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81. 发明申请

WO1997009386A1 ELECTRICALLY CONDUCTIVE ARTICLE 审中-公开
标题翻译：电导体文章
公开(公告)号：WO1997009386A1
公开(公告)日：1997-03-13
申请号：PCT/FI1996000476
申请日：1996-09-05
申请人： NESTE OY , VÄKIPARTA, Kimmo , VIRTANEN, Esa , SAVOLAINEN, Esko , KIRMANEN, Pauli , JUSSILA, Matti
发明人： NESTE OY
IPC分类号： C08L101/12
CPC分类号： H01B1/128
摘要： The invention relates to electrostatically controlled plastics articles, their manufacture and their use. An article according to the invention contains a conductive polymer, and the surface resistivity of its outer surface, expressed in OMEGA /square, is at minimum one decade higher than volume resistivity of its interior, expressed in OMEGA -cm. The conductive polymer used may be in particular polyaniline. The invention can be exploited in the manufacture from plastics, for example, of transportation containers or equipment casings in which electrostatic shielding is required.
摘要翻译：本发明涉及静电控制塑料制品，其制造及其用途。根据本发明的制品包含导电聚合物，以OMEGA / square表示的其外表面的表面电阻率比其内部的体积电阻率至少高十倍，以OMEGA-cm表示。所使用的导电聚合物可以是特别是聚苯胺。本发明可以在塑料制造中被利用，例如运输容器或需要静电屏蔽的设备外壳。

82. 发明申请

WO1996031552A1 THERMOPLASTIC BIODEGRADABLE POLYESTER, A PROCESS FOR THE PREPARATION THEREOF AND ARTICLES MANUFACTURED THEREFROM 审中-公开
标题翻译：热塑性生物可降解聚酯，其制备方法及其制造的制品
公开(公告)号：WO1996031552A1
公开(公告)日：1996-10-10
申请号：PCT/FI1996000183
申请日：1996-04-03
申请人： NESTE OY , SEPPÄLÄ, Jukka , HÄRKÖNEN, Mika , HILTUNEN, Kari , SELIN, Johan-Fredrik , HAKOLA, Jyrki
发明人： NESTE OY
IPC分类号： C08G63/06
CPC分类号： C08G63/912 , C08L63/00 , C08L2666/18
摘要： The invention concerns a novel melt-processible copolyester and a process and prepolymer for the preparation thereof. The copolyester contains structural units derived from a polyester and structural units derived from diepoxy, and the polyester units at least essentially consist of hydroxy acid monomers. The bonds between the structural units are ester bonds and the number average molar mass, Mn, is at least 10,000 g/mol, its weight average molar mass, Mw, is over 20,000 g/mol and molar mass distribution, expressed as the ratio Mw/Mn, is over 2. The copolyester is hydrolytically degradable and it can be used as a biodegradable polymer for the manufacture of injection moulded articles as well as thermoformed and blow moulded packages, pouches, sacks and bottles, for the coating of sacks bags and films made from paper or cardboard and for the preparation of fibres, fibre cloths and expanded polymer articles.
摘要翻译：本发明涉及一种新型的可熔融加工的共聚酯及其制备方法和预聚物。共聚酯包含衍生自聚酯的结构单元和衍生自二环氧基的结构单元，并且聚酯单元至少基本上由羟基酸单体组成。结构单元之间的键是酯键，数均摩尔质量Mn至少为10,000g / mol，其重均摩尔质量Mw大于20,000g / mol，摩尔质量分布以Mw / Mn，超过2.共聚酯是可水解降解的，可用作可生物降解的聚合物，用于制造注塑制品以及热成型和吹塑成型包装，袋，袋和瓶，用于袋袋的涂布和由纸或纸板制成的薄膜和用于制备纤维，纤维布和膨胀聚合物制品的薄膜。

