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41. 发明申请

WO2009147057A1 POLYMERIZABLE TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS 审中-公开
标题翻译：可聚合型II型光敏剂和可固化组合物
公开(公告)号：WO2009147057A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/056531
申请日：2009-05-28
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , VAN LUPPEN, Jaymes
IPC分类号： C07C219/08 , C07C219/14 , C07D295/18 , C07D311/86 , C09D11/00
CPC分类号： C07D335/16 , C07C217/22 , C07C219/08 , C07C219/14 , C09D11/101 , C09D11/322
摘要： A polymerizable Type Il photoinitiator according to Formula (I): wherein: A represents a Norrish Type Il initiating group; L represents a divalent linking group positioning the Norrish Type Il initiating group A and the CR2R3-group in a 1-5 to a 1-8 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 8 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks including the polymerizable Type Il photoinitiator are also disclosed.
摘要翻译：根据式（I）的可聚合II型光引发剂：其中：A表示Norrish II型起始基团; L表示在1-5至1-8位置定位Norrish II型起始基团A和CR 2 R 3基团的二价连接基团，其中位置1定义为A的芳族或脂环族环中的第一个原子，其中L 共价键合，位置5至8定义为L共价结合的CR 2 R 3 - 基团的碳原子，条件是L不含有胺。还公开了包含可聚合II型光引发剂的可辐射固化组合物和油墨。

42. 发明申请

WO2008061957A1 NOVEL RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：新型可辐射固化组合物
公开(公告)号：WO2008061957A1
公开(公告)日：2008-05-29
申请号：PCT/EP2007/062501
申请日：2007-11-19
申请人： Agfa Graphics NV , LOCCUFIER, Johan , CLAES, Roland
发明人： LOCCUFIER, Johan , CLAES, Roland
IPC分类号： C09D11/10 , C08F2/46 , C08F2/50 , C09D4/00
CPC分类号： C09D11/30 , C08F2/50 , C09D4/00 , C09D11/101 , Y10S522/908
摘要： A radiation curable composition comprising a curable compound, a photo-initiator and a co-initiator characterized in that said co-initiator has a structure according to Formula (l): A-L-B; wherein A represents a structural moiety comprising an aromatic tertiary amine; B represents a structural moiety comprising at least one aliphatic tertiary amine; L represents a divalent linking group positioning the nitrogen atom of the aromatic amine of the structural moiety A and the nitrogen of at least one aliphatic amine of the structural moiety B in a 1-3 to 1-23 position; with the proviso that at least one aromatic and at least one aliphatic amine each have at least one alfa-hydrogen.
摘要翻译：一种包含可固化化合物，光引发剂和共引发剂的可辐射固化组合物，其特征在于所述共引发剂具有式（I）的结构：A-L-B; 其中A表示包含芳族叔胺的结构部分; B表示包含至少一个脂族叔胺的结构部分; L表示将结构部分A的芳族胺的氮原子和结构部分B的至少一种脂族胺的氮定位在1-3至1-23位置的二价连接基团; 条件是至少一种芳族和至少一种脂族胺各自具有至少一个α-氢。

43. 发明申请

WO2008061954A1 NOVEL CO-INITIATORS 审中-公开
标题翻译：新兴合作伙伴
公开(公告)号：WO2008061954A1
公开(公告)日：2008-05-29
申请号：PCT/EP2007/062494
申请日：2007-11-19
申请人： Agfa Graphics NV , LOCCUFIER, Johan , CLAES, Roland
发明人： LOCCUFIER, Johan , CLAES, Roland
IPC分类号： C07C229/60 , C07D295/10 , C09D201/08 , C09D11/00 , G03F7/031
CPC分类号： G03F7/031 , C07C229/60 , C07D295/088 , C07D295/104 , C09D11/101
摘要： A novel co-initiator is disclosed characterized in that said CO- initiator has a structure according to Formula I wherein B represents a structural moiety comprising at least two aliphatic tertiary amines; L represents a divalent linking group positioning the nitrogen atom of the aromatic amine and the nitrogen of at least one aliphatic amine of the structural moiety B in a 1-9 to 1-23 position; with the proviso that at least one aromatic and at least two aliphatic amine each have an alf a-hydrogen.
摘要翻译：公开了一种新的共引发剂，其特征在于所述CO-引发剂具有式I的结构，其中B表示包含至少两个脂族叔胺的结构部分; L表示将芳族胺的氮原子和结构部分B的至少一种脂族胺的氮置于1-9至1-23位置的二价连接基团; 条件是至少一个芳族和至少两个脂族胺各自具有氢原子。

