLIN-3-ONES, THEIR PREPARATION AND USE AS INDUSTRIAL BIOCIDES 审中-公开
标题翻译： N-（β-分支烷基）-1,2-BENZISOTHIAZOLIN-3-ONES，其制备和用作工业生物
公开(公告)号：WO1994020479A1
公开(公告)日：1994-09-15
申请号：PCT/GB1994000320
申请日：1994-02-17
申请人： ZENECA LIMITED , AUSTIN, Peter, William
发明人： ZENECA LIMITED
IPC分类号： C07D275/04
CPC分类号： C07D275/04 , A01N43/80 , Y10S528/935
摘要： The invention relates to N-( beta -branched alkyl)-1,2-benzisothiazolin-3-ones having two or more carbon atoms in the alkyl side chain such as N-(2-ethylhexyl)-1,2-benzisothiazolin-3-one. The compounds are suitable as paint film fungicides.
摘要翻译：本发明涉及在烷基侧链中具有两个或更多个碳原子的N-（β-支链烷基）-1,2-苯并异噻唑啉-3-酮，例如N-（2-乙基己基）-1,2-苯并异噻唑啉-3 -一。该化合物适合作为漆膜杀真菌剂。

84. 发明申请

WO1994020204A1 PRODUCTION OF PARTICULATE MATERIALS 审中-公开
标题翻译：颗粒材料的生产
公开(公告)号：WO1994020204A1
公开(公告)日：1994-09-15
申请号：PCT/GB1993002554
申请日：1993-12-15
申请人： ZENECA LIMITED , IMPERIAL CHEMICAL INDUSTRIES PLC , OLIVER, Raymond , FAIRCLOUGH, Anthony, Rupert, Nigel , ANTONINI, Alejandro, Martin , MUNRO, Robert, James , LIPSCOMBE, Lynn, Wilfred
发明人： ZENECA LIMITED , IMPERIAL CHEMICAL INDUSTRIES PLC
IPC分类号： B01J02/04
CPC分类号： B01D1/18 , B01J2/04 , B05B7/0861
摘要： A process for producing solid particles by drying a spray of liquid droplets. The droplets are formed by projecting a liquid formulation as a plurality of jets (J) (Figure 6) in such a way that each jet breaks up into droplets of narrow size distribution. Prior to the onset of coalescence the droplets are contacted with a gas flow (G) which is arranged to reduce coalescence by disrupting slip streaming of the droplets and/or accelerating the droplets.
摘要翻译：通过干燥液滴喷雾来生产固体颗粒的方法。通过将液体制剂投影为多个喷嘴（J）（图6），使得每个射流分解成窄尺寸分布的液滴的方式形成液滴。在聚结开始之前，液滴与气流（G）接触，气流被设置为通过破坏液滴的滑动流动和/或加速液滴来减少聚结。

