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71. 发明申请

WO2017069495A1 폴리부타디엔의 제조 방법 审中-公开
标题翻译：聚丁二烯的生产方法
公开(公告)号：WO2017069495A1
公开(公告)日：2017-04-27
申请号：PCT/KR2016/011704
申请日：2016-10-18
申请人： 주식회사 엘지화학
发明人： 황우성 , 고준석 , 정회인 , 이종구
IPC分类号： C08F2/01 , C08F36/06 , C08F136/06
CPC分类号： C08F136/06 , C08F2/01 , C08F36/06 , C08F2/001
摘要： 폴리부타디엔 제조 중 발생하는 플러깅 현상을 최소화 하고, 전환율을 높임으로써, 생산성을 향상시킬 수 있는 폴리부타디엔의 제조 방법이 개시된다. 상기 폴리부타디엔의 제조 방법은, 플러깅 현상을 감소시키도록 병렬 배치된 2개의 제1 중합 반응기에 부타디엔, 중합 촉매 및 용매를 포함하는 원료를 각각 공급 및 중합하여 부타디엔 중합체를 포함하는 제1 중합액을 제조하고, 상기 제1 중합 반응기에서 중합열에 의해 생성되는 기체는 응축기로 배출되는 제1 중합 단계; 상기 제1 중합 반응기에 직렬 배치된 하나 이상의 제2 중합 반응기에 상기 제1 중합액을 공급 및 중합하여 부타디엔 중합체를 포함하는 제2 중합액을 제조하고, 상기 제2 중합 반응기에서 중합열에 의해 생성되는 기체는 응축기로 배출되는 제2 중합 단계; 및 상기 제2 중합액을 배출하는 단계를 포함한다.
摘要翻译：
最小化的聚丁二烯制造堵塞期间发生的现象，并且通过增加的转化率，公开了一种用于制造能够提高生产率的聚丁二烯的方法。第一聚合物溶液中以聚丁二烯的制造方法分别提供，并包含丁二烯，所述聚合催化剂和溶剂两个第一聚合反应器的并联布置，以减少堵塞现象丁二烯聚合物聚合原料第一聚合步骤，其中通过第一聚合反应器中的聚合热产生的气体被排出到冷凝器; 向第一聚合反应器中串联设置的至少一个第二聚合反应器供应并聚合第一聚合溶液以制备含有丁二烯聚合物的第二聚合溶液，第二聚合步骤，其中气体被排放到冷凝器; 并排出第二种聚合溶液。

72. 发明申请

WO2016196233A1 VINYLISOMERASE-DEHYDRATASES, ALKENOL DEHYDRATASES, LINALOOL DEHYDRATASES AND/ CROTYL ALCOHOL DEHYDRATASES AND METHODS FOR MAKING AND USING THEM 审中-公开
标题翻译：乙烯衍生物脱乙酰壳多糖，烷基脱氢ES ES，，，，ES ES ES ES M M M M M M M M M M M M M M M M M M M M
公开(公告)号：WO2016196233A1
公开(公告)日：2016-12-08
申请号：PCT/US2016/034488
申请日：2016-05-26
申请人： GENOMATICA, INC. , BRASKEM S.A.
发明人： CULLER, Stephanie J. , HASELBECK, Robert J. , NAGARAJAN, Harish , GOUVEA, Iuri Estrada , KOCH, Daniel Johannes , LOPES, Mateus Schreiner Garcez , PARIZZI, Lucas Pederson
IPC分类号： C08F36/06 , C12N1/21 , C12N15/60 , C12N15/63 , C12N9/88
CPC分类号： C12N9/88 , C07K2319/02 , C07K2319/034 , C12N9/90 , C12Y402/01 , C12Y402/01127 , C12Y504/04004
摘要： In alternative embodiments, provided are non-natural or genetically engineered vinylisomerase-dehydratase enzymes, including alkenol dehydratases, linalool dehydratases and crotyl alcohol dehydratases. In alternative embodiments, provided are non-natural or genetically engineered polypeptides having an activity comprising, for example, a vinylisomerase-dehydratase, an alkenol dehydratase, a linalool dehydratase and/or a crotyl alcohol dehydratase activity, or a combination thereof. In alternative embodiments, also provided are non-natural or genetically engineered nucleic acids (polynucleotides) encoding polypeptides described herein, expression or cloning vehicles comprising or having contained therein nucleic acids as described herein, and non-natural or genetically engineered cells comprising or having contained therein nucleic acids as described herein. In alternative embodiments, also provided are are methods for making various organic compounds, including methyl vinyl carbinol and butadiene.
摘要翻译：在替代实施方案中，提供非天然或遗传工程乙烯基异构酶 - 脱水酶，包括链烯醇脱水酶，里哪醇脱水酶和巴豆醇脱水酶。在替代实施方案中，提供了具有活性的非天然或遗传工程多肽，其包括例如乙烯基异构酶脱水酶，链烯醇脱水酶，芳樟醇脱水酶和/或巴豆醇脱水酶活性，或其组合。在替代实施方案中，还提供了编码本文所述的多肽的非天然或遗传工程化的核酸（多核苷酸），包含或含有本文所述的核酸的表达或克隆载体，以及非天然或遗传工程改造的细胞，其包含或含有其中如本文所述的核酸。在替代实施方案中，还提供了制备各种有机化合物，包括甲基乙烯基甲醇和丁二烯的方法。