44. 发明申请

WO2007107494A1 METHOD FOR MAKING A LITHOGRAPHIC PRINTING PLATE 审中-公开
标题翻译：制作平版印刷版的方法
公开(公告)号：WO2007107494A1
公开(公告)日：2007-09-27
申请号：PCT/EP2007/052443
申请日：2007-03-15
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , LINGIER, Stefaan , VAN DAMME, Marc
发明人： LOCCUFIER, Johan , LINGIER, Stefaan , VAN DAMME, Marc
IPC分类号： B41N3/08 , B41C1/10
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , G03F7/322
摘要： A method for making a lithographic printing plate is disclosed which comprises the steps of : (1) providing a heat-sensitive lithographic printing plate precursor comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a heat- sensitive coating, (2) image-wise exposing said precursor with IR-radiation or heat, and (3) developing said image-wise exposed precursor with an alkaline developing solution comprising a compound having at least two onium groups . According to the above method, a printing plate is formed with an improved developing latitude or an improved exposure latitude.
摘要翻译：公开了一种制备平版印刷版的方法，其包括以下步骤：（1）提供热敏平版印刷版前体，其包含在具有亲水性表面的支持体上，或者设置有亲水层，热敏涂层，（2）用IR辐射或加热使所述前体成像曝光，和（3）用包含具有至少两个鎓基的化合物的碱性显影溶液显影所述成像曝光的前体。根据上述方法，形成具有改善的显影纬度或改善曝光宽容度的印版。

45. 发明申请

WO2007099053A1 METHOD FOR MAKING A LITHOGRAPHIC PRINTING PLATE 审中-公开
标题翻译：制作平版印刷版的方法
公开(公告)号：WO2007099053A1
公开(公告)日：2007-09-07
申请号：PCT/EP2007/051684
申请日：2007-02-21
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , LINGIER, Stefaan , VANGAEVER, Frank , LENS, Mark , VAN DAMME, Marc
发明人： LOCCUFIER, Johan , LINGIER, Stefaan , VANGAEVER, Frank , LENS, Mark , VAN DAMME, Marc
IPC分类号： B41C1/10 , G03F7/32
CPC分类号： G03F7/322 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41N3/006
摘要： A method for making a lithographic printing plate is disclosed which comprises the steps of: (1) providing a heat-sensitive lithographic printing plate precursor comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a heat-sensitive coating, (2) image-wise exposing said precursor with IR-radiation or heat, and (3) developing said image-wise exposed precursor with an alkaline developing solution, characterised in that an antisludge agent is present in said precursor or in said developing solution or in said precursor and said developing solution, and wherein said antisludge agent is a 5-membered heteroaromatic compound, comprising a -NH-group wherein said hydrogen is capable of being deprotonated in said alkaline developing solution, selected from the group consisting of an optionally substituted benztriazole, 1, 2 , 3-triazole, tetrazole or indazole compound. According to the above method, the formation of sludge is inhibited or reduced.
摘要翻译：公开了一种制备平版印刷版的方法，其包括以下步骤：（1）提供热敏平版印刷版前体，其包含在具有亲水性表面的支持体上，或者设置有亲水层，热敏涂层，（2）用IR辐射或加热对所述前体进行成像曝光，和（3）用碱性显影液显影所述成像曝光的前体，其特征在于，所述前体或所述显影液中存在抗污剂或所述前体和所述显影溶液中，并且其中所述防淤剂是包含-NH-基团的5元杂芳族化合物，其中所述氢能够在所述碱性显影溶液中去质子化，所述碱性显影溶液选自任选地取代苯并三唑，1,2,3-三唑，四唑或吲唑化合物。根据上述方法，抑制或减少污泥的形成。

46. 发明申请

WO2007099047A1 A HEAT-SENSITIVE POSITIVE-WORKING LITHOGRAPHIC PRINTING PLATE PRECURSOR 审中-公开
标题翻译：高灵敏度平面印刷机前驱板
公开(公告)号：WO2007099047A1
公开(公告)日：2007-09-07
申请号：PCT/EP2007/051612
申请日：2007-02-20
申请人： Agfa Graphics NV , LOCCUFIER, Johan , LINGIER, Stefaan , VAN AERT, Hubertus , VENNEMAN, Jan , VAN DAMME, Marc
发明人： LOCCUFIER, Johan , LINGIER, Stefaan , VAN AERT, Hubertus , VENNEMAN, Jan , VAN DAMME, Marc
IPC分类号： B41C1/10
CPC分类号： B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , Y10S430/107 , Y10S430/109 , Y10S430/145
摘要： A heat-sensitive positive-working lithographic printing plate precursor comprising (1) a support having a hydrophilic surface or which is provided with a hydrophilic layer, (2) a heat-sensitive coating, comprising an IR absorbing agent, a phenolic resin and a first polymer, characterised in that said first polymer is an alkaline soluble polymer comprising a monomeric unit having a structure according to formula I or formula II wherein at least one of the aromatic groups Ar 1 and Ar 2 is an optionally substituted heteroaroraatic group.
摘要翻译： 1.一种热敏正性平版印刷版原版，其特征在于，具有：（1）具有亲水性表面的或具有亲水层的载体，（2）感光性涂层，其包含IR吸收剂，酚醛树脂和第一聚合物，其特征在于所述第一聚合物是包含具有根据式I或式II结构的单体单元的碱溶性聚合物，其中至少一个芳族基团Ar 1和Ar 2 2是任选取代的杂芳基基团。