83. 发明申请

WO1996029550A1 COLLECTOR OF SOLAR ENERGY 审中-公开
标题翻译：太阳能收集器
公开(公告)号：WO1996029550A1
公开(公告)日：1996-09-26
申请号：PCT/FI1996000159
申请日：1996-03-18
申请人： NESTE OY , PELTOLA, Seppo , KÄRNÄ, Toivo , MÄISTI, Asko , PENTTINEN, Paavo , NIEMINEN, Jukka-Pekka
发明人： NESTE OY
IPC分类号： F24J02/00
CPC分类号： F24S40/42 , F24S20/67 , F24S25/615 , F24S40/40 , F24S80/50 , F24S80/56 , F24S80/70 , Y02A30/62 , Y02B10/20 , Y02E10/44 , Y02E10/47
摘要： The invention concerns a collector (10) of solar energy, which includes a cover (11) penetrable by light and an absorber (12) as well as a system of flow ducts (13) in the absorber (12). The space between the cover (11) penetrable by light and the absorber (12) has been formed as a hermetically sealed space (17).
摘要翻译：本发明涉及一种太阳能收集器（10），其包括可被光穿透的盖子（11）以及吸收器（12）以及吸收器（12）中的流动管道系统（13）。可透过光的盖（11）和吸收体（12）之间的空间形成为气密密封空间（17）。

84. 发明申请

WO1996025472A1 PROCESS FOR THE PRODUCTION OF OLEFINS USING A MOLYBDENUM OXICARBIDE DEHYDROGENATION CATALYST 审中-公开
标题翻译：使用氧化硅脱氢催化剂生产烯烃的方法
公开(公告)号：WO1996025472A1
公开(公告)日：1996-08-22
申请号：PCT/FI1996000094
申请日：1996-02-19
申请人： NESTE OY , KRAUSE, Outi , LEDOUX, Marc, Jacques , MEUNIER, Frédéric , DEL GALLO, Pascal , PHAM-HUU, Cuong , NIEMI, Vesa , HILTUNEN, Jyrki
发明人： NESTE OY
IPC分类号： C10G29/16
CPC分类号： C10G11/02 , B01J27/22 , C07C5/333 , C07C2527/20 , C07C2527/224 , C07C11/02
摘要： A process for the production of light olefins, such as ethylene, propylene, butylene and/or amylene is described. The process comprises contacting a hydrocarbon feed comprising, for instance, a gasoline or naphta fraction containing alkanes having from 4 to 12 carbon atoms per molecule at an elevated temperature with a molybdenum oxicarbide catalyst. The process may be carried out in the presence of water vapour or free oxygen in order to stabilize the oxicarbide phase. The catalyst is preferably supported on silicon carbide optionally doped with at least one lanthanide, actinide, rare earth metal, or a mixture thereof.
摘要翻译：描述了生产轻质烯烃如乙烯，丙烯，丁烯和/或亚戊烯的方法。该方法包括在升高的温度下将包含例如含有每分子4-12个碳原子的烷烃的汽油或萘塔馏分与碳氧化钼催化剂接触。该方法可以在水蒸汽或游离氧的存在下进行，以稳定氧化碳相。催化剂优选负载在任选掺杂有至少一种镧系元素，锕系元素，稀土金属或其混合物的碳化硅上。