73. 发明申请

WO2016131590A1 MULTIVINYLAMINOSILANES AS BRANCHING AGENTS FOR FUNCTIONALIZED ELASTOMERIC POLYMERS 审中-公开
标题翻译：作为功能化弹性体聚合物分散剂的多官能团硅烷
公开(公告)号：WO2016131590A1
公开(公告)日：2016-08-25
申请号：PCT/EP2016/051086
申请日：2016-01-20
申请人： TRINSEO EUROPE GMBH
发明人： RÖSSLE, Michael , DÖRING, Christian , THIELE, Sven , THIELEMANN, Dominique
IPC分类号： C07F7/10 , C08F12/08 , C08F36/06 , C08F36/08 , C07F7/21 , C08F4/46 , C08L21/00
CPC分类号： C07F7/10 , C07F7/0801 , C07F7/21 , C08F36/06 , C08F36/08 , C08F236/10 , C08F293/005 , C08F2230/085 , C08F2438/00 , C08F2810/20 , C08J3/24 , C08J2347/00 , C08K3/04 , C08K3/36 , C08L9/06 , C08L21/00
摘要： The present invention relates to novel polymerizable multivinylaminosilanes which are useful as branching agents for synthetic and natural rubber. The compounds of the invention can be used as such in the polymerization of conjugated diene monomers, optionally together with aromatic vinyl monomers, thus producing polymers, specifically elastomeric polymers, which can favorably be used in rubber articles such as tires.
摘要翻译：本发明涉及可用作合成和天然橡胶支化剂的新型可聚合多维乙烯基氨基硅烷。本发明的化合物可以直接用于共轭二烯单体，任选与芳族乙烯基单体一起聚合，从而生产聚合物，特别是弹性体聚合物，其可有利地用于橡胶制品如轮胎。

74. 发明申请

WO2016039003A1 ゴム組成物审中-公开
标题翻译：橡胶组合物
公开(公告)号：WO2016039003A1
公开(公告)日：2016-03-17
申请号：PCT/JP2015/069783
申请日：2015-07-09
申请人：宇部興産株式会社
发明人：斯波　晃司 , 山田　雄太 , 深澤　駿 , 岡本　尚美
IPC分类号： C08L9/00 , C08K3/04 , C08K3/36 , C08L7/00 , C08F36/06 , B60C1/00
CPC分类号： B60C1/00 , C08C19/02 , C08F36/06 , C08F136/06 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/00 , C08L91/00 , Y02T10/862 , C08K3/22 , C08K3/06 , C08K5/09 , C08K5/18 , C08F4/545
摘要：　本発明は、シス－１，４－構造含有率が９０％以上であるポリブタジエン（α）と、ポリブタジエン（α）以外のジエン系重合体（β）と、ゴム補強剤（γ）とを含み、加硫後における－３０℃の貯蔵弾性率（Ｅ'）が、２９ＭＰａ以下であることを特徴とするゴム組成物に関する。
摘要翻译：本发明涉及一种橡胶组合物，其特征在于含有顺式-1,4-结构含量为90％以上的聚丁二烯（α），除聚丁二烯（α）以外的二烯系聚合物（β），以及橡胶增强剂（γ），其特征在于在硫化后在-30℃下的储能弹性模量（E'）为29MPa以下。