47. 发明申请

WO2010133381A1 POLYMERIZABLE POLYMERIC PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：可聚合聚合物和辐射可固化组合物
公开(公告)号：WO2010133381A1
公开(公告)日：2010-11-25
申请号：PCT/EP2010/050706
申请日：2010-01-22
申请人： Agfa Graphics NV , LOCCUFIER, Johan , VANMAELE, Luc , DOCX, Hedwige , WILLEMS, Nadine
发明人： LOCCUFIER, Johan , VANMAELE, Luc , DOCX, Hedwige , WILLEMS, Nadine
IPC分类号： C08F290/06 , C08F299/02 , C08F2/50 , C08F8/14 , C09D11/10
CPC分类号： C08F2/50 , C08F222/1006 , C08F290/06 , C08F290/061 , C08F290/14 , C08F290/141 , C08F290/142 , C08F299/00 , C08F299/02 , C08F299/065 , C08G83/005 , C09D11/101 , C09D11/30
摘要： A poiymerizable polymeric photoinitiator according to Formula (I): wherein: PL represents an n+m+p-functional polymeric core; n and m independently represent an integer from 1 to 30; p represents an integer from 0 to 10; 0 is 0 or 1; IN! represents a group selected from the group consisting of a benzophenone, a thioxanthone, a carbazole, a anthraquinone, a camphor quinone, an α-hydroxyalkylphenone, an α-aminoalkylphenone, an acylphosphine oxide, a bisacyl phosphine oxide, an acylphosphine sulfide, a phenyl glyoxalate, a benzoin ether, a benzyl ketal, an α-dialkoxyacetophenone, a carbazolyl-O-acyl-oxime, an α-haloarylketone and an α-haloaryl sulfone; L 3 and L 4 represent a substituted or unsubstituted divalent linking group comprising 1 to 14 carbon atoms; A represents a radically poiymerizable functional group selected from the group consisting of an acrylate, a methacrylate, a styrene, an acryl amide, a methacryl amide, a maleate, a fumarate, an itaconate, an vinyl ether, an allyl ether, an allyl ester, a maleimide, a vinyl nitrile and a vinyl ester; and R4 represents a substituted or unsubstituted alkyl group. Radiation curable compositions containing the poiymerizable polymeric photoinitiator and methods for preparing the poiymerizable polymeric photoinitiator are also disclosed.
摘要翻译：根据式（I）的可聚合的聚合物光引发剂：其中：PL表示n + m + p-官能聚合物核; n和m独立地表示1〜30的整数， p表示0〜10的整数， 0为0或1; 在！代表选自二苯甲酮，噻吨酮，咔唑，蒽醌，樟脑醌，α-羟基烷基苯酮，α-氨基烷基苯酮，酰基氧化膦，双酰基氧化膦，酰基膦硫化物，苯基乙二醛，苯偶姻醚，苄基缩酮，α-二烷氧基苯乙酮，咔唑基-O-酰基肟，α-卤代芳基酮和α-卤代芳基砜; L3和L4表示包含1至14个碳原子的取代或未取代的二价连接基团; A表示选自丙烯酸酯，甲基丙烯酸酯，苯乙烯，丙烯酰胺，甲基丙烯酰胺，马来酸酯，富马酸酯，衣康酸酯，乙烯基醚，烯丙基醚，烯丙基酯的自由基聚合的官能团，马来酰亚胺，乙烯基腈和乙烯酯; 并且R 4表示取代或未取代的烷基。还公开了含有可聚合聚合物光引发剂的可辐射固化组合物和制备可聚合聚合物光引发剂的方法。