85. 发明申请

WO1996011193A1 ALKENYL SUBSTITUTED CYCLIC CARBOXYL ACID ANHYDRIDES AND THEIR APPLICATION IN HYDROPHOBIC PAPER SIZING 审中-公开
标题翻译：烷基取代的环状羧酸酐及其在疏水纸尺寸上的应用
公开(公告)号：WO1996011193A1
公开(公告)日：1996-04-18
申请号：PCT/FI1995000541
申请日：1995-10-04
申请人： NESTE OY , KAPANEN, Mika , KOSKIMIES, Salme , RANTANEN, Jaana , HALME, Erkki , SAVOLAINEN, Raija
发明人： NESTE OY
IPC分类号： C07D307/60
CPC分类号： D21H17/16 , C07C57/13
摘要： The invention relates to alkene-substituted cyclic carboxylic acid anhydrides which are formed from the reaction product of a cyclic carboxylic acid anhydride, preferably succinic acid anhydride, and an olefin blend. The olefin blend is made up of internal linear and branched olefins and linear and/or branched alpha -olefins, in which blend the olefins contain 13-25 carbon atoms, and the internal and alpha -olefins are present at a ratio of 5-95 % to 95-5 %. The invention also relates to methods for the preparation of these compounds from a carboxylic acid anhydride and the said olefin blend, which is prepared by oligomerizing a so-called Raffinate II stream containing 1-butene and 2-butene, by pyrolyzing a high molecular weight polyethylene, and by separating from the obtained product the olefin fraction which primarily contains 13-25 carbon atoms or by dehydrogenating a blend of suitable alcohols to the said olefin blend. The obtained alkene-substituted cyclic carboxylic acid anhydride can be used in particular for the preparation of an ASA sizing agent suitable for paper sizing; this sizing agent has been observed to have excellent efficacy in reducing permeability to water.
摘要翻译：本发明涉及由环状羧酸酐，优选琥珀酸酐和烯烃共混物的反应产物形成的烯烃取代的环状羧酸酐。烯烃共混物由内部直链和支链烯烃和直链和/或支链α-烯烃组成，其中烯烃含有13-25个碳原子，内部和α-烯烃以5-95的比例存在％〜95-5％。本发明还涉及由羧酸酐和所述烯烃共混物制备这些化合物的方法，其通过将含有1-丁烯和2-丁烯的所谓的残液II流混合，通过热分解高分子量并且通过从所得产物中分离出主要包含13-25个碳原子的烯烃级分，或通过将合适的醇的共混物脱氢到所述烯烃共混物中。得到的烯烃取代的环状羧酸酐特别可用于制备适用于纸张施胶的ASA施胶剂; 已经观察到该施胶剂在降低水的渗透性方面具有优异的效果。

86. 发明申请

WO1996001863A1 MELT-PROCESSIBLE POLY(ESTER URETHANE) AND A PROCESS FOR THE PREPARATION THEREOF 审中-公开
标题翻译：熔融混合物（ESTER URETHANE）及其制备方法
公开(公告)号：WO1996001863A1
公开(公告)日：1996-01-25
申请号：PCT/FI1995000396
申请日：1995-07-07
申请人： ALKO GROUP LTD. , NESTE OY , SEPPÄLÄ, Jukka , HÄRKÖNEN, Mika , HILTUNEN, Kari , MALIN, Minna , KYLMÄ, Janne
发明人： ALKO GROUP LTD. , NESTE OY
IPC分类号： C08G18/42
CPC分类号： C08G18/4283 , C08G63/06 , C08G2101/00 , C08G2230/00
摘要： The invention concerns a novel melt-processible poly(ester urethane) and a process and a prepolymer for the preparation thereof. The poly(ester urethane) contains structural units derived from a polyester and structural units derived from a diisocyanate and, according to the invention, the bonds between the structural units are at least mainly comprised only of urethane bonds, the number average molar mass, Mn, of the polymer is at least 10,000 g/mol, its mass-average molar mass, Mw, is over 20,000 g/mol and its molar mass distribution, expressed as the ratio Mw/Mn, is over 2, and the polymer is essentially free from free isocyanate groups. The poly(ester urethane) is hydrolytically decomposable and it can be used as a biodegradable polymer, e.g., for manufacturing injection moulded pieces and thermoformed and blow moulded packages, bags, sacks and bottles, for coating of sacks, bags and films made of paper or cardboard, and for manufacturing fibres and non-woven fabrics.
摘要翻译：本发明涉及一种新型的可熔融加工的聚（酯聚氨酯）及其制备方法和预聚物。聚（酯氨基甲酸酯）含有衍生自聚酯的结构单元和衍生自二异氰酸酯的结构单元，根据本发明，结构单元之间的键至少主要仅包含氨基甲酸酯键，数均摩尔质量Mn 的聚合物为至少10,000g / mol，其质均平均摩尔质量Mw为20,000g / mol以上，其摩尔质量分布（以Mw / Mn表示）大于2，聚合物基本上不含游离异氰酸酯基团。聚（酯氨基甲酸酯）可水解分解，可用作可生物降解的聚合物，例如用于制造注塑件和热成型和吹塑成型包装，袋，袋和瓶子，用于包装纸袋，袋和纸制成的纸或纸板，以及用于制造纤维和无纺织物。