75. 发明申请

WO2015086391A1 EPOXYTERMINIERTES POLYBUTADIEN ALS SAUERSTOFF-FÄNGER 审中-公开
标题翻译： EPOXYTERMINIERTES聚丁二烯比氧气捕手
公开(公告)号：WO2015086391A1
公开(公告)日：2015-06-18
申请号：PCT/EP2014/076377
申请日：2014-12-03
申请人： EVONIK INDUSTRIES AG , HABERKORN, Niko , DENKINGER, Peter , NORDHOFF, Stefan , NUMRICH, Uwe
发明人： HABERKORN, Niko , DENKINGER, Peter , NORDHOFF, Stefan , NUMRICH, Uwe
IPC分类号： C08C19/38 , C08F36/06 , B65D81/26 , B32B27/08 , C08G81/02 , C08L87/00 , C08K5/098 , C08J5/18 , B32B27/32 , B32B27/30
CPC分类号： C08F136/06 , B32B27/08 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2250/24 , B32B2307/7244 , B32B2307/74 , B32B2439/00 , B65D65/38 , B65D81/266 , C08C19/38 , C08J5/18 , C08J2367/02 , C08J2377/02 , C08J2447/00 , C08L67/02 , C08L77/02 , C09D147/00
摘要： Die vorliegende Erfindung betrifft die Verwendung von epoxyterminiertem Polydien mit endständigen Epoxygruppen als Sauerstofffänger, insbesondere als Bestandteil in Verpackungen.
摘要翻译：本发明涉及使用具有末端环氧基团作为氧清除剂epoxyterminiertem聚二烯，尤其是如在包装的组分。

76. 发明申请

WO2015047026A1 고무질 중합체, 그라프트 공중합체와 이들의 제조방법, 내충격 내열수지 조성물 审中-公开
标题翻译：橡胶聚合物，共聚物，其制备方法和耐冲击和耐热树脂组合物
公开(公告)号：WO2015047026A1
公开(公告)日：2015-04-02
申请号：PCT/KR2014/009196
申请日：2014-09-30
申请人： (주) 엘지화학
发明人： 채주병 , 정유성 , 박은선 , 전태영 , 김영민 , 이진호
IPC分类号： C08F36/06 , C08F2/22 , C08F2/38 , C08F279/04 , C08L51/04 , C08L55/02
CPC分类号： C08F2/22 , C08F2/38 , C08F36/06 , C08F279/04 , C08L9/00 , C08L51/04 , C08L55/02
摘要： 본 발명은 고무질 중합체, 그라프트 공중합체와 이들의 제조방법, 내충격 내열수지 조성물에 관한 것으로, 본 발명에 따르면, 고무질 중합체에 특정 가교조절제를 포함함으로써 내충격성, 내열성 및 내화학성이 우수한 제품을 구현할 수 있는 고무질 라텍스, 그라프트 공중합체 와 이들의 제조방법, 및 내충격 내열수지 조성물을 제공하는 효과가 있다.
摘要翻译：本发明涉及橡胶聚合物，接枝共聚物，其制备方法和耐冲击和耐热树脂组合物。根据本发明，提供了一种橡胶胶乳和接枝共聚物，其可通过在橡胶聚合物中包含特定的交联控制剂而在产品中实施以具有优异的耐冲击性，耐热性和耐化学性; 准备方法; 和耐冲击和耐热树脂组合物。