85. 发明申请

WO1994017062A1 SUBSTITUTED FUSED PYRAZOLO COMPOUNDS AND THEIR USE AS HERBICIDES 审中-公开
标题翻译：取代的FUSED PYRAZOLO化合物及其作为除草剂的用途
公开(公告)号：WO1994017062A1
公开(公告)日：1994-08-04
申请号：PCT/GB1994000067
申请日：1994-01-13
申请人： ZENECA LIMITED
发明人： ZENECA LIMITED , MICHAELY, William, James , CURTIS, Jeff, Kimo , KNUDSEN, Christopher, Glade
IPC分类号： C07D471/04
CPC分类号： C07D471/04 , A01N43/90 , C07D487/04
摘要： Novel substituted pyrazolo-rings fused to nitrogen containing heterocyclic rings having formula (I) in which at least one of Y, Z or W is N or N-O and the remainder of Y, Z or W is C-R wherein R is hydrogen; halogen; nitro; cyano; alkyl; alkoxymethyl; acetoxymethyl; hydroxymethyl; haloalkyl; formyl; alkylcarbonyl; carboxy and its salts; COO alkyl; azido (N3); amino; substituted amino wherein the substituents are alkyl, alkoxy, hydroxy, formyl, alkylcarbonyl, alkoxycarbonylalkyloxy, alkoxycarbonylalkylthio, alkoxycarbonylalkylidenecarbonyl, hydroxycarbonylalkoxy, hydroxycarbonylthio, cyanoalkoxy, hydroxycarbonylalkyledinecarbonyl, alkylsufonyl, haloalkylsulfonyl, aminocarbonyl, (di)alkylaminocarbonyl, alkoxycarbonyl, alkoxyalkyl, hydroxycarbonylalkyl, alkoxycarbonylalkyl, and amino; carboxyamido; substituted carboxyamido wherein said substituents can be selected from alkyl, alkylsulfonyl, and haloalkylsulfonyl; sulfonamido wherein the N is substituted with hydrogen and/or alkyl; YR wherein Y is O and S(O)m and R is selected from the group hydrogen, alkyl, haloalkyl, cyanolalkyl, alkoxycarbonylalkyl, hydroxycarbonylalkyl and aminocarbonylalkyl wherein the N is substituted with hydrogen and/or alkyl; m is 0 to 2; R is hydrogen and halogen; R is hydrogen, nitro, halogen, cyano, alkylthio, alkylsulfinyl, alkylsulfonyl, and alkoxy; R is halogen, haloalkyl, cyano, alkylthio, alkylsulfinyl, and alkylsulfonyl; R is hydrogen and halogen; X is N or C-R ; wherein R is hydrogen, haloalkyl, halogen, cyano, nitro, alkylthio, alkylsulfinyl, alkylsulfonyl, and alkoxy; and agriculturally acceptable salts thereof.
摘要翻译：与式（I）的含氮杂环稠合的新型取代的吡唑并环，其中Y，Z或W中的至少一个为N或N-O，Y，Z或W的其余部分为C-R，其中R为氢; 卤素; 硝基; 氰基; 烷基; 烷氧基; 乙酰氧基; 羟甲基; 卤代; 甲酰基; 羰基; 羧基及其盐; COO烷基; 叠氮（N 3）; 氨基; 取代的氨基，其中取代基是烷基，烷氧基，羟基，甲酰基，烷基羰基，烷氧基羰基烷氧基，烷氧基羰基烷硫基，烷氧基羰基亚烷基羰基，羟基羰基烷氧基，羟基羰基硫基，氰基烷氧基，羟基羰基烷基羰基，烷基磺酰基，卤代烷基磺酰基，氨基羰基，（二）烷基氨基羰基，烷氧基羰基，烷氧基烷基，羟基羰基烷基，烷氧基羰基烷基和氨基; 羧酰胺; 取代的羧酰胺基，其中所述取代基可以选自烷基，烷基磺酰基和卤代烷基磺酰基; 其中N被氢和/或烷基取代; YR 6其中Y是O且S（O）m和R 6选自氢，烷基，卤代烷基，环烷醇烷基，烷氧基羰基烷基，羟基羰基烷基和氨基羰基烷基，其中N被氢和/或烷基取代; m为0〜2; R 1是氢和卤素; R 2是氢，硝基，卤素，氰基，烷硫基，烷基亚磺酰基，烷基磺酰基和烷氧基; R 3是卤素，卤代烷基，氰基，烷硫基，烷基亚磺酰基和烷基磺酰基; R 4是氢和卤素; X是N或C-R 5; 其中R 5是氢，卤代烷基，卤素，氰基，硝基，烷硫基，烷基亚磺酰基，烷基磺酰基和烷氧基; 和其农业上可接受的盐。