87. 发明申请

WO1996001480A1 ELECTRICALLY CONDUCTING POLYMER COMPOSITIONS 审中-公开
标题翻译：电导体聚合物组合物
公开(公告)号：WO1996001480A1
公开(公告)日：1996-01-18
申请号：PCT/FI1995000359
申请日：1995-06-21
申请人： NESTE OY , LAAKSO, Jukka , ÖSTERHOLM, Jan-Erik , JÄRVINEN, Hannele
发明人： NESTE OY
IPC分类号： H01B01/12
CPC分类号： H01B1/128 , C08L61/06 , C08L67/06 , C08L79/02 , C08L2666/20 , C08L2666/18 , C08L2666/16
摘要： The present invention relates to electrically conducting thermoset compositions and methods for preparing them. In the compositions according to the invention, the conducting component is a polyaniline protonated with a protonic acid containing at least one hydroxyl group. The thermoset matrix can be, for instance, a phenol-formaldehyde resin, a melamine-formaldehyde resin, or a polyester resin.
摘要翻译：本发明涉及导电热固性组合物及其制备方法。在根据本发明的组合物中，导电组分是用含有至少一个羟基的质子酸质子化的聚苯胺。热固性基质可以是例如酚醛树脂，三聚氰胺甲醛树脂或聚酯树脂。

88. 发明申请

WO1995032243A1 POLYPHENYLENE ETHER BLENDS AND PROCESS FOR PRODUCING THEM 审中-公开
标题翻译：聚苯醚及其生产方法
公开(公告)号：WO1995032243A1
公开(公告)日：1995-11-30
申请号：PCT/FI1995000275
申请日：1995-05-19
申请人： NESTE OY , IKKALA, Olli , PIETILÄ, Lars-Olof , HOLSTI-MIETTINEN, Riitta , KATSARAS, Nikitas , SELÄNTAUS, Maaria , ÖSTERHOLM, Heidi , BERGSTRÖM, Christer
发明人： NESTE OY
IPC分类号： C08L71/12
CPC分类号： C08L67/02 , C08K5/0008 , C08L67/00 , C08L71/02 , C08L71/123 , C08L77/00 , C08L79/08 , C08L71/12 , C08L2666/02 , C08L71/00
摘要： The present invention concerns polymer blends and processes for the preparation thereof. The present blends contain a) 5 to 95 parts by weight of poly(2,6-dimethyl-1,4-phenylene)ether, b) 95 to 5 parts by weight of a second polymer which is immiscible therewith, and c) a component (a compatibilizer) which enhances the compatibility of the polymers. According to the invention the component enhancing the compatibility of the polymers comprises 0.1 to 10 %, preferably about 1.5 to 10 %, calculated on basis of the total weight of components a and b, of at least one compound C, which has the formula (I): Ai-Bj wherein A stands for a group which contains at least one ring with 3 to 7 members, capable of forming ring-to-ring interactions with the phenyl rings of poly(2,6-dimethyl-1,4-phenylene)ether; B is a polar group; i is an integer 1 to 20; and j is an integer 0 to 20; whereat i + j is greater than or equal to 2; the melting point of compound C is above 50 DEG C and the boiling point thereof above 200 DEG C (at 760 mmHg) and c; compound C is capable of at least partially dissolving poly(2,6-dimethyl-1,4-phenylene)ether. The polymer blends according to the invention are processible and their elasticity moduli are at least 10 % greater than those of blends which do not contain substance C, which has instead been replaced by the same amount of component b. The polymer blends can be used for the preparation of fibres, coatings and films.
摘要翻译：本发明涉及聚合物共混物及其制备方法。本发明共混物包含a）5-95重量份的聚（2,6-二甲基-1,4-亚苯基）醚，b）95-5重量份与其不混溶的第二聚合物，和c）a 组分（增容剂），其增强聚合物的相容性。根据本发明，提高聚合物相容性的组分包含0.1至10％，优选约1.5至10％，基于组分a和b的总重量计算，至少一种化合物C具有式（ I）：Ai-Bj其中A代表含有至少一个具有3至7个成员的环的基团，其能够与聚（2,6-二甲基-1,4-苯并二恶烷）的苯环形成环 - 环相互作用，苯基）醚; B是极性基团; 我是整数1到20; j为0〜20的整数。其中i + j大于或等于2; 化合物C的熔点高于50℃，沸点高于200℃（760mmHg）和c; 化合物C能够至少部分溶解聚（2,6-二甲基-1,4-亚苯基）醚。根据本发明的聚合物共混物是可加工的，并且它们的弹性模量比不含有相同量的组分b的物质C的共混物的弹性模量大至少10％。聚合物共混物可用于制备纤维，涂料和薄膜。

