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    • 47. 发明申请
    • PROCESSES FOR THE PREPARATION OF AN OLEFINIC PRODUCT
    • 制备烯烃产品的方法
    • WO2014067958A1
    • 2014-05-08
    • PCT/EP2013/072630
    • 2013-10-29
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.SHELL OIL COMPANY
    • KLOTH, Antonius Gijsbertus JohannesSADASIVAN VIJAYAKUMARI, SivakumarVAN WESTRENEN, Jeroen
    • C07C1/20C07C11/02
    • C07C1/20C07C4/04C07C2529/40C10G3/49C10G9/00C10G2400/20Y02P30/42C07C11/02
    • The invention provides a process for the preparation of an olefinic product, the process comprising the steps of: • (a) reacting an oxygenate feedstock, comprising oxygenate, in an oxygenate reaction zone in the presence of a catalyst comprising a molecular sieve, at a temperature in the range of from 350 to 1000°C, to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; • (b) optionally cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; • (c) further rapidly cooling the reaction effluent stream to a temperature at or lower than the dew point temperature of the reaction effluent stream by direct injection of a first aqueous liquid into the reaction effluent stream, to form a quench effluent stream; • (d) separating the first quench effluent stream into a liquid quench stream and a gaseous quench stream; and passing the gaseous quench stream into a quench tower and contacting the gaseous quench stream with a second aqueous liquid in the presence of at least one set of quench tower internals, to produce a quench tower gaseous stream comprising the olefinic product.
    • 本发明提供了一种制备烯烃产物的方法,该方法包括以下步骤:(a)在包含分子筛的催化剂存在下,在含氧化合物反应区中使包含含氧化合物的含氧化合物原料在 温度在350至1000℃的范围内,以产生至少包含含氧化合物,烯烃,水和酸性副产物的反应流出物流; (b)任选地通过间接热交换将反应流出物流冷却到大于反应流出物流的露点温度的温度; (c)通过将第一含水液体直接注入反应流出物流中,将反应流出物流进一步快速冷却至等于或低于反应流出物流的露点温度的温度,以形成骤冷流出物流; •(d)将第一骤冷流出物流分离成液体骤冷流和气态骤冷流; 并将气态骤冷流通入骤冷塔中,并在至少一组骤冷塔内部存在的情况下使气态骤冷流与第二含水液体接触,以产生包含烯烃产物的骤冷塔气流。
    • 50. 发明申请
    • PROCESS FOR THE OXIDATIVE REGENERATION OF A DEACTIVATED CATALYST AND AN APPARATUS THEREFOR
    • 灭活催化剂氧化还原过程及其装置
    • WO2013079500A1
    • 2013-06-06
    • PCT/EP2012/073781
    • 2012-11-28
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.SHELL OIL COMPANY
    • SADASIVAN VIJAYAKUMARI, SivakumarCHEWTER, Leslie, AndrewVAN WESTRENEN, Jeroen
    • B01J39/02B01D53/26B01D53/28B01J29/90B01J38/12B01J20/18B01J39/14C07C1/20C07C11/02C07C11/04C07C11/06B01J29/85B01J29/40
    • B01J29/90B01J20/18B01J20/3408B01J20/3458B01J29/40B01J29/85B01J38/12C07C1/20C07C4/06C07C2529/00Y02P20/584Y02P30/42C07C11/02
    • The present invention relates to a process for the oxidative regeneration of a deactivated catalyst, an apparatus therefore and a process for the preparation of an olefinic product incorporating such a regeneration process, said oxidative regeneration process comprising at least the steps of: - providing a catalyst comprising molecular sieve in hydrogen form to a guard zone (200); - passing a regeneration gas stream (185, 185a) comprising oxidant through the guard zone (200) to remove at least a part of one or both of any alkali metal ion and any alkaline earth metal ion from the regeneration gas stream (185, 185a) by ion exchange with the catalyst, to provide a treated regeneration gas stream comprising oxidant (205); - providing deactivated catalyst comprising molecular sieve in a regeneration zone (100), said deactivated catalyst from one or both of an oxygenate to olefin process and an olefin cracking process, wherein said regeneration zone (100) is separated from said guard zone (200) such that there is no transfer of catalyst from the guard zone (200) to the regeneration zone (100); - regenerating the deactivated catalyst in the regeneration zone (100) with the treated regeneration gas stream (205) to provide regenerated catalyst comprising regenerated molecular sieve; wherein said catalyst comprising molecular sieve in hydrogen form in said guard zone (200) is one or both of deactivated catalyst comprising molecular sieve in hydrogen form and regenerated catalyst comprising regenerated molecular sieve in hydrogen form.
    • 本发明涉及一种失活催化剂的氧化再生方法,一种装置及其制备包含这种再生方法的烯烃产物的方法,所述氧化再生方法至少包括以下步骤: - 提供催化剂 包括氢形式的分子筛到保护区(200); - 通过所述保护区(200)使包含氧化剂的再生气流(185,185a)通过所述再生气流(185,185a)去除至少一部分任何碱金属离子和任何碱土金属离子中的一种或两种 ),以提供包含氧化剂(205)的经处理的再生气流; - 在再生区(100)中提供包含分子筛的失活催化剂,所述失活催化剂从含氧化合物至烯烃方法中的一种或两种和烯烃裂解方法,其中所述再生区(100)与所述保护区(200)分离, 使得催化剂不从保护区(200)转移到再生区(100); - 用经处理的再生气流(205)再生再生区(100)中的失活的催化剂,以提供包含再生分子筛的再生催化剂; 其中在所述保护区(200)中包含氢形式的分子筛的所述催化剂是包含氢形式的分子筛的失活催化剂之一或两者以及包含氢形式的再生分子筛的再生催化剂。