86. 发明申请

WO1994016021A1 AZO COMPOUND 审中-公开
标题翻译： AZO化合物
公开(公告)号：WO1994016021A1
公开(公告)日：1994-07-21
申请号：PCT/GB1993002585
申请日：1993-12-17
申请人： ZENECA LIMITED , KENYON, Ronald, Wynford , MISTRY, Prahalad, Manibhai
发明人： ZENECA LIMITED
IPC分类号： C09B33/052
CPC分类号： C09D11/328 , C09B33/052 , C09B62/03 , C09B62/043 , C09B62/09
摘要： A compound of the formula (1): Ar N = N-J-X-L-X-J-N = NAr and salts thereof, wherein: J is (2), Ar and Ar are each independently aryl containing at least two carboxy groups; and L is a group of formula (3a) or (3b), in which T and R each independently is C1-4-alkyl, C1-4-alkoxy or C3-4-alkenyl; and T and T each independently is H, C1-4-alkyl, C1-4-alkoxy or C3-4-alkenyl provided that T and T are not both H; each X independently is a group of formula (4), (5) or (6), each Z independently is H, halogen, alkyl, NR R , SR or OR ; each Y independently is Z, SR or OR ; each E independently is C1 or CN; and R , R , R and R are each independently H, alkyl, substituted alkyl, alkenyl, substituted alkenyl, cycloalkyl, aryl, substituted aryl, aralkyl or substituted aralkyl, or R and R , together with the nitrogen atom to which they are attached, form a 5 or 6 membered ring. A compound of formula (1) is suitable for use in the coloration of cellulosic substrates, such as paper, to give bright prints with good light and water fastness. It is especially suitable for use in the printing of paper by non-impact printing techniques, such as ink jet printing, especially thermal ink jet printing.
摘要翻译：式（1）的化合物：Ar 1 N = NJXLXJN = NAr 2及其盐，其中：J为（2），Ar 1和Ar 2各自独立地为含有至少两个羧基; 并且L是式（3a）或（3b）的基团，其中T 1和R 2各自独立地是C 1-4 - 烷基，C 1-4 - 烷氧基或C 3-8 - 烯基; 且T 3和T 4各自独立地为H，C 1-4 - 烷基，C 1-4 - 烷氧基或C 3-8 - 烯基，条件是T 3和T 4不均为H; 每个X独立地是式（4），（5）或（6）的基团，每个Z独立地是H，卤素，烷基，NR 1 R 2，SR 3或OR 3; 每个Y独立地是Z，SR 4或OR 4; 每个E独立地为C1或CN; R 1，R 2，R 3和R 4各自独立地为H，烷基，取代的烷基，烯基，取代的烯基，环烷基，芳基，取代的芳基，芳烷基或取代的芳烷基， 1和R 2与它们所连接的氮原子一起形成5或6元环。式（1）的化合物适合用于诸如纸等纤维素基质的着色，得到光亮和耐水牢度好的光亮印花。特别适用于通过非冲击印刷技术如喷墨印刷，特别是热喷墨印刷来印刷纸张。

87. 发明申请

WO1994016000A1 POLYHYDROXYALKANOATES AND FILM FORMATION THEREFROM 审中-公开
标题翻译：聚羟基烷酸酯和膜形成
公开(公告)号：WO1994016000A1
公开(公告)日：1994-07-21
申请号：PCT/GB1994000056
申请日：1994-01-12
申请人： ZENECA LIMITED , WADDINGTON, Simon, Dominic
发明人： ZENECA LIMITED
IPC分类号： C08J05/18
CPC分类号： C08J5/18 , C08G63/06 , C08J2367/04 , Y10T428/1355 , Y10T428/2913 , Y10T428/31786
摘要： A supported or cast film of a polyhydroxyalkanoate polymer, such as a polyhydroxybutyrate/valerate polymer, can be prepared by applying a layer of molten polymer to a cool (typically 4 to 20 DEG C) surface not substantially above the glass transition temperature of the polymer, so as to form a solid, glassy film with a high density of nucleation sites; subsequently the temperature of the film so formed is raised, for example to 40 DEG C or more, towards the optimum temperature for growth of the polymer's spherulites effectively separating the film formation/nucleation step from the crystallisation step (growth of spherulites around the nucleation sites). Smaller crystallites are formed, and the film has improved barrier properties.
摘要翻译：聚羟基链烷酸酯聚合物如聚羟基丁酸酯/戊酸酯聚合物的负载或流延膜可以通过将熔融聚合物层施加到基本上不超过聚合物的玻璃化转变温度的冷（通常为4至20℃）的表面来制备，以形成具有高密度成核点的固体，玻璃状膜; 随后将如此形成的膜的温度升高至例如40℃或更高，达到聚合物球晶生长的最佳温度，从而有效地将成膜/成核步骤与结晶步骤分离（成核位置周围的球晶生长）。形成较小的微晶，并且膜具有改善的阻隔性能。

88. 发明申请

WO1994013818A1 IDENTIFICATION OF COMPOUNDS MODULATIONS PROTEIN/CELL MEMBRANE ASSOCIATION 审中-公开
标题翻译：化合物调节蛋白/细胞膜结合的鉴定
公开(公告)号：WO1994013818A1
公开(公告)日：1994-06-23
申请号：PCT/GB1993002543
申请日：1993-12-14
申请人： ZENECA LIMITED , BROAD, Peter, Michael
发明人： ZENECA LIMITED
IPC分类号： C12N15/62
CPC分类号： G01N33/5011 , C07K14/395 , C07K2319/00 , C07K2319/61 , C07K2319/81 , C07K2319/90 , C12N15/1055 , C12N15/62 , C12Q1/6897 , G01N33/5008 , G01N33/502
摘要： A method for identifying compounds which modulate protein/cell membrane association which method comprises contacting a test compound with a cell, having (i) a cell membrane, (ii) a heterologous protein comprising a reporter sequence and a recognition sequence for cell membrane association, (iii) a reporter system which is acted upon by the reporter sequence such that there is a measurable change in cell phenotype upon modulation of protein/cell membrane association by the test compound, and detecting any change in cell phenotype.
摘要翻译：一种用于鉴定调节蛋白质/细胞膜缔合的化合物的方法，该方法包括使测试化合物与细胞接触，所述化合物具有（i）细胞膜，（ii）包含报道序列的异源蛋白质和细胞膜缔合的识别序列，（iii）由报道序列作用的报道系统，使得在调节受试化合物的蛋白质/细胞膜缔合后细胞表型存在可测量的变化，并检测细胞表型的任何变化。