89. 发明申请

WO1995022151A1 AN ELECTRICALLY CONDUCTING POLYMER COMPOSITION, ITS PRODUCTION AND ITS USE 审中-公开
标题翻译：电导式聚合物组合物及其生产及其使用
公开(公告)号：WO1995022151A1
公开(公告)日：1995-08-17
申请号：PCT/FI1995000054
申请日：1995-02-09
申请人： NESTE OY , IKKALA, Olli , KIRMANEN, Pauli , SAVOLAINEN, Esko , VIRTANEN, Esa
发明人： NESTE OY
IPC分类号： H01B01/12
CPC分类号： H01B1/128 , C08L79/02 , C08L2666/24
摘要： The invention relates to an electrically conductive elastomer composition which comprises a thermoplastic polymer and a doped aniline polymer. A problem in the preparation of electrically conductive elastomer compositions is the lack of thermoplasticity of the electrically conductive component, making difficult the processing and the obtaining of a homogenous product. This problem has now been solved by having the doped aniline polymer be a substantially thermoplastic doped aniline polymer which is obtained by reacting with a functionalized protic acid a conjugated homo- or copolymer made up of at least unsubstituted and/or substituted aniline mers. The protic acid functionalizes the aniline polymer either on being heated together with the aniline polymer to a temperature of 80-250 DEG C or on being heated together with the aniline polymer and a solvent and on the solvent being evaporated. The elastomer composition is also composed of a plasticizer which plasticizes the doped aniline polymer and promotes its flow, preferably a metal compound with a plasticizing effect, such as a reaction product of zinc oxide and dodecylbenzenesulfonic acid.
摘要翻译：本发明涉及一种导电弹性体组合物，其包含热塑性聚合物和掺杂的苯胺聚合物。制备导电弹性体组合物的一个问题是缺乏导电组分的热塑性，难以加工和获得均匀的产品。现在已经通过使掺杂的苯胺聚合物为基本上热塑性的掺杂苯胺聚合物解决了这个问题，该聚合物通过与至少由未取代的和/或取代的苯胺组成的共轭均聚物或共聚物与官能化的质子酸反应获得。在将苯胺聚合物与苯胺聚合物一起加热到80-250℃的温度下或者与苯胺聚合物和溶剂一起加热并在溶剂上蒸发时，质子酸将苯胺聚合物官能化。弹性体组合物还由增塑剂构成，该增塑剂使掺杂的苯胺聚合物增塑并促进其流动，优选具有增塑作用的金属化合物，例如氧化锌和十二烷基苯磺酸的反应产物。

90. 发明申请

WO1995006685A1 ELECTRICALLY CONDUCTING COMPOSITIONS 审中-公开
标题翻译：电导体组成
公开(公告)号：WO1995006685A1
公开(公告)日：1995-03-09
申请号：PCT/FI1994000385
申请日：1994-09-01
申请人： NESTE OY , UNIAX CORPORATION
发明人： NESTE OY , UNIAX CORPORATION , YONG, Cao , ANDREATTA, Alejandro , IKKALA, Olli , PIETILÄ, Lars-Olof , PASSINIEMI, Pentti
IPC分类号： C08L79/02
CPC分类号： H01B1/128 , C08G73/0266 , C08K5/06 , C08K5/13 , C08K5/42 , C08L79/02
摘要： Compositions are disclosed comprising electrically conducting polyaniline and particular substituted compounds that simultaneously form hydrogen bonds and ring-ring interactions with, respectively, the NH-groups and the six-membered rings of the conducting polyanilines. The present conducting polyaniline compositions show drastically enhanced processibility and their blends with insulating or semiconducting materials exhibit significantly improved electrical properties.
摘要翻译：公开了包含导电聚苯胺和特别取代的化合物的组合物，其同时分别与导电聚苯胺的NH-基团和六元环形成氢键和环 - 环相互作用。本发明的导电聚苯胺组合物显示出显着提高的可加工性，并且它们与绝缘或半导体材料的共混物表现出显着改善的电性能。

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