发明申请
WO2013186691A1 PROCESS FOR THE PREPARATION OF FUNCTIONALIZED AND BRANCHED ELASTOMERIC COPOLYMERS AND USE THEREOF IN VULCANIZABLE ELASTOMERIC COMPOSITIONS
审中-公开
基本信息:
- 专利标题: PROCESS FOR THE PREPARATION OF FUNCTIONALIZED AND BRANCHED ELASTOMERIC COPOLYMERS AND USE THEREOF IN VULCANIZABLE ELASTOMERIC COMPOSITIONS
- 专利标题(中):制备功能化和分支的弹性体共聚物的方法及其在可再生弹性体组合物中的用途
- 申请号:PCT/IB2013/054746 申请日:2013-06-10
- 公开(公告)号:WO2013186691A1 公开(公告)日:2013-12-19
- 发明人: SODDU, Luca
- 申请人: VERSALIS S.P.A
- 申请人地址: P.le Boldrini, 1 I-20097 S. Donato Mil.se (MI) IT
- 专利权人: VERSALIS S.P.A
- 当前专利权人: VERSALIS S.P.A
- 当前专利权人地址: P.le Boldrini, 1 I-20097 S. Donato Mil.se (MI) IT
- 代理机构: MAIWALD PATENTANWALTS GMBH
- 优先权: ITMI2012A001018 20120612
- 主分类号: C08F2/26
- IPC分类号: C08F2/26 ; C08F4/08 ; C08F36/06 ; C08F236/06 ; C08F236/10 ; C08L15/02 ; C08F236/20
摘要:
A process for the preparation of a functionalized and branched elastomeric copolymer comprising the following steps : (a) anionic copolymerization of at least one conjugated diene monomer and at least one vinyl arene, in the presence of at least one hydrocarbon solvent, of at least one lithium-based initiator, and of at least one polar modifier, obtaining a solution comprising an elastomeric copolymer; (b) reacting at least 10% by weight, preferably from 20% by weight to 100% by weight, of the polymeric chains present in the elastomeric copolymer obtained in step (a) with at least one compound having at least one functional group selected from: epoxides, ketones, esters, aldehydes, obtaining a solution comprising a functionali zed elastomeric copolymer; (c) adding a quantity of lithium-based initiator to the solution obtained in step (b), from 1 to 4 times, preferably from 1.5 to 3 times, the molar quantity of lithium-based initiator used in step (a) and a compound of bromine having general formula (I): R-Br (I) wherein R represents a linear or branched C 1 -C 30 , preferably C 2 -C 10 , alkyl group, a C 3 -C 30 , preferably C 4 -C 10 , cycloalkyl group, a C 6 -C 30 , preferably C 6 -C 12 , aryl group.
摘要(中):
一种制备官能化和支化的弹性体共聚物的方法,包括以下步骤:(a)至少一种共轭二烯单体和至少一种乙烯基芳烃在至少一种烃溶剂的存在下至少一种 锂基引发剂和至少一种极性改性剂,得到包含弹性体共聚物的溶液; (b)使在步骤(a)中获得的弹性体共聚物中存在的至少一种具有至少一个官能团的化合物选自至少10重量%,优选20重量%至100重量%的聚合物链 从:环氧化物,酮,酯,醛,获得包含功能性弹性体共聚物的溶液; (c)在步骤(b)中获得的溶液中加入一定量的锂基引发剂,为步骤(a)中使用的锂基引发剂的摩尔量和a(a)的摩尔量的1至4倍,优选1.5至3倍 具有通式(I)的溴化合物:R-Br(I)其中R表示直链或支链C 1 -C 30,优选C 2 -C 10烷基,C 3 -C 30,优选C 4 -C 10环烷基,C 6 -C30,优选C6-C12,芳基。