77. 发明申请

WO2014097245A1 PROCESS FOR THE PREPARATION OF (CO) POLYMERS OF CONJUGATED DIENES IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A BIS-IMINO-PYRIDINE COMPLEX OF COBALT 审中-公开
标题翻译：在含有BIS-IMINO-吡啶复合物的催化体系存在下制备（CO）聚合物的方法
公开(公告)号：WO2014097245A1
公开(公告)日：2014-06-26
申请号：PCT/IB2013/061193
申请日：2013-12-20
申请人： VERSALIS S.P.A.
发明人： MASI, Francesco , RICCI, Giovanni , SOMMAZZI, Anna , LEONE, Giuseppe , CALDARARO, Maria
IPC分类号： C08F36/06 , C08F136/06
CPC分类号： C08F136/06 , C07F15/065 , C08F4/7096 , C08F36/06 , C08F4/7042
摘要： Process for the preparation of (co) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one bis-imino-pyridine complex of cobalt having general formula (I) : wherein : R 2 and R 3 , equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; R 1 and R 4 , different from each other, represent a hydrogen atom; or they are selected from linear or branched C 1 -C 20 preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; arylalkyl groups; or R 1 and R 2 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R 3 and R 4 , can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R 5 , R 6 and R 7 , equal to or different from each other, represent a hydrogen atom, or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, optionally halogenated, cycloalkyl groups optionally substituted; aryl groups optionally substituted; arylalkyl groups; or R 5 and R 6 , can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, -sulfur, nitrogen, silicon, phosphorous, selenium; or R 6 and R 7 , can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C 1 - C 20 , preferably C 1 -C 15 , alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; X 1 and X 2 , equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C 1 -C 20 , preferably C 1 -C 15 , alkyl groups, -OCOR 8 groups or -OR 8 groups wherein R 8 is selected from linear or branched C 1 -C 20 / preferably C 1 -C 15 , alkyl groups.
摘要翻译：制备共轭二烯的（共）聚合物的方法，其包括在包含至少一种具有通式（I）的钴的二亚氨基 - 吡啶络合物的催化体系存在下聚合至少一种共轭二烯：其中：R2和 R 3彼此相同或不同，表示氢原子; 或者它们选自直链或支链C 1 -C 20，优选C 1 -C 15烷基，任选卤代的环烷基，任选取代的芳基，任选取代的芳基; R1和R4彼此不同，表示氢原子; 或者它们选自直链或支链C 1 -C 20，优选C 1 -C 15烷基，任选卤代的环烷基，任选取代的芳基，任选取代的芳基; 芳基烷基; 或者R 1和R 2可以任选地彼此结合形成与其结合的其它原子一起，含有3至6个碳原子的饱和的，不饱和的或芳族的，任选地被直链或支链C1- C20，优选C1-C15烷基，所述循环任选地含有其它杂原子，例如氧，硫，氮，硅，磷，硒; 或R 3和R 4可以任选地彼此结合形成与它们所结合的其它原子一起形成含有3-6个碳原子的饱和的，不饱和的或芳族的，任选被直链或支链C1 -C 20，优选C 1 -C 15烷基，所述循环任选地含有其它杂原子，例如氧，硫，氮，硅，磷，硒; R 5，R 6和R 7彼此相同或不同，表示氢原子，或它们选自直链或支链C 1 -C 20，优选C 1 -C 15烷基，任选卤代的环烷基任选取代; 任选取代的芳基; 芳基烷基; 或者R 5和R 6可以任选地彼此结合形成与它们所连接的其它原子一起形成含有3-6个碳原子的饱和的，不饱和的或芳族的，任选被直链或支链C1 -C 20，优选C 1 -C 15烷基，所述循环任选地含有其它杂原子，例如氧，硫，氮，硅，磷，硒; 或R6和R7可以任选地彼此结合形成与其结合的其它原子一起，含有3至6个碳原子的饱和，不饱和或芳族的环，任选被直链或支链C1 -C 20，优选C 1 -C 15烷基，所述循环任选地含有其它杂原子，例如氧，硫，氮，硅，磷，硒; X 1和X 2彼此相同或不同，表示卤素原子，例如氯，溴，碘; 或者它们选自直链或支链C 1 -C 20，优选C 1 -C 15烷基，-OCOR 8基团或-OR 8基团，其中R 8选自直链或支链C 1 -C 20，优选C 1 -C 15烷基。