89. 发明申请

WO1994012625A2 LIGAND BINDING VARIABLE DOMAIN (V-MIN) COMPRISING A FRAMEWORK REGION WITH A CYCLICALLY PERMUTED CENTRAL 'beta'-BARREL 审中-公开
标题翻译：配有可循环中心型贝塔的框架区域（V-MIN）绑定可变域（V-MIN）
公开(公告)号：WO1994012625A2
公开(公告)日：1994-06-09
申请号：PCT/GB1993002375
申请日：1993-11-19
申请人： ZENECA LIMITED
发明人： ZENECA LIMITED , SLATER, Anthony, Michael , TIMMS, David
IPC分类号： C12N15/00
CPC分类号： C07K16/00 , A61K38/00
摘要： The invention relates to ligand binding variable domains (V-mins) having structural rearrangement of the binding domain of immunoglobulins and other ligand binding members of the immunoglobulin superfamily. The minimal elements necessary to retain good antigen binding affinity, the complementarity determining region (CDRs) and the central beta barrel structure for the Fv fragment, may be retained positioned appropriately in space by cyclic permutation of the central beta barrel structure and leaving the strands of the beta barrel intact. The invention is also independently based on recognising that after cyclic permutation of the central beta barrel the framework region which supports the CDRs can be pared down through creation of novel linkages in the structure.
摘要翻译：本发明涉及具有免疫球蛋白结合域和免疫球蛋白超家族的其他配体结合成员的结构重排的配体结合可变结构域（V-mins）。保留良好抗原结合亲和力，互补决定区（CDR）和Fv片段的中央β桶结构所必需的最小元素可以通过中心β桶结构的循环排列保持适当地定位在空间中，并留下 beta桶完好无损。本发明还独立地基于认识到在中央β桶的循环置换之后，通过在结构中产生新的连接，可以减少支持CDR的框架区。

90. 发明申请

WO1994012577A2 POLYCYCLIC DYES 审中-公开
标题翻译：多环染料
公开(公告)号：WO1994012577A2
公开(公告)日：1994-06-09
申请号：PCT/GB1993002296
申请日：1993-11-08
申请人： ZENECA LIMITED
发明人： ZENECA LIMITED , BENTLEY, Stephen, John , KENYON, Ronald, Wynford , MILNER, David, John
IPC分类号： C09B57/00
CPC分类号： C07D493/04 , C07C69/65 , C07C201/12 , C07C205/56 , C07C231/02 , C07C233/11 , C07C253/30 , C07C255/35 , C09B57/00
摘要： A process for the preparation of a polycyclic dye of formula (1) by reacting a compound of formula (2) with a compound of formula (3), wherein Ring A is unsubstituted or is substituted by from 1 to 5 groups; Ring B is unsubstituted or is substituted by from 1 to 5 groups; X and X each independently is -H, halogen, cyano, alkyl or aryl; X and X each independently is halogen; and Z is -CN, -CO2R or -CONR R , in which R is optionally substituted alkyl, optionally substituted aryl or optionally substituted aralkyl, and R and R each independently is -H, alkyl, aryl or aralkyl. A process for the preparation of compounds of formula (3) and novel compounds of formula (3) are also claimed. The compounds of formula (1) are useful as dyes particularly for the coloration of synthetic textile materials.
摘要翻译：通过使式（2）的化合物与式（3）的化合物反应制备式（1）的多环染料的方法，其中环A是未取代的或被1至5个基团取代; 环B是未取代的或被1至5个基团取代; X和X 1各自独立地为-H，卤素，氰基，烷基或芳基; X 2和X 3各自独立地为卤素; 并且Z为-CN，-CO 2 R或-CONR 1 R 2，其中R为任选取代的烷基，任选取代的芳基或任选取代的芳烷基，R 1和R 2各自独立地为-H ，烷基，芳基或芳烷基。还要求保护制备式（3）化合物和式（3）新化合物的方法。式（1）的化合物可用作染料，特别用于合成纺织材料的着色。

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