48. 发明申请

WO2009147054A1 MULTIFUNCTIONAL TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS 审中-公开
标题翻译：多功能型II型光敏元件和可固化组合物
公开(公告)号：WO2009147054A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/056517
申请日：2009-05-28
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , VAN LUPPEN, Jaymes
IPC分类号： C07C229/16 , C07D311/86 , C07D295/185 , C09D11/00
CPC分类号： C07D295/185 , C07C217/22 , C07C219/14 , C07C229/12 , C07D311/86 , C09D11/101
摘要： A multifunctional Type Il photoinitiator according to Formula (I): wherein X represents a structural moiety according to Formula (II) : wherein: A represents a Norrish Type Il initiating group; and L represents a divalent linking group positioning the Norrish Type Il initiating group A and the CR2R3-group in a 1-5 to a 1-9 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 9 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks including the multifunctional Type Il photoinitiator are also disclosed.
摘要翻译：根据式（I）的多官能II型光引发剂：其中X表示根据式（II）的结构部分：其中：A表示Norrish II型引发基团; L表示在1-5至1-9位置定位Norrish II型起始基团A和CR 2 R 3基团的二价连接基团，其中位置1定义为A的芳族或脂环族环中的第一个原子， L共价键合，位置5至9定义为L共价结合的CR 2 R 3 - 基团的碳原子，条件是L不含胺。还公开了包括多功能II型光引发剂的可辐射固化组合物和油墨。

49. 发明申请

WO2009068590A1 PREPARATION METHOD OF COPOLYMERIZABLE PHOTOINITIATORS 审中-公开
标题翻译：可共聚光敏剂的制备方法
公开(公告)号：WO2009068590A1
公开(公告)日：2009-06-04
申请号：PCT/EP2008/066289
申请日：2008-11-27
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan
发明人： LOCCUFIER, Johan
IPC分类号： C07C69/63 , C07C67/14 , C07C67/317 , C07C69/54 , C07D335/16 , C07F9/53
CPC分类号： C07C69/63 , C07C67/14 , C07C67/317 , C07C69/54 , C07D335/16 , C07F9/3247 , C07F9/5337
摘要： An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group comprising at least one photoinitiating moiety selected from the group consisting of benzil ketals, α,α-dialkoxyacetophenones, α-hydroxyalkylphenones, α-aminoalkylphenones, acylphosphine oxides, bis- acylphosphine oxides, acylphosphine sulfides, α-haloketones, α-halosulfones, phenylglyoxalates, benzophenones, thioxanthones, and 1,2-diketones; L represents a n+o-valent linking group comprising at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to O or 1; X represents a group selected from the group consisting of Cl, Br, I and R 2 SO 3 ; and R 2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group, an aralkyl group, an aryl group and a heteroaryl group; A method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I) is also disclosed.
摘要翻译：用于制备根据式（I）的（甲基）丙烯酸酯化光引发剂的中间体：其中：R1选自氢和甲基; A表示包含至少一个选自苯偶酰缩酮，a，α-二烷氧基苯乙酮，α-羟基烷基苯酮，α-氨基烷基苯酮，酰基氧化膦，双酰基氧化膦，酰基膦硫化物，α-卤代酮，卤代砜，苯基乙醛酸酯，二苯甲酮，噻吨酮和1,2-二酮; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自Cl，Br，I和R 2 SO 3的基团; R 2表示选自烷基，烯基，炔基，烷芳基，芳烷基，芳基和杂芳基的任意取代的基团。还公开了通过根据式（I）从中间体除去HX来制备（甲基）丙烯酸酯化光引发剂的方法。

50. 发明申请

WO2009030658A1 RADIATION CURABLE COMPOSITIONS FOR FOOD APPLICATIONS 审中-公开
标题翻译：食品应用的辐射可固化组合物
公开(公告)号：WO2009030658A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061484
申请日：2008-09-01
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , CLAES, Roland
发明人： LOCCUFIER, Johan , CLAES, Roland
IPC分类号： C07C229/60 , C08F2/48 , C09D11/00 , C09D11/10
CPC分类号： C08F2/48 , C09D11/101 , C09D11/38 , Y10T428/31507 , Y10T428/31551 , Y10T428/31678 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31938
摘要： A liquid radiation curable composition for inkjet printing comprising a photoinitiating system consisting of one or more diffusion hindered photoinitiators selected from the group consisting of non-polymeric di- or multifunctional initiators, oligomeric or polymeric initiators and polymerizable initiators and one or more polymerizable co- initiators wherein at least one of the polymerizable co-initiators is a polymerizable aromatic tertiary amine. Inkjet inks, an inkjet printing process and packaging materials are also disclosed.
摘要翻译：一种用于喷墨印刷的液体可辐射固化组合物，其包含由一种或多种扩散受阻光引发剂组成的光引发体系，所述扩散受阻光引发剂选自非聚合二 - 或多官能引发剂，低聚或聚合引发剂和可聚合引发剂和一种或多种可聚合共引发剂其中至少一种可聚合共引发剂是可聚合的芳族叔胺。还公开了喷墨油墨，喷墨印刷工艺和包装材料。

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