78. 发明申请

WO2013184783A3 METHOD OF MAKING POLYMERS, POLYMER COMPOSITIONS AND ARTICLES CONTAINING SUCH POLYMERS 审中-公开
标题翻译：制备聚合物的方法，聚合物组合物和含有这种聚合物的制品
公开(公告)号：WO2013184783A3
公开(公告)日：2014-03-20
申请号：PCT/US2013044288
申请日：2013-06-05
申请人： FIRESTONE POLYMERS LLC
发明人： NAKATANI KENJI , DEDECKER MARK N , PADOLEWSKI JOSEPH P , PAWLOW JAMES H
IPC分类号： C08C19/25 , B60C1/00 , C08F36/06 , C08F236/10 , C08L15/00
CPC分类号： C08K5/5419 , C08C2/06 , C08C19/25 , C08C19/44 , C08F236/10 , C08J3/12 , C08J3/21 , C08J2309/06 , C08F2/06 , C08F4/48 , C08F236/06 , C08F212/08
摘要： A method of making a polymer with stable Mooney viscosity and molecular weight is described. A conjugated diolefin is reacted in a hydrocarbon solvent in the presence of an initiator to form a polymer. After forming the polymer, alkoxy silane terminal functionalizing groups are bonded to the polymer. A stabilizing agent having the formula (R)4-nSi(OH)n wherein R is a C1 to C18 alkyl, C1 to C18 alkyl group containing a heteroatom such as nitrogen or oxygen, C4 to C8 cycloalkyl, or C6 to C18 aromatic group is then added to the polymer, optionally in the presence of hydrocarbon oil. The polymer is then desolvatizing, resulting in a polymer with stable Mooney viscosity and molecular weight, even over prolonged periods of time. Compositions and articles containing the polymer are also described.
摘要翻译：描述了制备具有稳定门尼粘度和分子量的聚合物的方法。共轭二烯烃在烃溶剂中在引发剂的存在下反应以形成聚合物。形成聚合物之后，烷氧基硅烷末端官能化基团与聚合物结合。具有式（R）4-nSi（OH）n的稳定剂，其中R是C1至C18烷基，含有氮或氧的杂原子的C1至C18烷基，C4至C8环烷基或C6至C18芳族基团然后加入到聚合物中，任选地在烃油存在下。然后将聚合物脱溶剂化，得到具有稳定的门尼粘度和分子量的聚合物，甚至在较长的时间段内。还描述了含有聚合物的组合物和制品。

79. 发明申请

WO2014037861A1 PROCESS FOR THE PREPARATION OF DIENE POLYMERS OR OF RANDOM VINYL ARENE-DIENE COPOLYMERS 审中-公开
标题翻译：制备二烯聚合物或随机乙烯基二烯共聚物的方法
公开(公告)号：WO2014037861A1
公开(公告)日：2014-03-13
申请号：PCT/IB2013/058169
申请日：2013-08-30
申请人： VERSALIS S.P.A.
发明人： SODDU, Luca , SOLITO, Antonio Giuseppe
IPC分类号： C08C19/28 , C08C19/44 , C08F2/26 , C08F4/48 , C08F36/06 , C08F236/10
CPC分类号： C08F36/06 , C08C19/44 , C08F236/10 , C08F4/48
摘要： Process for the preparation of diene polymers or random vinyl arene-diene copolymers which comprises (co) polymerizing, anionically, in the presence of at least one hydrocarbon solvent, at least one conjugated diene monomer and optionally at least one vinyl arene, in the presence of at least one lithium-based initiator, at least one aprotic polar compound, and at least one compound containing one or more functional groups of the acetylenic type. Said process allows diene polymers or random vinyl arene-diene copolymers to be obtained, which can be advantageously used in the production of tyres, in particular in the production of tyre treads. The diene polymers or the random vinyl arene-diene copolymers obtained through said process can also be used for the modification of plastic materials [for example, for obtaining high impact polystyrene (HIPS) ].
摘要翻译：二烯聚合物或无规乙烯基芳烃 - 二烯共聚物的制备方法，其包括（共）在至少一种烃溶剂存在下阴离子聚合至少一种共轭二烯单体和任选的至少一种乙烯基芳烃的至少一种锂基引发剂，至少一种非质子极性化合物和至少一种含有一个或多个炔属型官能团的化合物。所述方法允许获得二烯聚合物或无规乙烯基芳烃 - 二烯共聚物，其可有利地用于生产轮胎，特别是在轮胎胎面的生产中。通过所述方法获得的二烯聚合物或无规乙烯基芳烃 - 二烯共聚物也可用于塑料材料的改性（例如获得高抗冲聚苯乙烯（HIPS）]。

80. 发明申请

WO2013186691A1 PROCESS FOR THE PREPARATION OF FUNCTIONALIZED AND BRANCHED ELASTOMERIC COPOLYMERS AND USE THEREOF IN VULCANIZABLE ELASTOMERIC COMPOSITIONS 审中-公开
标题翻译：制备功能化和分支的弹性体共聚物的方法及其在可再生弹性体组合物中的用途
公开(公告)号：WO2013186691A1
公开(公告)日：2013-12-19
申请号：PCT/IB2013/054746
申请日：2013-06-10
申请人： VERSALIS S.P.A
发明人： SODDU, Luca
IPC分类号： C08F2/26 , C08F4/08 , C08F36/06 , C08F236/06 , C08F236/10 , C08L15/02 , C08F236/20
CPC分类号： C08F236/10 , C08C19/44 , C08F212/08 , C08F2810/40 , C08K3/04 , C08K3/36 , C08L9/00 , C08L9/06 , C08L15/00 , C08L81/04 , C08L91/00 , C08F4/08
摘要： A process for the preparation of a functionalized and branched elastomeric copolymer comprising the following steps : (a) anionic copolymerization of at least one conjugated diene monomer and at least one vinyl arene, in the presence of at least one hydrocarbon solvent, of at least one lithium-based initiator, and of at least one polar modifier, obtaining a solution comprising an elastomeric copolymer; (b) reacting at least 10% by weight, preferably from 20% by weight to 100% by weight, of the polymeric chains present in the elastomeric copolymer obtained in step (a) with at least one compound having at least one functional group selected from: epoxides, ketones, esters, aldehydes, obtaining a solution comprising a functionali zed elastomeric copolymer; (c) adding a quantity of lithium-based initiator to the solution obtained in step (b), from 1 to 4 times, preferably from 1.5 to 3 times, the molar quantity of lithium-based initiator used in step (a) and a compound of bromine having general formula (I): R-Br (I) wherein R represents a linear or branched C 1 -C 30 , preferably C 2 -C 10 , alkyl group, a C 3 -C 30 , preferably C 4 -C 10 , cycloalkyl group, a C 6 -C 30 , preferably C 6 -C 12 , aryl group.
摘要翻译：一种制备官能化和支化的弹性体共聚物的方法，包括以下步骤：（a）至少一种共轭二烯单体和至少一种乙烯基芳烃在至少一种烃溶剂的存在下至少一种锂基引发剂和至少一种极性改性剂，得到包含弹性体共聚物的溶液; （b）使在步骤（a）中获得的弹性体共聚物中存在的至少一种具有至少一个官能团的化合物选自至少10重量％，优选20重量％至100重量％的聚合物链从：环氧化物，酮，酯，醛，获得包含功能性弹性体共聚物的溶液; （c）在步骤（b）中获得的溶液中加入一定量的锂基引发剂，为步骤（a）中使用的锂基引发剂的摩尔量和a（a）的摩尔量的1至4倍，优选1.5至3倍具有通式（I）的溴化合物：R-Br（I）其中R表示直链或支链C 1 -C 30，优选C 2 -C 10烷基，C 3 -C 30，优选C 4 -C 10环烷基，C 6 -C30，优选C6-C12，芳基。

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